Mikenewite Yang H, Jenkins R A, McGlasson J A, Gibbs R B, Downs R T Mineralogical Magazine 87 (2023) 534-541 Mikenewite, the natural analogue of synthetic a-Mn2+(S4+O3)*3H2O, a new sulfite mineral from the Ojuela mine, Mapimí, Mexico Locality: Ojuela mine, Mapimí, Mexico _database_code_amcsd 0021221 CELL PARAMETERS: 6.6390 8.8895 8.7900 90.000 96.095 90.000 SPACE GROUP: P2_1/n ATOM X Y Z OCCUPANCY ISO(B) Mn 0.43086 0.24689 0.64354 0.904 1.014 Zn 0.43086 0.24689 0.64354 0.096 1.014 S 0.67451 0.57024 0.67378 1.000 1.026 O 0.54450 0.69750 0.59497 1.000 1.500 O 0.77740 0.64257 0.81998 1.000 1.634 O 0.52070 0.46359 0.73310 1.000 1.437 O 0.11068 0.34728 0.64347 1.000 1.500 O 0.26410 0.04567 0.57326 1.000 2.124 O 0.36377 0.16726 0.87396 1.000 1.508 H 0.05800 0.32600 0.70000 1.000 3.948 H 0.11300 0.45500 0.64600 1.000 3.948 H 0.25500 0.01000 0.49300 1.000 3.948 H 0.16500 0.02500 0.62200 1.000 3.948 H 0.24600 0.17500 0.89500 1.000 3.948 H 0.45300 0.17800 0.95600 1.000 3.948 X-RAY WAVELENGTH: 1.541838 BOUNDS ON TWO THETA: 0.0 90.0 LIMITS IMPOSED ON THE INDICES ARE: +/- 6 +/- 8 +/- 8 MAX. ABS. INTENSITY / VOLUME**2: 6.434908972 The INTENSITY cut off value is 0.01 2-THETA INTENSITY D-SPACING H K L 14.21 13.47 6.2324 0 1 1 15.94 42.78 5.5593 -1 0 1 16.73 16.30 5.2999 1 1 0 17.68 36.29 5.0178 1 0 1 18.83 100.00 4.7135 -1 1 1 19.98 22.78 4.4447 0 2 0 20.32 38.41 4.3702 0 0 2 20.32 2.79 4.3697 1 1 1 22.44 44.90 3.9619 0 2 1 22.67 45.49 3.9219 0 1 2 24.14 19.80 3.6869 1 2 0 25.28 0.27 3.5223 -1 1 2 25.66 0.31 3.4716 -1 2 1 26.80 65.75 3.3271 1 2 1 27.01 1.89 3.3007 2 0 0 27.54 19.98 3.2389 1 1 2 28.65 0.46 3.1162 0 2 2 28.85 48.68 3.0943 2 1 0 29.65 43.57 3.0128 -2 1 1 30.79 34.58 2.9042 -1 2 2 31.62 5.48 2.8297 2 1 1 31.89 11.92 2.8063 0 3 1 32.20 1.35 2.7796 -2 0 2 32.24 49.81 2.7765 -1 0 3 32.34 19.74 2.7685 0 1 3 32.69 0.26 2.7391 1 2 2 33.14 10.28 2.7033 1 3 0 33.79 3.01 2.6530 -2 1 2 33.82 1.83 2.6503 -1 1 3 33.83 29.32 2.6500 2 2 0 34.29 9.43 2.6149 -1 3 1 34.52 21.03 2.5982 -2 2 1 34.96 0.14 2.5666 1 0 3 35.17 17.17 2.5515 1 3 1 35.79 4.38 2.5089 2 0 2 36.25 3.45 2.4780 2 2 1 36.44 6.58 2.4659 1 1 3 36.64 17.44 2.4525 0 3 2 36.89 3.84 2.4366 0 2 3 37.24 5.81 2.4146 2 1 2 38.19 3.39 2.3567 -2 2 2 38.22 4.26 2.3548 -1 2 3 38.38 2.21 2.3451 -1 3 2 39.97 23.37 2.2556 1 3 2 40.35 1.00 2.2351 -2 1 3 40.59 5.74 2.2227 1 2 3 40.59 3.70 2.2224 0 4 0 40.93 4.72 2.2050 2 3 0 41.23 5.17 2.1897 -3 0 1 41.32 22.00 2.1851 0 0 4 41.32 11.20 2.1848 2 2 