Important Update News
The RRUFF Project is being updated to improve its interface and content. The beta version of the update is accessible to the public at RRUFF.net. New data is only being added to the beta site. Please note that it is in development, and some components are not functional. Existing RRUFF.info links will resolve to the new site after RRUFF.net is officially released.
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Name: Piypite RRUFF ID: R130048 Ideal Chemistry: K4Cu4O2(SO4)4·(Na,Cu)Cl Locality: Second scoria cone, Northern Breakthrough (North Breach), Great Fissure (Main Fracture) eruption, Tolbachik volcano, Kamchatka Oblast', Far-Eastern Region, Russia Source: Don Doell [view label] Owner: RRUFF Description: Sprays of bright green acicular crystals Status: The identification of this mineral has been confirmed by single-crystal X-ray diffraction. |
RAMAN SPECTRUM | ||||||||||||
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BROAD SCAN WITH SPECTRAL ARTIFACTS | ||||||||||||
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POWDER DIFFRACTION | |||||||
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RRUFF ID: | R130048.9 | ||||||
Sample Description: | Single crystal, powder profile is calculated | ||||||
Cell Refinement Output: |
a: 13.599(6)Å b: 13.599(6)Å c: 4.995(2)Å alpha: 90° beta: 90° gamma: 90° Volume: 923.8(4)Å3 Crystal System: tetragonal |
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REFERENCES for Piypite | |
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American Mineralogist Crystal Structure Database Record: [view record] |
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Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file] |
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Effenberger H, Zemann J (1984) The crystal structure of caratiite, Mineralogical Magazine, 48, 541-546 [view file] |
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Vergasova L P, Filatov S K, Serafimova E K, Starova G L (1984) Piypite K2Cu2O(SO4)2 - a new mineral of volcanic sublimates, Doklady Akademii Nauk SSSR, 275, 714-717 [view file] |
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Dunn P J, Gobel V, Grice J D, Puziewicz J, Shigley J E, Vanko D A, Zilczer J (1985) New mineral names, American Mineralogist, 70, 436-441 [view file] |
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Filatov S K, Vergasova L P (1989) Discrediting of caratiite and priority for piypite, Zapiski Vsesoyuznogo Mineralogicheskogo Obshchestva, 118, issue 3 88-90 [view file] |
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Kahlenberg V, Piotrowski A, Giester G (2000) Crystal structure of Na4[Cu4O2(SO4)4]·MeCl (Me: Na, Cu, ◻) the synthetic Na-analogue of piypite (caratiite), Mineralogical Magazine, 64, 1099-1108 [view file] |
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Shablinskii A P, Filatov S K, Biryukov Y P, Yuriev A A, Vergasova L P (2023) Thermal expansion of fedotovite K2Cu3O(SO4)3 and piypite K4Cu4O(SO4)4·(Na,Cu)Cl, Glass Physics and Chemistry, 49, 386-393 |
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