Hydrox R050512 - RRUFF Database: Raman, X-ray, Infrared, and Chemistry

Hydroxylapatite R050512

Name: Hydroxylapatite
RRUFF ID: R050512
Ideal Chemistry: Ca₅(PO₄)₃OH
Locality: Moneta Island, Mayeguez, Puerto Rico, USA
Source: American Museum of Natural History 15214 [view label]
Owner: RRUFF
Description: Pale pink consolidated powder
Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis

Mineral Group: [ Apatite (56) ]

Quick search: [ All Hydroxylapatite samples (4) ]

CHEMISTRY

RRUFF ID:	R050512.2
Sample Description:	Microprobe Fragment
Measured Chemistry:	Ca_5.00(PO₄)₃((OH)_0.67F_0.33)

RAMAN SPECTRUM

RRUFF ID:

Sample Description:

Unoriented sample

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orientation angle.

BROAD SCAN WITH SPECTRAL ARTIFACTS

RRUFF ID:

R050512

Wavelength:

Sample Description:

Unoriented sample

Instrument settings:

Thermo Almega XR 532nm @ 100% of 150mW

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	Raman Data (Processed)
	RRUFF File
	Raman Data (RAW)
	RRUFF File

INFRARED SPECTRUM (Attenuated Total Reflectance)

RRUFF ID:

R050512.1

Instrument settings:

SensIR Durascope on a Nicolet Magna 860 FTIR

Resolution:

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	Infrared Data (Processed)
	RRUFF File

POWDER DIFFRACTION

RRUFF ID:

R050512.1

Sample Description:

Powder

Cell Refinement Output:

a: 9.4377(6)Å b: 9.4377(6)Å c: 6.8756(6)Å
alpha: 90° beta: 90° gamma: 120° Volume: 530.37(7)Å³ Crystal System: hexagonal

File Type Information

Calculated diffraction file.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

DOWNLOADS:

	Cell Refinement Data
	Cell Refinement Output Data
	DIF File
	X-ray Data (XY - Processed)
	RRUFF File
	X-ray Data (XY - RAW)
	RRUFF File

