Hydroxylapatite R130713

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Record 179 of 476  

Name: Hydroxylapatite
RRUFF ID: R130713
Ideal Chemistry: Ca5(PO4)3OH
Locality: Wessels mine, Kalahari manganese field, Northern Cape Province, South Africa
Source: Robert Lavinsky
Owner: RRUFF
Description: Transparent pale green hexagonal tablets
Status: The identification of this mineral has been confirmed only by single crystal X-ray diffraction.
Mineral Group: [ Apatite (56) ]
Quick search: [ All Hydroxylapatite samples (4) ]
RAMAN SPECTRUM 
RRUFF ID:
Sample Description: Unoriented sample
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BROAD SCAN WITH SPECTRAL ARTIFACTS
RRUFF ID: R130713
Wavelength:
Sample Description: Unoriented sample
Instrument settings: Thermo Almega XR 532nm @ 100% of 150mW
POWDER DIFFRACTION 
RRUFF ID: R130713.9
Sample Description: Single crystal, powder profile is calculated
Cell Refinement Output: a: 9.4378(8)Å    b: 9.4378(8)Å    c: 6.9109(8)Å
alpha: 90°    beta: 90°    gamma: 120°   Volume: 533.10(7)Å3    Crystal System: hexagonal
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Calculated diffraction file.

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Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

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REFERENCES for Hydroxylapatite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Damour A A (1856) Sur l'hydro-apatite, espèce minérale, Annales des Mines, 10, 65-68   [view file]

Schaller W T (1912) Mineralogical notes, Series 2. Mineralogy of the French phosphorites, U.S. Geological Survey Bulletin, 509, 89-100   [view file]

Foshag W F (1936) New mineral names, American Mineralogist, 21, 269-272   [view file]

Kay M I, Young R A, Posner A S (1964) Crystal structure of hydroxyapatite, Nature, 204, 1050-1052

Jullmann H, Mosebach R (1966) Zur Synthese, Licht- und Doppelbrechung des Hydroxylapatits, Zeitschrift für Naturforschung B Chemical Science, 21, 493-494   [view file]

Sudarsanan K, Young R A (1969) Significant precision in crystal structural details: Holly Springs hydroxyapatite, Acta Crystallographica, B25, 1534-1543

Dickens B, Brown W E, Kruger G J, Stewart J M (1973) Ca4(PO4)2O, tetracalcium diphosphate monooxide. Crystal structure and relationships to Ca5(PO4)3OH and K3Na(SO4)2, Acta Crystallographica, B29, 2046-2056

Elliot J C, Mackie P E, Young R A (1973) Monoclinic hydroxyapatite, Science, 180, 1055-1057

Fiore S, Lavanio R (1991) Brushite, hydroxylapatite, and taranakite from Apulian caves (southern Italy): New mineralogical data, American Mineralogist, 76, 1722-1727   [view file]

Nasdala L (1992) A Raman study on the so-called “pseudoapatite” from Halsbrücke near Freiberg/Saxony, Neues Jahrbuch für Mineralogie, Abhandlungen, 164, 211-227

Jeanjean J, Vincent U, Fedorov M (1994) Structural modification of calcium hydroxyapatite induced by sorption of cadmium ions, Journal of Solid State Chemistry, 108, 68-72

Kikuchi M, Yamazaki A, Otsuka R, Akao M, Aoki H (1994) Crystal structure of Sr-substituted hydroxyapatite synthesized by hydrothermal method, Journal of Solid State Chemistry, 113, 373-378

Jeanjean J, McGrellis S, Rouchaud J C, Fedorov M, Rondeau A, Perocheau S, Dubis A (1996) A crystallographic study of the sorption of cadmium on calcium hydroxyapatites: incidence of cationic vacancies, Journal of Solid State Chemistry, 126, 195-201

Chakhmouradian A R, Mitchell R H (1999) Niobian ilmenite, hydroxylapatite and sulfatian monazite: alternative hosts for incompatible elements in calcite kimberlite from Internatsional'naya, Yakutia, The Canadian Mineralogist, 37, 1177-1189   [view file]

Ikoma T, Yamazaki A (1999) Preparation and structure refinement of monoclinic hydroxyapatite, Journal of Solid State Chemistry, 144, 272-276

