R060809 - RRUFF Database: Raman, X-ray, Infrared, and Chemistry

Gismondine-Ca R060809

Name: Gismondine-Ca
RRUFF ID: R060809
Ideal Chemistry: Ca₂(Si₄Al₄)O₁₆·8H₂O
Locality: Arensberg, Eifel Mountains, Germany
Source: Michael Scott S101162 [view label]
Owner: RRUFF
Description: Colorless pseudo-octahedral crystals
Status: The identification of this mineral has been confirmed by single-crystal X-ray diffraction.

Mineral Group: [ Gismondine (3) ]

CHEMISTRY

RRUFF ID:	R060809.2
Sample Description:	Microprobe Fragment

RAMAN SPECTRUM

RRUFF ID:

Sample Description:

Unoriented sample

DOWNLOADS:

To download sample data,
please select a specific
orientation angle.

BROAD SCAN WITH SPECTRAL ARTIFACTS

RRUFF ID:

R060809

Wavelength:

Sample Description:

Unoriented sample

Instrument settings:

Thermo Almega XR 532nm @ 100% of 150mW

DOWNLOADS:

	Raman Data (Processed)
	RRUFF File
	Raman Data (RAW)
	RRUFF File

POWDER DIFFRACTION

RRUFF ID:

R060809.9

Sample Description:

Single crystal, powder profile is calculated

Cell Refinement Output:

a: 10.055(3)Å b: 10.667(4)Å c: 9.874(4)Å
alpha: 90° beta: 92.52(2)° gamma: 90° Volume: 1058.0(5)Å³ Crystal System: monoclinic

File Type Information

Calculated diffraction file.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

DOWNLOADS:

	DIF File
	X-ray Data (XY - RAW)
	RRUFF File

REFERENCES for Gismondine-Ca
Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]
von Leonhard K C (1817) Die Zeagonit, ein neues Mineral vom Capo di Bove bei Rom. Beschrieben von Herrn Professor Gismondi, Taschenbuch für die gesammte Mineralogie mit Hinsicht auf die neuesten Entdeckungen, 11, 164-168 [view file]
Fischer K (1963) The crystal structure determination of the zeolite gismondite, CaAl₂Si₂O₈·4H₂O, American Mineralogist, 48, 664-672 [view file]
Baerlocher C, Meier W M (1970) Synthese und kristallstruktur von tetramethylammonium gismondin, Helvetica Chimica Acta, 53, 1285-1293
Vezzalini G, Oberti R (1984) The crystal chemistry of gismondines : the non-existence of K-rich gismondines, Bulletin de Minéralogie, 107, 805-812
Artioli G, Rinaldi R, Kvick Å, Smith J V (1986) Neutron diffraction structure refinement of the zeolite gismondine at 15 K, Zeolites, 6, 361-366
Vezzalini G, Quartieri S, Alberti A (1993) Structural modifications induced by dehydration in the zeolite gismondine, Zeolites, 13, 34-42
Coombs D S, Alberti A, Armbruster T, Artioli G, Colella C, Galli E, Grice J D, Liebau F, Mandarino J A, Minato H, Nickel E H, Passaglia E, Peacor D R, Quartieri S, Rinaldi R, Ross M, Sheppard R A, Tillmanns E, Vezzalini G, (1997) Recommended nomenclature for zeolite minerals: report of the Subcommittee on Zeolites of the International Mineralogical Association, Commission on New Minerals and Mineral Names, The Canadian Mineralogist, 35, 1571-1606 [view file]
Celestian A J, Parise J B, Goodell C, Tripathi A, Hanson J (2004) Time-resolved diffraction studies of ion exchange: K⁺ and Na⁺ exchange into (Al,Ge) gismondine (GIS) Na₂₄Al₂₄Ge₂₄O₉₆·40H₂O and K₈Al₈Ge₈O₃₂·8H₂O, Chemistry of Materials, 16, 2244-2254
Ori S, Quartieri S, Vezzalini G, Dmitriev V (2008) Pressure-induced over-hydration and water ordering in gismondine: a synchrotron powder diffraction study, American Mineralogist, 93, 1393-1403 [view file]
Wadoski-Romeijn E, Armbruster T (2013) Topotactic transformation and dehydration of the zeolite gismondine to a novel Ca feldspar structure, American Mineralogist, 98, 1988-1997
Miyawaki R, Hatert F, Pasero M, Mills S J (2021) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) Newsletter 63, Mineralogical Magazine, 85, 910-915 [view file]
Skrzyńska K, Cametti G, Juroszek R, Schäfer C, Galuskina I (2023) New data on minerals with the GIS framework-type structure: gismondine-Sr from the Bellerberg volcano, Germany, and amicite and Ba-rich gismondine from the Hatrurim Complex, Israel, Mineralogical Magazine, 87, 443-454

