D R060010 - RRUFF Database: Raman, X-ray, Infrared, and Chemistry

Ludwigite R060010

Name: Ludwigite
RRUFF ID: R060010
Ideal Chemistry: Mg₂Fe³⁺O₂(BO₃)
Locality: Victoria Quarry, Riverside, California, USA
Source: University of Arizona Mineral Museum 9094 [view label]
Owner: RRUFF
Description: Black elongated prismatic crystals, associated with pale yellow clinohumite on white calcite matrix
Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis

Mineral Group: [ Ludwigite (5) ]

Quick search: [ All Ludwigite samples (2) ]

CHEMISTRY

RRUFF ID:	R060010.2
Sample Description:	Microprobe fragment
Measured Chemistry:	(Mg_1.68Fe²⁺_0.32)_Σ=2(Fe³⁺_0.74Al_0.23Cr_0.03)_Σ=1O₅ ; B not measured but estimated by difference and charge balance

RAMAN SPECTRUM

RRUFF ID:

Sample Description:

Unoriented sample

DOWNLOADS:

To download sample data,
please select a specific
orientation angle.

BROAD SCAN WITH SPECTRAL ARTIFACTS

RRUFF ID:

R060010

Wavelength:

Sample Description:

Unoriented sample

Instrument settings:

Thermo Almega XR 532nm @ 100% of 150mW

DOWNLOADS:

	Raman Data (RAW)
	RRUFF File

INFRARED SPECTRUM (Attenuated Total Reflectance)

RRUFF ID:

R060010.1

Sample Description:

Powder

Instrument settings:

SensIR Durascope on a Nicolet Magna 860 FTIR

Resolution:

DOWNLOADS:

	Infrared Data (Processed)
	RRUFF File

POWDER DIFFRACTION

RRUFF ID:

R060010.1

Sample Description:

Powder

Cell Refinement Output:

a: 9.2330(4)Å b: 12.254(1)Å c: 3.0200(2)Å
alpha: 90° beta: 90° gamma: 90° Volume: 341.69(4)Å³ Crystal System: orthorhombic

File Type Information

Calculated diffraction file.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

DOWNLOADS:

	Cell Refinement Data
	Cell Refinement Output Data
	DIF File
	X-ray Data (XY - Processed)
	RRUFF File
	X-ray Data (XY - RAW)
	RRUFF File

REFERENCES for Ludwigite
American Mineralogist Crystal Structure Database Record: [view record]
Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]
Tschermak G (1874) Ludwigit, ein neues Mineral aus dem Banate, Mineralogische Mittheilungen, 1874, 59-66 [view file]
Bertaut E F (1950) Structures des boroferrites, Acta Crystallographica, 3, 473-474
Takéuchi Y, Watanabé T, Ito T (1950) The crystal structures of warwickite, ludwigite and pinakiolite, Acta Crystallographica, 3, 98-107
Bovin J O, O'Keefe M, O'Keefe M A (1981) Electron microscopy of oxyborates. I. Defect structures in the minerals pinakiolite, ludwigite, orthopinakiolite, and takéuchiite, Acta Crystallographica, A37, 28-35
Hriljac J A, Brown R D, Cheetham A K, Satek L C (1990) The synthesis and crystal structures of the related series of aluminoborates: Co_2.1Al_0.9BO₅, Ni₂AlBO₅ and Cu₂AlBO, Journal of Solid State Chemistry, 84, 289-298
Norrestam R, Kritikos M, Nielsen K, Sotofte I, Thorup N (1994) Structural characterization of two synthetic Ni-ludwigites, and some semiempirical EHTB calculations on the ludwigite structure type, Journal of Solid State Chemistry, 111, 217-223
Irwin M B, Peterson R C (1999) The crystal structure of ludwigite, The Canadian Mineralogist, 37, 939-943 [view file]
Marincea S (1999) Ludwigite from the type locality, Onca de Fier, Romania: new data and review, The Canadian Mineralogist, 37, 1343-1362 [view file]
Holtstam D (2001) Crystal chemistry of a manganian ludwigite, Neues Jahrbuch für Mineralogie, Monatshefte, 2001, 520-528
Leite C A F, Guimaraes R B, Fernandes J C, Continentino M A, Paschoal C W A, Ayala A P, Guedes I (2001) Temperature-dependent Raman scattering study of Fe₃O₂BO₃ ludwigite, Journal of Raman Spectroscopy, 33, 1-5
Brovkin A A, Rozhdestvenskaya I V, Rykova E A (2002) Cation distribution in the structure of titanium-containing ludwigite, Crystallography Reports, 47, 412-414
Brovkin A A, Rozhdestvenskaya I V, Rykova E A (2002) Cation distribution in the structure of titanium-containing ludwigite [Russian], Kristallografiya, 47, 457-459
Girgsdies F, Behrens M (2012) On the structural relations of malachite. I. The rosasite and ludwigite structure families, Acta Crystallographica, B68, 107-117
Bilohuščin V, Uher P, Koděra P, Milovská S, Mikuš T, Bačík P (2017) Evolution of borate minerals from contact metamorphic to hydrothermal stages: Ludwigite-group minerals and szaibélyite from the Vysoká - Zlatno skarn, Slovakia, Mineralogy and Petrology, 111, 643-658
Biryukov Y P, Zinnatullin A L, Levashova I O, Shablinskii A P, Bubnova R S, Vagizov F G, Ugolkov V L, Filatov S K, Pekov I V (2023) Crystal structure refinement, low- and high-temperature X-ray diffraction and Mössbauer spectroscopy study of the oxoborate ludwigite from the Iten'yurginskoe deposit, Acta Crystallographica, B79, S2052520623006455 [link]

