Rosasite R050294



Name: Rosasite
RRUFF ID: R050294
Ideal Chemistry: CuZn(CO3)(OH)2
Locality: 79 mine, 4th level, Hayden, Gila County, Arizona, USA
Source: George Godas, John Callahan
Owner: RRUFF
Description: Green botryoidal crust associated with intergrown smithsonite
Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis
Mineral Group: [ malachite (7) ]
Quick search: [ All Rosasite samples (4) ]
CHEMISTRY 
RRUFF ID: R050294.2
Sample Description: Microprobe Fragment
Measured Chemistry: (Cu1.24Zn0.76)Σ=2(CO3)(OH)2
RAMAN SPECTRUM 
RRUFF ID:
Sample Description: Unoriented sample
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BROAD SCAN WITH SPECTRAL ARTIFACTS
RRUFF ID: R050294
Wavelength:
Sample Description: Unoriented sample
Instrument settings: Thermo Almega XR 532nm @ 100% of 150mW
INFRARED SPECTRUM (Attenuated Total Reflectance) 
RRUFF ID: R050294.1
Instrument settings: SensIR Durascope on a Nicolet Magna 860 FTIR
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POWDER DIFFRACTION 
RRUFF ID: R050294.1
Sample Description: Powder, intimately mixed with smithsonite
Cell Refinement Output: a: 12.864(2)Å    b: 9.355(1)Å    c: 3.1589(5)Å
alpha: 90°    beta: 110.04(2)°    gamma: 90°   Volume: 357.15(6)Å3    Crystal System: monoclinic
  File Type Information Close
Calculated diffraction file.

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Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

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REFERENCES for Rosasite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Lovisato D (1908) Rosasite, nuovo minerale della miniera di Rosas (Sulcis, Sardegna), Atti della Reale Accademia dei Lincei, 17, 723-728   [view file]

Strunz H (1959) Tsumeb, seine Erze und Sekundärmineralien, insbesondere der neu aufgeschlossenen zweiten Oxydationszone, Fortschritte der Mineralogie, 37, 87-90

Hawthorne F C, Jambor J L, Bladh K W, Burke E A J, Grice J D, Phillips D, Roberts A C, Schedler R A, Shigley J E (1987) New mineral names, American Mineralogist, 72, 1023-1028   [view file]

Perchiazzi N (2006) Crystal structure determination and Rietveld refinement of rosasite and mcguinnessite, Zeitschrift für Kristallographie Supplement, 23, 505-510

Frost R L, Hales M C, Wain D L (2008) Raman spectroscopy of smithsonite, Journal of Raman Spectroscopy, 39, 108-114

Girgsdies F, Behrens M (2012) On the structural relations of malachite. I. The rosasite and ludwigite structure families, Acta Crystallographica, B68, 107-117

Perchiazzi N, Demitri N, Fehér B, Vignola P (2017) On the crystal-chemistry of rosasite and parádsasvárite, The Canadian Mineralogist, 55, 1027-1040