Diaboleite R050270

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Record 158 of 500  


Name: Diaboleite
RRUFF ID: R050270
Ideal Chemistry: CuPb2Cl2(OH)4
Locality: Tiger, Pinal County, Arizona, USA
Source: Marcus Origlieri
Owner: RRUFF
Description: Blue irregular crystalline
Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis
Mineral Group: [ Perovskite (44) ]
Quick search: [ All Diaboleite samples (2) ]
CHEMISTRY 
RRUFF ID: R050270.2
Sample Description: Microprobe Fragment
Measured Chemistry: (Cu0.97Pb0.03)Σ=1Pb2.00Cl2.00(OH)4
Microprobe Data File: [ Download Excel File ]
RAMAN SPECTRUM 
RRUFF ID:
Sample Description: Unoriented sample
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Direction of polarization of laser relative to fiducial mark:
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BROAD SCAN WITH SPECTRAL ARTIFACTS
RRUFF ID: R050270
Wavelength:
Sample Description: Unoriented sample
Instrument settings: Thermo Almega XR 532nm @ 100% of 150mW
INFRARED SPECTRUM (Attenuated Total Reflectance) 
RRUFF ID: R050270.1
Instrument settings: SensIR Durascope on a Nicolet Magna 860 FTIR
Resolution:
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POWDER DIFFRACTION 
RRUFF ID: R050270.1
Sample Description: Powder
Cell Refinement Output: a: 5.8675(2)Å    b: 5.8675(2)Å    c: 5.4927(4)Å
alpha: 90°    beta: 90°    gamma: 90°   Volume: 189.10(2)Å3    Crystal System: tetragonal
  File Type Information Close
Calculated diffraction file.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

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REFERENCES for Diaboleite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Spencer L J, Mountain E D (1923) New lead-copper minerals from the Mendip Hills (Somerset), Mineralogical Magazine, 20, 67-92   [view file]

Wherry E T (1924) New minerals: new species, American Mineralogist, 9, 96-97   [view file]

Cooper M A, Hawthorne F C (1995) Diaboleite, Pb2Cu(OH)4Cl2, a defect perovskite structure with stereoactive lone-pair behavior of Pb2+, The Canadian Mineralogist, 33, 1125-1129   [view file]

Frost R L, Williams P A, Martens W (2003) Raman spectroscopy of the minerals boléite, cumengéite, diaboléite and phosgenite - implications for the analysis of cosmetics of antiquity, Mineralogical Magazine, 67, 103-111   [view file]

Frost R L, Williams P A (2004) Raman spectroscopy of some basic chloride containing minerals of lead and copper, Spectrochimica Acta Part A, 60, 2071-2077

Mitchell R H, Welch M D, Chakhmouradian A R (2017) Nomenclature of the perovskite supergroup: A hierarchical system of classification based on crystal structure and composition, Mineralogical Magazine, 81, 411-461   [view file]