Hydroxylapatite R060180

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Record 177 of 476  


Name: Hydroxylapatite
RRUFF ID: R060180
Ideal Chemistry: Ca5(PO4)3OH
Locality: Holly Springs, Georgia, USA
Source: Julian Gray
Owner: RRUFF
Description: Tan colored nodule in talc schist associated with serpentinite
Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis
Mineral Group: [ Apatite (56) ]
Quick search: [ All Hydroxylapatite samples (4) ]
CHEMISTRY 
RRUFF ID: R060180.2
Sample Description: Microprobe Fragment
Measured Chemistry: Ca5.00(P1.00O4)3((OH)0.98Cl0.02)
Microprobe Data File: [ Download Excel File ]
RAMAN SPECTRUM 
RRUFF ID:
Sample Description: Unoriented sample
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BROAD SCAN WITH SPECTRAL ARTIFACTS
RRUFF ID: R060180
Wavelength:
Sample Description: Unoriented sample
Instrument settings: Thermo Almega XR 532nm @ 100% of 150mW
POWDER DIFFRACTION 
RRUFF ID: R060180.1
Sample Description: Powder
Cell Refinement Output: a: 9.41932(9)Å    b: 9.41932(9)Å    c: 6.8792(1)Å
alpha: 90°    beta: 90°    gamma: 120°   Volume: 528.58(1)Å3    Crystal System: hexagonal
  File Type Information Close
Calculated diffraction file.

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Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

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REFERENCES for Hydroxylapatite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Damour A A (1856) Sur l'hydro-apatite, espèce minérale, Annales des Mines, 10, 65-68   [view file]

Schaller W T (1912) Mineralogical notes, Series 2. Mineralogy of the French phosphorites, U.S. Geological Survey Bulletin, 509, 89-100   [view file]

Foshag W F (1936) New mineral names, American Mineralogist, 21, 269-272   [view file]

Kay M I, Young R A, Posner A S (1964) Crystal structure of hydroxyapatite, Nature, 204, 1050-1052

Jullmann H, Mosebach R (1966) Zur Synthese, Licht- und Doppelbrechung des Hydroxylapatits, Zeitschrift für Naturforschung B Chemical Science, 21, 493-494   [view file]

Sudarsanan K, Young R A (1969) Significant precision in crystal structural details: Holly Springs hydroxyapatite, Acta Crystallographica, B25, 1534-1543

Dickens B, Brown W E, Kruger G J, Stewart J M (1973) Ca4(PO4)2O, tetracalcium diphosphate monooxide. Crystal structure and relationships to Ca5(PO4)3OH and K3Na(SO4)2, Acta Crystallographica, B29, 2046-2056

Elliot J C, Mackie P E, Young R A (1973) Monoclinic hydroxyapatite, Science, 180, 1055-1057

Fiore S, Lavanio R (1991) Brushite, hydroxylapatite, and taranakite from Apulian caves (southern Italy): New mineralogical data, American Mineralogist, 76, 1722-1727   [view file]

Nasdala L (1992) A Raman study on the so-called “pseudoapatite” from Halsbrücke near Freiberg/Saxony, Neues Jahrbuch für Mineralogie, Abhandlungen, 164, 211-227

Jeanjean J, Vincent U, Fedorov M (1994) Structural modification of calcium hydroxyapatite induced by sorption of cadmium ions, Journal of Solid State Chemistry, 108, 68-72

Kikuchi M, Yamazaki A, Otsuka R, Akao M, Aoki H (1994) Crystal structure of Sr-substituted hydroxyapatite synthesized by hydrothermal method, Journal of Solid State Chemistry, 113, 373-378

Jeanjean J, McGrellis S, Rouchaud J C, Fedorov M, Rondeau A, Perocheau S, Dubis A (1996) A crystallographic study of the sorption of cadmium on calcium hydroxyapatites: incidence of cationic vacancies, Journal of Solid State Chemistry, 126, 195-201

Chakhmouradian A R, Mitchell R H (1999) Niobian ilmenite, hydroxylapatite and sulfatian monazite: alternative hosts for incompatible elements in calcite kimberlite from Internatsional'naya, Yakutia, The Canadian Mineralogist, 37, 1177-1189   [view file]

Ikoma T, Yamazaki A (1999) Preparation and structure refinement of monoclinic hydroxyapatite, Journal of Solid State Chemistry, 144, 272-276

