R060949 - RRUFF Database: Raman, X-ray, Infrared, and Chemistry

Arsentsumebite R060949

Name: Arsentsumebite
RRUFF ID: R060949
Ideal Chemistry: Pb₂Cu(AsO₄)(SO₄)(OH)
Locality: Capitana mine, Copiapo, Chile
Source: Bob Jenkins [view label]
Owner: RRUFF
Description: Green crystalline blebs scattered on the barite matrix
Status: The identification of this mineral is confirmed by single-crystal X-ray diffraction and chemical analysis.

Mineral Group: [ Brackebuschite (17) ]

Quick search: [ All Arsentsumebite samples (3) ]

CHEMISTRY

RRUFF ID:	R060949.2
Sample Description:	Microprobe Fragment
Measured Chemistry:	Pb_2.00(Cu_0.98Fe_0.02)_Σ=1(As_1.00O₄)(S_1.00O₄)(OH); OH estimated by charge balance and difference
Microprobe Data File:	[ Download Excel File ]

RAMAN SPECTRUM

RRUFF ID:

Sample Description:

Unoriented sample

DOWNLOADS:

To download sample data,
please select a specific
orientation angle.

BROAD SCAN WITH SPECTRAL ARTIFACTS

RRUFF ID:

R060949

Wavelength:

Sample Description:

Unoriented sample

Instrument settings:

Thermo Almega XR 532nm @ 100% of 150mW

DOWNLOADS:

	Raman Data (Processed)
	RRUFF File

POWDER DIFFRACTION

RRUFF ID:

R060949.9

Sample Description:

Single crystal, powder profile is calculated

Cell Refinement Output:

a: 7.841(8)Å b: 5.908(5)Å c: 8.922(8)Å
alpha: 90° beta: 112.14(4)° gamma: 90° Volume: 382.8(7)Å³ Crystal System: monoclinic

File Type Information

Calculated diffraction file.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

DOWNLOADS:

	DIF File
	X-ray Data (XY - RAW)
	RRUFF File

REFERENCES for Arsentsumebite
American Mineralogist Crystal Structure Database Record: [view record]
Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]
Vésignié J P L (1935) Présentation d'échantillons, Bulletin de la Société Française de Minéralogie, 58, 4-5 [view file]
Bideaux R A, Nichols M C, Williams S A (1966) The arsenate analog of tsumebite, a new mineral, American Mineralogist, 51, 258-259 [view file]
Chudoba K F (1974) Arsentsumebit, Handbuch der Mineralogie, 4, 5-5
Zubkova N V, Pushcharovsky D Y, Giester G, Tillmanns E, Pekov I V, Kleimenov D A (2002) The crystal structure of arsentsumebite, Pb₂Cu[(As,S)O₄]₂(OH), Mineralogy and Petrology, 75, 79-88
Frost R L, Palmer S J, Xi Y (2011) Raman spectroscopy of the multi anion mineral arsentsumebite Pb₂Cu(AsO₄)(SO₄)(OH) and in comparison with tsumebite Pb₂Cu(PO₄)(SO₄)(OH), Spectrochimica Acta Part A-Molecular and Biomolecular Spectroscopy, A83, 449-452

REFERENCES for Arsentsumebite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Vésignié J P L (1935) Présentation d'échantillons, Bulletin de la Société Française de Minéralogie, 58, 4-5 [view file]

Bideaux R A, Nichols M C, Williams S A (1966) The arsenate analog of tsumebite, a new mineral, American Mineralogist, 51, 258-259 [view file]

Chudoba K F (1974) Arsentsumebit, Handbuch der Mineralogie, 4, 5-5

Zubkova N V, Pushcharovsky D Y, Giester G, Tillmanns E, Pekov I V, Kleimenov D A (2002) The crystal structure of arsentsumebite, Pb₂Cu[(As,S)O₄]₂(OH), Mineralogy and Petrology, 75, 79-88

Frost R L, Palmer S J, Xi Y (2011) Raman spectroscopy of the multi anion mineral arsentsumebite Pb₂Cu(AsO₄)(SO₄)(OH) and in comparison with tsumebite Pb₂Cu(PO₄)(SO₄)(OH), Spectrochimica Acta Part A-Molecular and Biomolecular Spectroscopy, A83, 449-452