R050383 - RRUFF Database: Raman, X-ray, Infrared, and Chemistry

Arsenolite R050383

Name: Arsenolite
RRUFF ID: R050383
Ideal Chemistry: As₂O₃
Locality: Eureka, Nevada, USA
Source: University of Arizona Mineral Museum 3603 [view label]
Owner: RRUFF
Description: Colorless hoppered octahedra
Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis

Mineral Group: [ Arsenolite (4) ]

Quick search: [ All Arsenolite samples (2) ]

CHEMISTRY

RRUFF ID:	R050383.2
Sample Description:	Microprobe Fragment
Measured Chemistry:	As_2.00O₃
Microprobe Data File:	[ Download Excel File ]

RAMAN SPECTRUM

RRUFF ID:

Sample Description:

Unoriented sample

DOWNLOADS:

To download sample data,
please select a specific
orientation angle.

BROAD SCAN WITH SPECTRAL ARTIFACTS

RRUFF ID:

R050383

Wavelength:

Sample Description:

Unoriented sample

Instrument settings:

Thermo Almega XR 532nm @ 100% of 150mW

DOWNLOADS:

	Raman Data (Processed)
	RRUFF File
	Raman Data (RAW)
	RRUFF File

INFRARED SPECTRUM (Attenuated Total Reflectance)

RRUFF ID:

R050383.1

Sample Description:

Powder

Instrument settings:

SensIR Durascope on a Nicolet Magna 860 FTIR

Resolution:

DOWNLOADS:

	Infrared Data (Processed)
	RRUFF File

POWDER DIFFRACTION

RRUFF ID:

R050383.1

Sample Description:

Powder

Cell Refinement Output:

a: 11.0749(3)Å b: 11.0749(3)Å c: 11.0749(3)Å
alpha: 90.° beta: 90.° gamma: 90.° Volume: 1358.4(1)Å³ Crystal System: cubic

File Type Information

Calculated diffraction file.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

DOWNLOADS:

	Cell Refinement Data
	Cell Refinement Output Data
	DIF File
	X-ray Data (XY - Processed)
	RRUFF File
	X-ray Data (XY - RAW)
	RRUFF File

REFERENCES for Arsenolite
American Mineralogist Crystal Structure Database Record: [view record]
Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]
Dana J D (1854) II. Oxyds of elements of the arsenic group. I. Oxyds of arsenic, antimony, etc. Arsenolite, in A System of Mineralogy, Comprising the Most Recent Discoveries, Fourth Edition, Volume II George P. Putnam & Co. New York and London 139-140 [view file]
Bozorth R M (1923) The crystal structures of the cubic forms of arsenious and antimonous oxides, Journal of the American Chemical Society, 45, 1621-1627 [view file]
Beattie I R, Livingston K M S, Ozin G A, Reynolds D J (1970) Single-crystal Raman spectra of arsenolite (As₄O₆) and senarmonite (Sb₄O₆). The gas-phase Raman spectra pf P₄O₆, P₄O₁₀, and As₄O₆, Journal of the Chemical Society A: Inorganic, Physical, Theoretical, 1970, 449-451
Flynn E J, Solin S A, Papatheodorou G N (1976) Vibrational excitations of As₂O₃. II. Crystalline phases, Physical Review B, 13, 1752-1758
Mrose M E, Larson R R, Estep P A (1976) Forbesite — a mixture of cobaltoan annabergite and arsenolite, The Canadian Mineralogist, 14, 414-421 [view file]
Pertlik F (1978) Strukturverfeinerung von kubischem As₂O₃ (arsenolith) mit einkristalldaten, Czechoslovak Journal of Physics, 28, 170-176
Treacy D J, Taylor P C (1981) Nuclear quadrupole resonance in two crystalline forms of As₂O₃, arsenolite and claudetite I, Solid State Communications, 40, 135-138
Grzechnik A (1999) Compressibility and vibrational modes in solid As₄O₆, Journal of Solid State Chemistry, 144, 416-422
Ballirano P, Maras A (2002) Refinement of the crystal structure of arsenolite, As₂O₃, Zeitschrift für Kristallographie, 217, 177-178
Shannon R D, Shannon R C, Medenbach O, Fischer R X (2002) Refractive index and dispersion of fluorides and oxides, Journal of Physical and Chemical Reference Data, 31, 931-970 [view file]
Gilliam S J, Merrow C N, Kirkby S J, Jensen J O, Zeroka D, Banerjee A (2003) Raman spectroscopy of arsenolite: crystalline cubic As₄O₆, Journal of Solid State Chemistry, 173, 54-58
Ballirano P, Maras A (2006) In-situ X-ray transmission powder diffraction study of the kinetics of the light induced alteration of realgar (α-As4S4), European Journal of Mineralogy, 18, 589-599
Soignard E, Amin S A, Mei Q, Benmore C J, Yarger J L (2008) High-pressure behavior of As₂O₃: Amorphous-amorphous and crystalline-amorphous transitions, Physical Review B, 77, 144113-8
Gibbs G V, Wallace A F, Cox D F, Dove P M, Downs R T, Ross N L, Rosso K M (2009) Role of directed van der Waals bonded interactions in the determination of the structures of molecular arsenate solids, Journal of Physical Chemistry A, 113, 736-749 [view file]
Ballirano P (2012) Thermal behavior of realgar As₄S₄, and of arsenolite As₂O₃ and non-stoichiometric As₈S_8+x crystals produced from As₄S₄ melt recrystallization, American Mineralogist, 97, 1320-1329 [view file]

