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Name: Arsenolite RRUFF ID: R050383 Ideal Chemistry: As2O3 Locality: Eureka, Nevada, USA Source: University of Arizona Mineral Museum 3603 [view label] Owner: RRUFF Description: Colorless hoppered octahedra Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis |
Mineral Group: [ Arsenolite (4) ] | ||
Quick search: [ All Arsenolite samples (2) ] |
CHEMISTRY | ||||||||||
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RAMAN SPECTRUM | ||||||||||||
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BROAD SCAN WITH SPECTRAL ARTIFACTS | ||||||||||||
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INFRARED SPECTRUM (Attenuated Total Reflectance) | |||||||||||||||
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POWDER DIFFRACTION | ||||||||
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RRUFF ID: | R050383.1 | |||||||
Sample Description: | Powder | |||||||
Cell Refinement Output: |
a: 11.0749(3)Å b: 11.0749(3)Å c: 11.0749(3)Å alpha: 90.° beta: 90.° gamma: 90.° Volume: 1358.4(1)Å3 Crystal System: cubic |
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REFERENCES for Arsenolite | |
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American Mineralogist Crystal Structure Database Record: [view record] |
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Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file] |
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Dana J D (1854) II. Oxyds of elements of the arsenic group. I. Oxyds of arsenic, antimony, etc. Arsenolite, in A System of Mineralogy, Comprising the Most Recent Discoveries, Fourth Edition, Volume II George P. Putnam & Co. New York and London 139-140 [view file] |
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Bozorth R M (1923) The crystal structures of the cubic forms of arsenious and antimonous oxides, Journal of the American Chemical Society, 45, 1621-1627 [view file] |
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Beattie I R, Livingston K M S, Ozin G A, Reynolds D J (1970) Single-crystal Raman spectra of arsenolite (As4O6) and senarmonite (Sb4O6). The gas-phase Raman spectra pf P4O6, P4O10, and As4O6, Journal of the Chemical Society A: Inorganic, Physical, Theoretical, 1970, 449-451 |
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Flynn E J, Solin S A, Papatheodorou G N (1976) Vibrational excitations of As2O3. II. Crystalline phases, Physical Review B, 13, 1752-1758 |
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Mrose M E, Larson R R, Estep P A (1976) Forbesite a mixture of cobaltoan annabergite and arsenolite, The Canadian Mineralogist, 14, 414-421 [view file] |
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Pertlik F (1978) Strukturverfeinerung von kubischem As2O3 (arsenolith) mit einkristalldaten, Czechoslovak Journal of Physics, 28, 170-176 |
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Treacy D J, Taylor P C (1981) Nuclear quadrupole resonance in two crystalline forms of As2O3, arsenolite and claudetite I, Solid State Communications, 40, 135-138 |
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Grzechnik A (1999) Compressibility and vibrational modes in solid As4O6, Journal of Solid State Chemistry, 144, 416-422 |
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Ballirano P, Maras A (2002) Refinement of the crystal structure of arsenolite, As2O3, Zeitschrift für Kristallographie, 217, 177-178 |
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Shannon R D, Shannon R C, Medenbach O, Fischer R X (2002) Refractive index and dispersion of fluorides and oxides, Journal of Physical and Chemical Reference Data, 31, 931-970 [view file] |
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Gilliam S J, Merrow C N, Kirkby S J, Jensen J O, Zeroka D, Banerjee A (2003) Raman spectroscopy of arsenolite: crystalline cubic As4O6, Journal of Solid State Chemistry, 173, 54-58 |
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Ballirano P, Maras A (2006) In-situ X-ray transmission powder diffraction study of the kinetics of the light induced alteration of realgar (α-As4S4), European Journal of Mineralogy, 18, 589-599 |
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Soignard E, Amin S A, Mei Q, Benmore C J, Yarger J L (2008) High-pressure behavior of As2O3: Amorphous-amorphous and crystalline-amorphous transitions, Physical Review B, 77, 144113-8 |
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Gibbs G V, Wallace A F, Cox D F, Dove P M, Downs R T, Ross N L, Rosso K M (2009) Role of directed van der Waals bonded interactions in the determination of the structures of molecular arsenate solids, Journal of Physical Chemistry A, 113, 736-749 [view file] |
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Ballirano P (2012) Thermal behavior of realgar As4S4, and of arsenolite As2O3 and non-stoichiometric As8S8+x crystals produced from As4S4 melt recrystallization, American Mineralogist, 97, 1320-1329 [view file] |
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