Summary: Based on nearly 1500 published amphibole analyses the maximum possible Al^vi in hornblendes is shown to increase with increase of Al^iv. New analyses of hornblendes from amphibole-corundum rocks, with and without anorthite, are given and after critical examination of the available data it is concluded that the maximum verified Al^vi-rich calciferous amphibole that approaches the closest to hypothetical tschermakite comes from a kyanite-bearing aluminous high-pressure-crystallized schist from Lukmanier, Switzerland. Pure natural edenite or ferroedenite is unknown, but a new analysis of the nearest known natural edenite, from Mysore, India, agrees with the postulated view that extraordinarily low temperatures are needed for edenite-ferroedenite crystallization, much below that possible in magmas and only rarely achieved in metamorphic rocks containing amphiboles. The limit of the approach of igneous hornblendes to edenite-ferroedenite and tremolite-ferroactinolite is outlined.

At least 1100 °C is required for complete expulsion of water from some amphiboles.