REFERENCES for Arsenolite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Dana J D (1854) II. Oxyds of elements of the arsenic group. I. Oxyds of arsenic, antimony, etc. Arsenolite, in A System of Mineralogy, Comprising the Most Recent Discoveries, Fourth Edition, Volume II George P. Putnam & Co. New York and London 139-140 [view file]

Bozorth R M (1923) The crystal structures of the cubic forms of arsenious and antimonous oxides, Journal of the American Chemical Society, 45, 1621-1627 [view file]

Beattie I R, Livingston K M S, Ozin G A, Reynolds D J (1970) Single-crystal Raman spectra of arsenolite (As₄O₆) and senarmonite (Sb₄O₆). The gas-phase Raman spectra pf P₄O₆, P₄O₁₀, and As₄O₆, Journal of the Chemical Society A: Inorganic, Physical, Theoretical, 1970, 449-451

Flynn E J, Solin S A, Papatheodorou G N (1976) Vibrational excitations of As₂O₃. II. Crystalline phases, Physical Review B, 13, 1752-1758

Mrose M E, Larson R R, Estep P A (1976) Forbesite — a mixture of cobaltoan annabergite and arsenolite, The Canadian Mineralogist, 14, 414-421 [view file]

Pertlik F (1978) Strukturverfeinerung von kubischem As₂O₃ (arsenolith) mit einkristalldaten, Czechoslovak Journal of Physics, 28, 170-176

Treacy D J, Taylor P C (1981) Nuclear quadrupole resonance in two crystalline forms of As₂O₃, arsenolite and claudetite I, Solid State Communications, 40, 135-138

Grzechnik A (1999) Compressibility and vibrational modes in solid As₄O₆, Journal of Solid State Chemistry, 144, 416-422

Ballirano P, Maras A (2002) Refinement of the crystal structure of arsenolite, As₂O₃, Zeitschrift für Kristallographie, 217, 177-178

Shannon R D, Shannon R C, Medenbach O, Fischer R X (2002) Refractive index and dispersion of fluorides and oxides, Journal of Physical and Chemical Reference Data, 31, 931-970 [view file]

Gilliam S J, Merrow C N, Kirkby S J, Jensen J O, Zeroka D, Banerjee A (2003) Raman spectroscopy of arsenolite: crystalline cubic As₄O₆, Journal of Solid State Chemistry, 173, 54-58

Ballirano P, Maras A (2006) In-situ X-ray transmission powder diffraction study of the kinetics of the light induced alteration of realgar (α-As4S4), European Journal of Mineralogy, 18, 589-599

Soignard E, Amin S A, Mei Q, Benmore C J, Yarger J L (2008) High-pressure behavior of As₂O₃: Amorphous-amorphous and crystalline-amorphous transitions, Physical Review B, 77, 144113-8

Gibbs G V, Wallace A F, Cox D F, Dove P M, Downs R T, Ross N L, Rosso K M (2009) Role of directed van der Waals bonded interactions in the determination of the structures of molecular arsenate solids, Journal of Physical Chemistry A, 113, 736-749 [view file]

Ballirano P (2012) Thermal behavior of realgar As₄S₄, and of arsenolite As₂O₃ and non-stoichiometric As₈S_8+x crystals produced from As₄S₄ melt recrystallization, American Mineralogist, 97, 1320-1329 [view file]