Abstract: Volcanic-hosted advanced argillic alteration on Barton Peninsula comprises an assemblage of chalcedonic silica, alunite family minerals, pyrophyllite, pyrite, native sulphur, zunyite and rutile, characteristic of an acid sulphate-type epithermal system. The minerals minamiite, (Na_0.36Ca_0.27K_0.1□_0.27)Al₃(SO₄)₂(OH)₆, and zunyite, Al₁₃Si₅O₂₀(OH,F)₁₈Cl, are reported at this locality, and in Antarctica, for the first time. The WNW-striking, 1 km-long zone of alteration is hosted by early Tertiary andesitic rocks and contained in a 1.5 km-wide depression, rimmed by an arcuate ridge, probably representing a volcanic crater or small caldera structure.

Stability relations of minerals in the advanced argillic alteration zone indicate alteration took place under acidic conditions in the near-surface environment. Mineralogical and textural evidence also suggest alteration occurred in a magmatic hydrothermal system, possibly with a magmatic steam component, rather than in a supergene or steam-heated environment.