Perovskite R050456

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Record 1 of 6  

Name: Perovskite
RRUFF ID: R050456
Ideal Chemistry: CaTiO3
Locality: Magnet Cove, Arkansas, USA
Source: University of Arizona Mineral Museum 2370 [view label]
Owner: RRUFF
Description: Groups of black cubo-octahedral crystals
Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis
Mineral Group: [ Perovskite (44) ]
Quick search: [ All Perovskite samples (6) ]
RRUFF ID: R050456.2
Sample Description: Microprobe Fragment
Measured Chemistry: darker phase: (Ca0.82Fe2+0.09Na0.07Ce0.01La0.01)Σ=1(Ti0.95Nb5+0.05)Σ=1O3 ; gray phase: (Ca0.89Fe2+0.05Na0.04Ce0.01La0.01)Σ=1(Ti0.98Nb5+0.02)Σ=1O3
Sample Description: Unoriented sample

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RRUFF ID: R050456
Sample Description: Unoriented sample
Instrument settings: Thermo Almega XR 532nm @ 100% of 150mW
INFRARED SPECTRUM (Attenuated Total Reflectance) 
RRUFF ID: R050456.1
Sample Description: Powder
Instrument settings: SensIR Durascope on a Nicolet Magna 860 FTIR
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RRUFF ID: R050456.1
Sample Description: Powder
Cell Refinement Output: a: 5.3980(2)Å    b: 5.4637(4)Å    c: 7.6711(8)Å
alpha: 90°    beta: 90°    gamma: 90°   Volume: 226.24(2)Å3    Crystal System: orthorhombic
  File Type Information Close
Calculated diffraction file.

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Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

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REFERENCES for Perovskite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Rose G (1839) Beschreibung einiger neuen Mineralien des Urals, Annalen der Physik und Chemie, 48, 551-573   [view file]

Náray-Szabó I (1942) A perovskit (CaTiO3) szerkezete, Matematikai és Természettudományi Értesitö, 61, 913-925

Náray-Szabó S (1943) Der strukturtyp des perowskits (CaTiO3), Naturwissenschaften, 31, 202-203

Kay H F, Bailey P C (1957) Structures and properties of CaTiO3, Acta Crystallographica, 10, 219-226

Nickel E H, McAdam R C (1963) Niobian perovskite from Oka, Quebec; a new classification for minerals of the perovskite group, The Canadian Mineralogist, 7, 683-697   [view file]

Fleischer M (1964) New mineral names, American Mineralogist, 49, 816-821   [view file]

Muir I J, Metson J B, Bancroft G M (1984) 57Fe Mössbauer spectra of perovskite and titanite, The Canadian Mineralogist, 22, 689-694   [view file]

Devi P S, Rao M S (1992) Preparation, structure, and properties of strontium-doped lanthanum chromites: La1-xSrxCrO3, Journal of Solid State Chemistry, 98, 237-244

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Genouel R, Michel C, Nguyen N, Studer F, Hervieu M, Raveau B (1995) On the cubic perovskites La0.2Sr0.8Cu0.4M0.6O3-y (M=Co,Fe), Journal of Solid State Chemistry, 119, 260-270

Leinenweber K, Parise K (1995) High-pressure synthesis and crystal structure of CaFeTi2O6, a new perovskite structure type, Journal of Solid State Chemistry, 114, 277-281

Beran A, Libowitzky E, Armbruster T (1996) A single-crystal infrared spectroscopic and X-ray-diffraction study of untwinned San Benito perovskite containing OH groups, The Canadian Mineralogist, 34, 803-809   [view file]

Taguchi H, Sonoda M, Nagao M, Kido H (1996) Role of tetravalent ion in metal-insulator transition in (La0.1Ca0.9)(Mn1-xTix)O3, Journal of Solid State Chemistry, 126, 235-241

Chakhmouradian A R, Mitchell R H (1998) A structural study of the perovskite series CaTi1-2xFexNbxO3, Journal of Solid State Chemistry, 138, 272-277

Mitchell R H, Chakhmouradian A R (1998) Instability of perovskite in a CO2-rich environment: examples from carbonatite and kimberlite, The Canadian Mineralogist, 36, 939-952   [view file]

Zhao Y (1998) Crystal chemistry and phase transitions of perovskite in p-t-x space: data for (KxNa1-x)MgF3 perovskites, Journal of Solid State Chemistry, 141, 121-132

Joswig W, Stachel T, Harris J W, Baur W H, Brey G P (1999) New Ca-silicate inclusions in diamonds - tracers from the lower mantle, Earth and Planetary Science Letters, 173, 1-6

Mitchell R H, Chakhmouradian A R (1999) Solid solubility in the system NaLREETi2O6 - ThTi2O6 (LREE, light rare-earth elements): experimental and analytical data, Physics and Chemistry of Minerals, 26, 396-405

Mitchell R H, Chakhmouradian A R (1999) Sr-bearing perovskite and loparite from lamproite and agpaitic nepheline syenite pegmatites, The Canadian Mineralogist, 37, 99-112   [view file]

Haines J, Rouquette J, Bornand V, Pintard M, Papet P, Gorelli F A (2003) Raman scattering studies at high pressure and low tempurature: technique and application to the piezoelectric material PbZr0.52Ti0.48O3, Journal of Raman Spectroscopy, 34, 519-523

Kojitani H, Katsura T, Akaogi M (2007) Aluminum substitution mechanisms in perovskite-type MgSiO3: an investigation by Rietveld analysis, Physics and Chemistry of Minerals, 34, 257-267

Knight K S (2009) Parameterization of the crystal structures of centerosymmetric zone-boundary-tilted perovskites: An analysis in terms of symmetry-adapted basis-vectors of the cubic aristotype phase, The Canadian Mineralogist, 47, 381-400   [view file]

Kleppe A K, Welch M D, Crichton W A, Jephcoat A P (2012) Phase transitions in hydroxide perovskites: a Raman spectroscopic study of stottite, FeGe(OH)6, to 21 GPa, Mineralogical Magazine, 76, 949-962   [view file]

Nakatsuka A, Kuribayashi S, Nakayama N, Fukui H, Arima H, Yoneda A, Yoshiasa A (2015) Temperature dependence of crystal structure of CaGeO3 high-pressure perovskite phase and experimental determination of its Debye temperatures studied by low- and high-temperature single-crystal X-ray diffraction, American Mineralogist, 100, 1190-1202

Crichton W A, Bernal F L, Guignard J, Hanfland M, Margadonna S (2016) Observation of Sb2S3-type post-post-perovskite in NaFeF3. Implications for ABX3 and A2X3 systems at ultrahigh pressure, Mineralogical Magazine, 80, 659-674

Feng D, Shivaramaiah R, Navrotsky A (2016) Rare-earth perovskites along the CaTiO3-Na0.5La0.5TiO3 join: Phase transitions, formation enthalpies, and implications for loparite minerals, American Mineralogist, 101, 2051-2056

Mitchell R H, Welch M D, Chakhmouradian A R (2017) Nomenclature of the perovskite supergroup: A hierarchical system of classification based on crystal structure and composition, Mineralogical Magazine, 81, 411-461   [view file]

Duffy T S (2018) Single-crystal elastic properties of minerals and related materials with cubic symmetry, American Mineralogist, 103, 977-988

Tschauner O (2019) High-pressure minerals, American Mineralogist, 104, 1701-1731