REFERENCES for Ludwigite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Tschermak G (1874) Ludwigit, ein neues Mineral aus dem Banate, Mineralogische Mittheilungen, 1874, 59-66 [view file]

Bertaut E F (1950) Structures des boroferrites, Acta Crystallographica, 3, 473-474

Takéuchi Y, Watanabé T, Ito T (1950) The crystal structures of warwickite, ludwigite and pinakiolite, Acta Crystallographica, 3, 98-107

Bovin J O, O'Keefe M, O'Keefe M A (1981) Electron microscopy of oxyborates. I. Defect structures in the minerals pinakiolite, ludwigite, orthopinakiolite, and takéuchiite, Acta Crystallographica, A37, 28-35

Hriljac J A, Brown R D, Cheetham A K, Satek L C (1990) The synthesis and crystal structures of the related series of aluminoborates: Co_2.1Al_0.9BO₅, Ni₂AlBO₅ and Cu₂AlBO, Journal of Solid State Chemistry, 84, 289-298

Norrestam R, Kritikos M, Nielsen K, Sotofte I, Thorup N (1994) Structural characterization of two synthetic Ni-ludwigites, and some semiempirical EHTB calculations on the ludwigite structure type, Journal of Solid State Chemistry, 111, 217-223

Irwin M B, Peterson R C (1999) The crystal structure of ludwigite, The Canadian Mineralogist, 37, 939-943 [view file]

Marincea S (1999) Ludwigite from the type locality, Onca de Fier, Romania: new data and review, The Canadian Mineralogist, 37, 1343-1362 [view file]

Holtstam D (2001) Crystal chemistry of a manganian ludwigite, Neues Jahrbuch für Mineralogie, Monatshefte, 2001, 520-528

Leite C A F, Guimaraes R B, Fernandes J C, Continentino M A, Paschoal C W A, Ayala A P, Guedes I (2001) Temperature-dependent Raman scattering study of Fe₃O₂BO₃ ludwigite, Journal of Raman Spectroscopy, 33, 1-5

Brovkin A A, Rozhdestvenskaya I V, Rykova E A (2002) Cation distribution in the structure of titanium-containing ludwigite, Crystallography Reports, 47, 412-414

Brovkin A A, Rozhdestvenskaya I V, Rykova E A (2002) Cation distribution in the structure of titanium-containing ludwigite [Russian], Kristallografiya, 47, 457-459

Girgsdies F, Behrens M (2012) On the structural relations of malachite. I. The rosasite and ludwigite structure families, Acta Crystallographica, B68, 107-117

Bilohuščin V, Uher P, Koděra P, Milovská S, Mikuš T, Bačík P (2017) Evolution of borate minerals from contact metamorphic to hydrothermal stages: Ludwigite-group minerals and szaibélyite from the Vysoká - Zlatno skarn, Slovakia, Mineralogy and Petrology, 111, 643-658

Biryukov Y P, Zinnatullin A L, Levashova I O, Shablinskii A P, Bubnova R S, Vagizov F G, Ugolkov V L, Filatov S K, Pekov I V (2023) Crystal structure refinement, low- and high-temperature X-ray diffraction and Mössbauer spectroscopy study of the oxoborate ludwigite from the Iten'yurginskoe deposit, Acta Crystallographica, B79, S2052520623006455 [link]