REFERENCES for Gismondine-Ca

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

von Leonhard K C (1817) Die Zeagonit, ein neues Mineral vom Capo di Bove bei Rom. Beschrieben von Herrn Professor Gismondi, Taschenbuch für die gesammte Mineralogie mit Hinsicht auf die neuesten Entdeckungen, 11, 164-168 [view file]

Fischer K (1963) The crystal structure determination of the zeolite gismondite, CaAl₂Si₂O₈·4H₂O, American Mineralogist, 48, 664-672 [view file]

Baerlocher C, Meier W M (1970) Synthese und kristallstruktur von tetramethylammonium gismondin, Helvetica Chimica Acta, 53, 1285-1293

Vezzalini G, Oberti R (1984) The crystal chemistry of gismondines : the non-existence of K-rich gismondines, Bulletin de Minéralogie, 107, 805-812

Artioli G, Rinaldi R, Kvick Å, Smith J V (1986) Neutron diffraction structure refinement of the zeolite gismondine at 15 K, Zeolites, 6, 361-366

Vezzalini G, Quartieri S, Alberti A (1993) Structural modifications induced by dehydration in the zeolite gismondine, Zeolites, 13, 34-42

Coombs D S, Alberti A, Armbruster T, Artioli G, Colella C, Galli E, Grice J D, Liebau F, Mandarino J A, Minato H, Nickel E H, Passaglia E, Peacor D R, Quartieri S, Rinaldi R, Ross M, Sheppard R A, Tillmanns E, Vezzalini G, (1997) Recommended nomenclature for zeolite minerals: report of the Subcommittee on Zeolites of the International Mineralogical Association, Commission on New Minerals and Mineral Names, The Canadian Mineralogist, 35, 1571-1606 [view file]

Celestian A J, Parise J B, Goodell C, Tripathi A, Hanson J (2004) Time-resolved diffraction studies of ion exchange: K⁺ and Na⁺ exchange into (Al,Ge) gismondine (GIS) Na₂₄Al₂₄Ge₂₄O₉₆·40H₂O and K₈Al₈Ge₈O₃₂·8H₂O, Chemistry of Materials, 16, 2244-2254

Ori S, Quartieri S, Vezzalini G, Dmitriev V (2008) Pressure-induced over-hydration and water ordering in gismondine: a synchrotron powder diffraction study, American Mineralogist, 93, 1393-1403 [view file]

Wadoski-Romeijn E, Armbruster T (2013) Topotactic transformation and dehydration of the zeolite gismondine to a novel Ca feldspar structure, American Mineralogist, 98, 1988-1997

Miyawaki R, Hatert F, Pasero M, Mills S J (2021) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) Newsletter 63, Mineralogical Magazine, 85, 910-915 [view file]

Skrzyńska K, Cametti G, Juroszek R, Schäfer C, Galuskina I (2023) New data on minerals with the GIS framework-type structure: gismondine-Sr from the Bellerberg volcano, Germany, and amicite and Ba-rich gismondine from the Hatrurim Complex, Israel, Mineralogical Magazine, 87, 443-454