Carrollite R130024

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Name: Carrollite
RRUFF ID: R130024
Ideal Chemistry: CuCo2S4
Locality: Kisanfu, Katanga, Democratic Republic of the Congo
Source: Isabel Fay
Owner: RRUFF
Description: Silver metallic, massive, associated with chalcocite, bornite, digenite and magnesite
Status: The identification of this mineral has been confirmed only by single crystal X-ray diffraction.
Mineral Group: [ Spinel (66) ]
Quick search: [ All Carrollite samples (3) ]
CHEMISTRY 
RRUFF ID: R130024.2
Sample Description: Microprobe Fragment
RAMAN SPECTRUM 
RRUFF ID:
Sample Description: Unoriented Raman on the primary sample
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RRUFF ID: R130024
Wavelength:
Sample Description: Unoriented Raman on the primary sample
Instrument settings: Thermo Almega XR 532nm @ 100% of 150mW
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Raman Data (Processed)
RRUFF File
POWDER DIFFRACTION 
RRUFF ID: R130024.9
Sample Description: Single crystal, powder profile is calculated
Cell Refinement Output: a: 9.467(2)Å    b: 9.467(2)Å    c: 9.467(2)Å
alpha: 90°    beta: 90°    gamma: 90°   Volume: 848.33(7)Å3    Crystal System: cubic
  File Type Information Close
Calculated diffraction file.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

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DIF File
X-ray Data (XY - RAW) View Graph
RRUFF File
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REFERENCES for Carrollite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Faber W L (1852) On carrollite, a new cobalt mineral, American Journal of Science and Arts, 13, 418-419   [view file]

Foshag W F (1928) New mineral names, American Mineralogist, 13, 32-34   [view file]

Riedel E, Horvath E (1973) Kationen-anionen-abstände in kupfer- und chrom-thiospinellen, Materials Research Bulletin, 8, 973-982

Williamson D P, Grimes N W (1974) An X-ray diffraction investigation of sulphide spinels, Journal of Physics D: Applied Physics, 7, 1-6

Wagner T, Cook N J (1999) Carrollite and related minerals of the linnaeite group: Solid solutions and nomenclature in the light of new data from the Siegerland District, Germany, The Canadian Mineralogist, 37, 545-558   [view file]

Pattrick R A D, Coker V S, Pearce C I, Telling N D, van der Laan G (2008) The oxidation state of copper and cobalt in carrollite, CuCo2S4, The Canadian Mineralogist, 46, 1317-1322   [view file]

Buckley A N, Skinner W M, Harmer S L, Pring A, Fan L J (2009) Electronic environments in carrollite, CuCo2S4, determined by soft X-ray photoelectron absorption spectroscopy, Geochimica et Cosmochimica Acta, 73, 4452-4467

Hazen R M, Hystad G, Golden J J, Hummer D R, Liu C, Downs R T, Morrison S M, Ralph J, Grew E S (2017) Cobalt mineral ecology, American Mineralogist, 102, 108-116   [view file]

Bosi F, Biagioni C, Pasero M (2019) Nomenclature and classification of the spinel supergroup, European Journal of Mineralogy, 31, 183-192   [view file]