Fleet M E, Liu X (2000) Site preference of rare earth elements in hydroxyapatite [Ca10(PO4)6(OH)2], Journal of Solid State Chemistry, 149, 391-398

Ivanova T I, Frank-Kamenetskaya O V, Kol'tsov A B, Ugolkov V L (2001) Crystal structure of calcium-deficient carbonated hydroxyapatite. thermal decomposition, Journal of Solid State Chemistry, 160, 340-349

Takagi S, Mathew M (2001) Structures of biological minerals in dental research, Journal of Research of the National Bureau of Standards, 106, 1035-1044   [view file]

Wilson R M, Elliott J C, Dowker S E P (2003) Formate incorporation in the structure of Ca–deficient apatite: Rietveld structure refinement, Journal of Solid State Chemistry, 174, 132-140

Roth P (2007) Hydroxylapatite, in Minerals first discovered in Switzerland and minerals named after Swiss individuals Kristallografik Verlag Achberg Germany 86-87

Burke E A J (2008) Tidying up mineral names: an IMA-CNMNC scheme for suffixes, hyphens and diacritical marks, The Mineralogical Record, 39, 131-135   [view file]

Oxmann J F, Pham Q H, Lara R J (2008) Quantification of individual phosphorus species in sediment: a sequential conversion and extraction method, European Journal of Soil Science, 59, 1177-1190   [view file]

Lee Y J, Stephens P W, Tang Y, Li W, Phillips B L, Parise J B, Reeder R J (2009) Arsenate substitution in hydroxylapatite: Structural characterization of the Ca5(PxAs1-xO4)3OH solid solution, American Mineralogist, 94, 666-675   [view file]

Pasero M, Kampf A R, Ferraris C, Pekov I V, Rakovan J R, White T J (2010) Nomenclature of the apatite supergroup minerals, European Journal of Mineralogy, 22, 163-179   [view file]

Biagioni C, Pasero M (2013) The crystal structure of johnbaumite, Ca5(AsO4)3OH, the arsenate analogue of hydroxylapatite, American Mineralogist, 98, 1580-1584

Ulian G, Valdrè G, Corno M, Ugliengo P (2013) The vibrational features of hydroxylapatite and type A carbonated apatite: A first principle contribution, American Mineralogist, 98, 752-759

Hovis G L, McCubbin F M, Nekvasil H, Ustunisik G, Woerner W R, Lindsley D H (2014) A novel technique for fluorapatite synthesis and the thermodynamic mixing behavior of F-OH apatite crystalline solutions, American Mineralogist, 99, 890-897

Hovis G L, Scott B T, Altomare C M, Leaman A R, Morris M D, Tomaino G P, McCubbin F M (2014) Thermal expansion of fluorapatite-hydroxylapatite crystalline solutions, American Mineralogist, 99, 2171-2175

Hughes J M (2015) The many facets of apatite, American Mineralogist, 100, 1033-1039

Banno Y, Miyawaki R, Momma K, Bunno M (2016) A CO3-bearing member of the hydroxylapatite-hydroxylellestadite series from Tadano, Fukushima Prefecture, Japan: CO3-SO4 substitution in the apatite-ellestadite series, Mineralogical Magazine, 80, 363-370

Hughes J M, Harlov D, Kelly S R, Rakovan J, Wilke M (2016) Solid solution in the apatite OH-Cl binary system: Compositional dependence of solid-solution mechanisms in calcium phosphate apatites along the Cl-OH binary, American Mineralogist, 101, 1783-1791

Antonakos A, Liarokapis E, Kyriacou A, Leventouri T (2017) Raman and IR studies of the effect of Fe substitution in hydroxyapatites and deuterated hydroxyapatite, American Mineralogist, 102, 85-91

Hughes J M, Harlov D, Rakovan J F (2018) Structural variations along the apatite F-OH join, American Mineralogist, 103, 1981-1987

Fau A, Beyssac O, Gauthier M, Panczer G, Gasnault O, Meslin P Y, Bernard S, Maurice S, Forni O, Boulliard J C, Bosc F, Drouet C (2022) Time-resolved Raman and luminescence spectroscopy of synthetic REE-doped hydroxylapatites and natural apatites, American Mineralogist, 107, 1341-1352