Fleet M E, Liu X (2000) Site preference of rare earth elements in hydroxyapatite [Ca10(PO4)6(OH)2], Journal of Solid State Chemistry, 149, 391-398

Ivanova T I, Frank-Kamenetskaya O V, Kol'tsov A B, Ugolkov V L (2001) Crystal structure of calcium-deficient carbonated hydroxyapatite. thermal decomposition, Journal of Solid State Chemistry, 160, 340-349

Takagi S, Mathew M (2001) Structures of biological minerals in dental research, Journal of Research of the National Bureau of Standards, 106, 1035-1044   [view file]

Wilson R M, Elliott J C, Dowker S E P (2003) Formate incorporation in the structure of Ca–deficient apatite: Rietveld structure refinement, Journal of Solid State Chemistry, 174, 132-140

Roth P (2007) Hydroxylapatite, in Minerals first discovered in Switzerland and minerals named after Swiss individuals Kristallografik Verlag Achberg Germany 86-87

Burke E A J (2008) Tidying up mineral names: an IMA-CNMNC scheme for suffixes, hyphens and diacritical marks, The Mineralogical Record, 39, 131-135   [view file]

Oxmann J F, Pham Q H, Lara R J (2008) Quantification of individual phosphorus species in sediment: a sequential conversion and extraction method, European Journal of Soil Science, 59, 1177-1190   [view file]

Lee Y J, Stephens P W, Tang Y, Li W, Phillips B L, Parise J B, Reeder R J (2009) Arsenate substitution in hydroxylapatite: Structural characterization of the Ca5(PxAs1-xO4)3OH solid solution, American Mineralogist, 94, 666-675   [view file]

Pasero M, Kampf A R, Ferraris C, Pekov I V, Rakovan J R, White T J (2010) Nomenclature of the apatite supergroup minerals, European Journal of Mineralogy, 22, 163-179   [view file]

Biagioni C, Pasero M (2013) The crystal structure of johnbaumite, Ca5(AsO4)3OH, the arsenate analogue of hydroxylapatite, American Mineralogist, 98, 1580-1584

Ulian G, Valdrè G, Corno M, Ugliengo P (2013) The vibrational features of hydroxylapatite and type A carbonated apatite: A first principle contribution, American Mineralogist, 98, 752-759

Hovis G L, McCubbin F M, Nekvasil H, Ustunisik G, Woerner W R, Lindsley D H (2014) A novel technique for fluorapatite synthesis and the thermodynamic mixing behavior of F-OH apatite crystalline solutions, American Mineralogist, 99, 890-897

Hovis G L, Scott B T, Altomare C M, Leaman A R, Morris M D, Tomaino G P, McCubbin F M (2014) Thermal expansion of fluorapatite-hydroxylapatite crystalline solutions, American Mineralogist, 99, 2171-2175

Hughes J M (2015) The many facets of apatite, American Mineralogist, 100, 1033-1039

Banno Y, Miyawaki R, Momma K, Bunno M (2016) A CO3-bearing member of the hydroxylapatite-hydroxylellestadite series from Tadano, Fukushima Prefecture, Japan: CO3-SO4 substitution in the apatite-ellestadite series, Mineralogical Magazine, 80, 363-370

Hughes J M, Harlov D, Kelly S R, Rakovan J, Wilke M (2016) Solid solution in the apatite OH-Cl binary system: Compositional dependence of solid-solution mechanisms in calcium phosphate apatites along the Cl-OH binary, American Mineralogist, 101, 1783-1791

Antonakos A, Liarokapis E, Kyriacou A, Leventouri T (2017) Raman and IR studies of the effect of Fe substitution in hydroxyapatites and deuterated hydroxyapatite, American Mineralogist, 102, 85-91

Hughes J M, Harlov D, Rakovan J F (2018) Structural variations along the apatite F-OH join, American Mineralogist, 103, 1981-1987

Fau A, Beyssac O, Gauthier M, Panczer G, Gasnault O, Meslin P Y, Bernard S, Maurice S, Forni O, Boulliard J C, Bosc F, Drouet C (2022) Time-resolved Raman and luminescence spectroscopy of synthetic REE-doped hydroxylapatites and natural apatites, American Mineralogist, 107, 1341-1352