Hydrated Copper Oxalate, Moolooite, in Lichens

J. E. Chisholm*, G. C. Jones* and O. W. Purvis
* Departments of Mineralogy, British Museum (Natural History), Cromwell Road, London SW7 5BD
Botany, British Museum (Natural History), Cromwell Road, London SW7 5BD

Abstract: Vivid blue inclusions in white whewellite or weddellite, occurring within the medulla of four lichen species growing on copper-bearing rocks, have been identified as the hydrated copper oxalate, moolooite, CuC2O4. nH2O (n ∼ 0.4–0.7), by infrared spectroscopy and X-ray powder diffraction. The mineral is believed to have been formed by reaction between oxalic acid secreted by the lichen and ground or surface water containing copper.

Keywords: moolooite • lichens • copper oxalate • whewellite • weddellite

Mineralogical Magazine; December 1987 v. 51; no. 363; p. 715-718; DOI: 10.1180/minmag.1987.051.363.12
© 1987, The Mineralogical Society
Mineralogical Society (www.minersoc.org)