REFERENCES for Hydroxylapatite
American Mineralogist Crystal Structure Database Record: [view record]
Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]
Damour A A (1856) Sur l'hydro-apatite, espèce minérale, Annales des Mines, 10, 65-68 [view file]
Schaller W T (1912) Mineralogical notes, Series 2. Mineralogy of the French phosphorites, U.S. Geological Survey Bulletin, 509, 89-100 [view file]
Foshag W F (1936) New mineral names, American Mineralogist, 21, 269-272 [view file]
Kay M I, Young R A, Posner A S (1964) Crystal structure of hydroxyapatite, Nature, 204, 1050-1052
Jullmann H, Mosebach R (1966) Zur Synthese, Licht- und Doppelbrechung des Hydroxylapatits, Zeitschrift für Naturforschung B Chemical Science, 21, 493-494 [view file]
Sudarsanan K, Young R A (1969) Significant precision in crystal structural details: Holly Springs hydroxyapatite, Acta Crystallographica, B25, 1534-1543
Dickens B, Brown W E, Kruger G J, Stewart J M (1973) Ca₄(PO₄)₂O, tetracalcium diphosphate monooxide. Crystal structure and relationships to Ca₅(PO₄)₃OH and K₃Na(SO₄)₂, Acta Crystallographica, B29, 2046-2056
Elliot J C, Mackie P E, Young R A (1973) Monoclinic hydroxyapatite, Science, 180, 1055-1057
Fiore S, Lavanio R (1991) Brushite, hydroxylapatite, and taranakite from Apulian caves (southern Italy): New mineralogical data, American Mineralogist, 76, 1722-1727 [view file]
Nasdala L (1992) A Raman study on the so-called “pseudoapatite” from Halsbrücke near Freiberg/Saxony, Neues Jahrbuch für Mineralogie, Abhandlungen, 164, 211-227
Jeanjean J, Vincent U, Fedorov M (1994) Structural modification of calcium hydroxyapatite induced by sorption of cadmium ions, Journal of Solid State Chemistry, 108, 68-72
Kikuchi M, Yamazaki A, Otsuka R, Akao M, Aoki H (1994) Crystal structure of Sr-substituted hydroxyapatite synthesized by hydrothermal method, Journal of Solid State Chemistry, 113, 373-378
Jeanjean J, McGrellis S, Rouchaud J C, Fedorov M, Rondeau A, Perocheau S, Dubis A (1996) A crystallographic study of the sorption of cadmium on calcium hydroxyapatites: incidence of cationic vacancies, Journal of Solid State Chemistry, 126, 195-201
Chakhmouradian A R, Mitchell R H (1999) Niobian ilmenite, hydroxylapatite and sulfatian monazite: alternative hosts for incompatible elements in calcite kimberlite from Internatsional'naya, Yakutia, The Canadian Mineralogist, 37, 1177-1189 [view file]
Ikoma T, Yamazaki A (1999) Preparation and structure refinement of monoclinic hydroxyapatite, Journal of Solid State Chemistry, 144, 272-276
Fleet M E, Liu X (2000) Site preference of rare earth elements in hydroxyapatite [Ca₁₀(PO₄)₆(OH)₂], Journal of Solid State Chemistry, 149, 391-398
Ivanova T I, Frank-Kamenetskaya O V, Kol'tsov A B, Ugolkov V L (2001) Crystal structure of calcium-deficient carbonated hydroxyapatite. thermal decomposition, Journal of Solid State Chemistry, 160, 340-349
Takagi S, Mathew M (2001) Structures of biological minerals in dental research, Journal of Research of the National Bureau of Standards, 106, 1035-1044 [view file]
Wilson R M, Elliott J C, Dowker S E P (2003) Formate incorporation in the structure of Ca–deficient apatite: Rietveld structure refinement, Journal of Solid State Chemistry, 174, 132-140
Roth P (2007) Hydroxylapatite, in Minerals first discovered in Switzerland and minerals named after Swiss individuals Kristallografik Verlag Achberg Germany 86-87
Burke E A J (2008) Tidying up mineral names: an IMA-CNMNC scheme for suffixes, hyphens and diacritical marks, The Mineralogical Record, 39, 131-135 [view file]
Oxmann J F, Pham Q H, Lara R J (2008) Quantification of individual phosphorus species in sediment: a sequential conversion and extraction method, European Journal of Soil Science, 59, 1177-1190 [view file]
Lee Y J, Stephens P W, Tang Y, Li W, Phillips B L, Parise J B, Reeder R J (2009) Arsenate substitution in hydroxylapatite: Structural characterization of the Ca₅(P_xAs_1-xO₄)₃OH solid solution, American Mineralogist, 94, 666-675 [view file]
Pasero M, Kampf A R, Ferraris C, Pekov I V, Rakovan J R, White T J (2010) Nomenclature of the apatite supergroup minerals, European Journal of Mineralogy, 22, 163-179 [view file]
Biagioni C, Pasero M (2013) The crystal structure of johnbaumite, Ca₅(AsO₄)₃OH, the arsenate analogue of hydroxylapatite, American Mineralogist, 98, 1580-1584
Ulian G, Valdrè G, Corno M, Ugliengo P (2013) The vibrational features of hydroxylapatite and type A carbonated apatite: A first principle contribution, American Mineralogist, 98, 752-759
Hovis G L, McCubbin F M, Nekvasil H, Ustunisik G, Woerner W R, Lindsley D H (2014) A novel technique for fluorapatite synthesis and the thermodynamic mixing behavior of F-OH apatite crystalline solutions, American Mineralogist, 99, 890-897
Hovis G L, Scott B T, Altomare C M, Leaman A R, Morris M D, Tomaino G P, McCubbin F M (2014) Thermal expansion of fluorapatite-hydroxylapatite crystalline solutions, American Mineralogist, 99, 2171-2175
Hughes J M (2015) The many facets of apatite, American Mineralogist, 100, 1033-1039
Banno Y, Miyawaki R, Momma K, Bunno M (2016) A CO₃-bearing member of the hydroxylapatite-hydroxylellestadite series from Tadano, Fukushima Prefecture, Japan: CO₃-SO₄ substitution in the apatite-ellestadite series, Mineralogical Magazine, 80, 363-370
Hughes J M, Harlov D, Kelly S R, Rakovan J, Wilke M (2016) Solid solution in the apatite OH-Cl binary system: Compositional dependence of solid-solution mechanisms in calcium phosphate apatites along the Cl-OH binary, American Mineralogist, 101, 1783-1791
Antonakos A, Liarokapis E, Kyriacou A, Leventouri T (2017) Raman and IR studies of the effect of Fe substitution in hydroxyapatites and deuterated hydroxyapatite, American Mineralogist, 102, 85-91
Hughes J M, Harlov D, Rakovan J F (2018) Structural variations along the apatite F-OH join, American Mineralogist, 103, 1981-1987
Fau A, Beyssac O, Gauthier M, Panczer G, Gasnault O, Meslin P Y, Bernard S, Maurice S, Forni O, Boulliard J C, Bosc F, Drouet C (2022) Time-resolved Raman and luminescence spectroscopy of synthetic REE-doped hydroxylapatites and natural apatites, American Mineralogist, 107, 1341-1352

