R050231 - RRUFF Database: Raman, X-ray, Infrared, and Chemistry

Tyrolite R050231

Name: Tyrolite
RRUFF ID: R050231
Ideal Chemistry: Ca₂Cu₉(AsO₄)₄(CO₃)(OH)₈·11H₂O
Locality: Tyrol, Austria
Source: Marcus Origlieri
Owner: RRUFF
Description: Thin green scaly crystals
Status: The identification of this mineral is confirmed by single-crystal X-ray diffraction and chemical analysis.

Mineral Group: [ Tyrolite (3) ]

Quick search: [ All Tyrolite samples (3) ]

CHEMISTRY

RRUFF ID:	R050231.2
Sample Description:	Microprobe fragment
Measured Chemistry:	(Ca_0.80Fe²⁺_0.20)_Σ=1(Cu_4.86Zn_0.11◻_0.03)_Σ=5((As_0.96S_0.03P_0.01)_Σ=1O4)₂(CO₃)(OH)₄·6H₂O
Microprobe Data File:	[ Download Excel File ]

RAMAN SPECTRUM

RRUFF ID:

Sample Description:

Unoriented sample

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please select a specific
orientation angle.

BROAD SCAN WITH SPECTRAL ARTIFACTS

RRUFF ID:

R050231

Wavelength:

Sample Description:

Unoriented sample

Instrument settings:

Thermo Almega XR 532nm @ 50% of 150mW

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	Raman Data (RAW)
	RRUFF File

POWDER DIFFRACTION

RRUFF ID:

R050231.9

Sample Description:

Single crystal, powder profile is calculated

Cell Refinement Output:

a: 10.40(3)Å b: 54.9(3)Å c: 5.52(2)Å
alpha: 90° beta: 90° gamma: 90° Volume: 3151(10)Å³ Crystal System: orthorhombic

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REFERENCES for Tyrolite
American Mineralogist Crystal Structure Database Record: [view record]
Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]
Werner A G (1817) Kupferschaum, in Letztes Mineral-System Craz, Gerlach and Gerold Freiberg 50-51 [view file]
Haidinger W (1845) Zweite Klasse: Geogenide. IV. Ordnung. Malachite. VII. Euchlormalachit. Tirolit., in Handbuch der Bestimmenden Mineralogie Bei Braumüller and Seidel Wien 506-511 [view file]
Church A H (1895) A chemical study of some native arsenates and phosphates, Mineralogical Magazine, 11, 1-12 [view file]
Berry L G (1948) Tyrolite, higginsite and cornwallite, American Mineralogist, 33, 193-193 [view file]
Guillemin C (1956) Contribution a la minéralogie des arséniates, phosphates et vanadates de cuivre, Bulletin de la Société Française de Minéralogie et de Cristallographie, 79, 7-95 [view file]
Fleischer M (1957) New mineral names, American Mineralogist, 42, 117-124 [view file]
Kloprogge J T, Frost R L (2000) Raman microscopy study of tyrolite: a multi-anion arsenate mineral, Applied Spectroscopy, 54, 517-521
Krivovichev S V, Chernyshov D Y, Döbelin N, Armbruster T, Kahlenberg V, Kaindl R, Ferraris G, Tessadri R, Kaltenhauser G (2006) Crystal chemistry and polytypism of tyrolite, American Mineralogist, 91, 1378-1384 [view file]

REFERENCES for Tyrolite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Werner A G (1817) Kupferschaum, in Letztes Mineral-System Craz, Gerlach and Gerold Freiberg 50-51 [view file]

Haidinger W (1845) Zweite Klasse: Geogenide. IV. Ordnung. Malachite. VII. Euchlormalachit. Tirolit., in Handbuch der Bestimmenden Mineralogie Bei Braumüller and Seidel Wien 506-511 [view file]

Church A H (1895) A chemical study of some native arsenates and phosphates, Mineralogical Magazine, 11, 1-12 [view file]

Berry L G (1948) Tyrolite, higginsite and cornwallite, American Mineralogist, 33, 193-193 [view file]

Guillemin C (1956) Contribution a la minéralogie des arséniates, phosphates et vanadates de cuivre, Bulletin de la Société Française de Minéralogie et de Cristallographie, 79, 7-95 [view file]

Fleischer M (1957) New mineral names, American Mineralogist, 42, 117-124 [view file]

Kloprogge J T, Frost R L (2000) Raman microscopy study of tyrolite: a multi-anion arsenate mineral, Applied Spectroscopy, 54, 517-521

Krivovichev S V, Chernyshov D Y, Döbelin N, Armbruster T, Kahlenberg V, Kaindl R, Ferraris G, Tessadri R, Kaltenhauser G (2006) Crystal chemistry and polytypism of tyrolite, American Mineralogist, 91, 1378-1384 [view file]