Haüyne R040023

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Record 1 of 5  

Name: Haüyne
RRUFF ID: R040023
Ideal Chemistry: Na3Ca(Si3Al3)O12(SO4)
Locality: Cazadero river, Ovalle, Limarí Province, Coquimbo, Chile
Source: University of Arizona Mineral Museum 6685 [view label]
Owner: RRUFF
Description: Blue fine-grained massive, associated with wollastonite and calcite
Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis
Mineral Groups: [ sodalite (24) ] [ cancrinite-sodalite (37) ]
Quick search: [ All Haüyne samples (5) ]
CHEMISTRY 
RRUFF ID: R040023.2
Sample Description: Microprobe fragment, dark material is hauyne, medium gray is calcite
Measured Chemistry: (Na0.99K0.01)6(Ca0.99Na0.01)2Al6.00Si6.00O24[(SO4)0.67S0.32Cl0.01]2
Microprobe Data File: [ Download Excel File ]
RAMAN SPECTRUM 
RRUFF ID:
Sample Description: Unoriented sample
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BROAD SCAN WITH SPECTRAL ARTIFACTS
RRUFF ID: R040023
Wavelength:
Sample Description: Unoriented sample
Instrument settings: Thermo Almega XR 532nm @ 100% of 150mW
INFRARED SPECTRUM (Attenuated Total Reflectance) 
RRUFF ID: R040023.1
Instrument settings: SensIR Durascope on a Nicolet Magna 860 FTIR
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POWDER DIFFRACTION 
RRUFF ID: R040023.1
Sample Description: Powder
Cell Refinement Output: a: 9.0744(3)Å    b: 9.0744(3)Å    c: 9.0744(3)Å
alpha: 90°    beta: 90°    gamma: 90°   Volume: 747.24(9)Å3    Crystal System: cubic
  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

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REFERENCES for Haüyne

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Bruun-Neergard T C (1807) De la haüyne, nouvelle substance minerale, Journal des Mines, 21, 365-380   [view file]

Bruun-Neergard T C (1807) Ueber den hauyn (la hauyne), eine neue mineralische substanz, Journal of Chemical Physics, 4, 417-429   [view file]

Van Peteghem J K, Burley B J (1963) Studies on solid solution between sodalite, nosean and hauyne, The Canadian Mineralogist, 7, 808-813   [view file]

Leoni L, Mellini M, Merlino S, Orlandi P (1979) Cancrinite-like minerals: new data and crystal chemical considerations, Rendiconti della Società Italiana di Mineralogia e Petrologia, 35, 713-719   [view file]

Hassan I, Grundy H D (1984) The crystal structures of sodalite-group minerals, Acta Crystallographica, B40, 6-13

Hassan I, Grundy H D (1991) The crystal structure of hauyne at 293 and 153 K, The Canadian Mineralogist, 29, 123-130   [view file]

Ballirano P, Maras A, Buseck P R (1996) Crystal chemistry and IR spectroscopy of Cl- and SO4-bearing cancrinite-like minerals, American Mineralogist, 81, 1003-1012   [view file]

Hassan I, Antao S M, Parise J B (2004) Haüyne: phase transition and high-temperature structures obtained from synchrotron radiation and Rietveld refinements, Mineralogical Magazine, 68, 499-513

Nasti V (2009) L'olotipo della haüyna, Il Cercapietre, 2009, issue 1-2 16-43   [view file]

Hettmann K, Wenzel T, Marks M, Markl G (2012) The sulfur speciation in S-bearing minerals: New constraints by a combination of electron microprobe analysis and DFT calculations with special reference to sodalite-group minerals, American Mineralogist, 97, 1653-1661   [view file]

Baudouin C, Parat F (2015) Role of volatiles (S, Cl, H2O) and silica activity on the crystallization of haüyne and nosean in phonolitic magmas (Eifel, Germany and Saghro, Morocco), American Mineralogist, 100, 2308-2322

Balassone G, Bellatreccia F, Ottolini L, Mormone A, Petti C, Ghiara M R, Altomare A, Saviano M, Rizi R, D'Orazio L (2016) Sodalite-group minerals, from the Somma-Vesuvius volcano (Naples, Italy): A combined EPMA, SIMS, and FTIR crystal-chemical study, The Canadian Mineralogist, 54, 583-604

Farsang S, Caracas R, Adachi T B M, Schnyder C, Zajacz Z (2023) S2- and S3- radicals and the S42- polysulfide ion in lazurite, haüyne, and synthetic ultramarine blue revealed by resonance Raman spectroscopy, American Mineralogist, 108, 2234-2243