REFERENCES for Hydroxylapatite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Damour A A (1856) Sur l'hydro-apatite, espèce minérale, Annales des Mines, 10, 65-68 [view file]

Schaller W T (1912) Mineralogical notes, Series 2. Mineralogy of the French phosphorites, U.S. Geological Survey Bulletin, 509, 89-100 [view file]

Foshag W F (1936) New mineral names, American Mineralogist, 21, 269-272 [view file]

Kay M I, Young R A, Posner A S (1964) Crystal structure of hydroxyapatite, Nature, 204, 1050-1052

Jullmann H, Mosebach R (1966) Zur Synthese, Licht- und Doppelbrechung des Hydroxylapatits, Zeitschrift für Naturforschung B Chemical Science, 21, 493-494 [view file]

Sudarsanan K, Young R A (1969) Significant precision in crystal structural details: Holly Springs hydroxyapatite, Acta Crystallographica, B25, 1534-1543

Dickens B, Brown W E, Kruger G J, Stewart J M (1973) Ca₄(PO₄)₂O, tetracalcium diphosphate monooxide. Crystal structure and relationships to Ca₅(PO₄)₃OH and K₃Na(SO₄)₂, Acta Crystallographica, B29, 2046-2056

Elliot J C, Mackie P E, Young R A (1973) Monoclinic hydroxyapatite, Science, 180, 1055-1057

Fiore S, Lavanio R (1991) Brushite, hydroxylapatite, and taranakite from Apulian caves (southern Italy): New mineralogical data, American Mineralogist, 76, 1722-1727 [view file]

Nasdala L (1992) A Raman study on the so-called “pseudoapatite” from Halsbrücke near Freiberg/Saxony, Neues Jahrbuch für Mineralogie, Abhandlungen, 164, 211-227

Jeanjean J, Vincent U, Fedorov M (1994) Structural modification of calcium hydroxyapatite induced by sorption of cadmium ions, Journal of Solid State Chemistry, 108, 68-72

Kikuchi M, Yamazaki A, Otsuka R, Akao M, Aoki H (1994) Crystal structure of Sr-substituted hydroxyapatite synthesized by hydrothermal method, Journal of Solid State Chemistry, 113, 373-378

Jeanjean J, McGrellis S, Rouchaud J C, Fedorov M, Rondeau A, Perocheau S, Dubis A (1996) A crystallographic study of the sorption of cadmium on calcium hydroxyapatites: incidence of cationic vacancies, Journal of Solid State Chemistry, 126, 195-201

Chakhmouradian A R, Mitchell R H (1999) Niobian ilmenite, hydroxylapatite and sulfatian monazite: alternative hosts for incompatible elements in calcite kimberlite from Internatsional'naya, Yakutia, The Canadian Mineralogist, 37, 1177-1189 [view file]

Ikoma T, Yamazaki A (1999) Preparation and structure refinement of monoclinic hydroxyapatite, Journal of Solid State Chemistry, 144, 272-276

Fleet M E, Liu X (2000) Site preference of rare earth elements in hydroxyapatite [Ca₁₀(PO₄)₆(OH)₂], Journal of Solid State Chemistry, 149, 391-398

Ivanova T I, Frank-Kamenetskaya O V, Kol'tsov A B, Ugolkov V L (2001) Crystal structure of calcium-deficient carbonated hydroxyapatite. thermal decomposition, Journal of Solid State Chemistry, 160, 340-349

Takagi S, Mathew M (2001) Structures of biological minerals in dental research, Journal of Research of the National Bureau of Standards, 106, 1035-1044 [view file]

Wilson R M, Elliott J C, Dowker S E P (2003) Formate incorporation in the structure of Ca–deficient apatite: Rietveld structure refinement, Journal of Solid State Chemistry, 174, 132-140

Roth P (2007) Hydroxylapatite, in Minerals first discovered in Switzerland and minerals named after Swiss individuals Kristallografik Verlag Achberg Germany 86-87

Burke E A J (2008) Tidying up mineral names: an IMA-CNMNC scheme for suffixes, hyphens and diacritical marks, The Mineralogical Record, 39, 131-135 [view file]

Oxmann J F, Pham Q H, Lara R J (2008) Quantification of individual phosphorus species in sediment: a sequential conversion and extraction method, European Journal of Soil Science, 59, 1177-1190 [view file]

Lee Y J, Stephens P W, Tang Y, Li W, Phillips B L, Parise J B, Reeder R J (2009) Arsenate substitution in hydroxylapatite: Structural characterization of the Ca₅(P_xAs_1-xO₄)₃OH solid solution, American Mineralogist, 94, 666-675 [view file]

Pasero M, Kampf A R, Ferraris C, Pekov I V, Rakovan J R, White T J (2010) Nomenclature of the apatite supergroup minerals, European Journal of Mineralogy, 22, 163-179 [view file]

Biagioni C, Pasero M (2013) The crystal structure of johnbaumite, Ca₅(AsO₄)₃OH, the arsenate analogue of hydroxylapatite, American Mineralogist, 98, 1580-1584

Ulian G, Valdrè G, Corno M, Ugliengo P (2013) The vibrational features of hydroxylapatite and type A carbonated apatite: A first principle contribution, American Mineralogist, 98, 752-759

Hovis G L, McCubbin F M, Nekvasil H, Ustunisik G, Woerner W R, Lindsley D H (2014) A novel technique for fluorapatite synthesis and the thermodynamic mixing behavior of F-OH apatite crystalline solutions, American Mineralogist, 99, 890-897

Hovis G L, Scott B T, Altomare C M, Leaman A R, Morris M D, Tomaino G P, McCubbin F M (2014) Thermal expansion of fluorapatite-hydroxylapatite crystalline solutions, American Mineralogist, 99, 2171-2175

Hughes J M (2015) The many facets of apatite, American Mineralogist, 100, 1033-1039

Banno Y, Miyawaki R, Momma K, Bunno M (2016) A CO₃-bearing member of the hydroxylapatite-hydroxylellestadite series from Tadano, Fukushima Prefecture, Japan: CO₃-SO₄ substitution in the apatite-ellestadite series, Mineralogical Magazine, 80, 363-370

Hughes J M, Harlov D, Kelly S R, Rakovan J, Wilke M (2016) Solid solution in the apatite OH-Cl binary system: Compositional dependence of solid-solution mechanisms in calcium phosphate apatites along the Cl-OH binary, American Mineralogist, 101, 1783-1791

Antonakos A, Liarokapis E, Kyriacou A, Leventouri T (2017) Raman and IR studies of the effect of Fe substitution in hydroxyapatites and deuterated hydroxyapatite, American Mineralogist, 102, 85-91

Hughes J M, Harlov D, Rakovan J F (2018) Structural variations along the apatite F-OH join, American Mineralogist, 103, 1981-1987

Fau A, Beyssac O, Gauthier M, Panczer G, Gasnault O, Meslin P Y, Bernard S, Maurice S, Forni O, Boulliard J C, Bosc F, Drouet C (2022) Time-resolved Raman and luminescence spectroscopy of synthetic REE-doped hydroxylapatites and natural apatites, American Mineralogist, 107, 1341-1352