2 41.52 1.84 2.1749 -2 3 1 41.95 0.01 2.1538 0 4 1 42.31 0.19 2.1360 3 1 0 42.52 14.38 2.1261 -3 1 1 42.61 6.65 2.1219 0 1 4 42.94 0.33 2.1062 1 4 0 43.01 0.47 2.1029 2 3 1 43.43 1.43 2.0837 -1 1 4 43.46 9.92 2.0822 3 0 1 43.57 0.03 2.0775 0 3 3 43.87 0.97 2.0636 -1 4 1 44.20 3.24 2.0492 -2 2 3 44.59 18.18 2.0320 1 4 1 44.70 3.70 2.0273 3 1 1 44.70 2.42 2.0273 -2 3 2 44.73 1.70 2.0261 -1 3 3 44.80 0.01 2.0231 2 1 3 45.29 0.48 2.0022 -3 1 2 46.22 1.86 1.9642 -3 2 1 46.27 0.92 1.9620 1 1 4 46.30 17.75 1.9609 0 2 4 46.83 1.71 1.9400 1 3 3 47.07 0.03 1.9306 -1 2 4 47.27 0.50 1.9230 -1 4 2 47.39 1.50 1.9182 -2 0 4 47.48 1.92 1.9147 2 3 2 48.27 20.25 1.8856 3 2 1 48.36 0.27 1.8821 2 2 3 48.55 16.99 1.8750 -2 1 4 48.62 1.61 1.8727 1 4 2 48.82 3.16 1.8653 -3 2 2 49.17 0.15 1.8531 -3 0 3 49.38 0.71 1.8455 3 1 2 49.44 8.27 1.8435 2 4 0 49.75 0.83 1.8327 1 2 4 49.95 2.92 1.8258 -2 4 1 50.08 0.28 1.8215 -2 3 3 50.30 14.31 1.8141 -3 1 3 51.25 2.31 1.7826 2 4 1 51.75 1.55 1.7666 3 3 0 51.92 0.63 1.7612 -2 2 4 51.92 1.00 1.7610 -3 3 1 52.00 7.40 1.7586 0 3 4 52.53 0.07 1.7422 0 5 1 52.71 0.85 1.7367 -1 3 4 52.71 0.01 1.7366 3 2 2 52.73 0.05 1.7360 -1 0 5 52.74 17.99 1.7358 -2 4 2 52.76 7.73 1.7350 -1 4 3 53.42 0.58 1.7152 0 1 5 53.58 6.98 1.7104 -3 2 3 53.71 0.90 1.7067 2 1 4 53.80 4.59 1.7039 -1 1 5 53.81 9.37 1.7036 3 3 1 53.90 3.16 1.7011 2 3 3 54.16 14.68 1.6934 -1 5 1 54.33 0.15 1.6886 -3 3 2 54.63 4.56 1.6801 1 4 3 54.89 0.18 1.6726 3 0 3 55.19 0.25 1.6644 1 3 4 55.22 2.29 1.6636 2 4 2 55.69 0.02 1.6504 4 0 0 55.82 2.44 1.6468 0 5 2 55.94 4.95 1.6437 3 1 3 56.57 0.78 1.6268 0 2 5 56.60 1.82 1.6261 -4 1 1 56.73 4.26 1.6226 4 1 0 56.85 2.17 1.6195 1 1 5 56.85 14.05 1.6195 2 2 4 56.94 0.56 1.6171 -1 2 5 57.10 0.04 1.6131 -1 5 2 57.11 0.01 1.6128 -3 1 4 57.21 1.55 1.6102 -2 3 4 57.56 0.27 1.6013 -2 4 3 57.56 3.18 1.6012 -4 0 2 57.95 0.05 1.5914 3 3 2 57.95 1.56 1.5913 -2 1 5 58.28 0.35 1.5831 1 5 2 58.58 0.02 1.5758 -4 1 2 58.77 1.52 1.5712 -3 3 3 58.97 0.24 1.5663 4 1 1 59.01 0.15 1.5654 3 2 3 59.01 6.35 1.5653 2 5 0 59.24 0.07 1.5598 -3 4 1 59.31 1.02 1.5581 0 4 4 59.47 0.31 1.5544 -2 5 1 59.64 0.32 1.5502 -4 2 1 59.77 0.91 1.5472 4 2 0 59.89 7.56 1.5445 1 2 5 60.14 2.28 1.5386 -3 2 4 60.62 0.16 1.5275 2 5 1 60.96 0.02 1.5199 -2 2 5 60.98 0.88 1.5195 3 4 1 61.06 1.43 1.5177 2 4 3 61.06 0.11 1.5176 0 5 3 61.45 2.93 1.5088 -3 4 2 61.56 1.20 1.5064 -4 2 2 61.60 2.52 1.5056 0 3 5 61.86 1.68 1.4998 2 3 4 61.94 0.11 1.4981 4 2 1 61.95 8.44 1.4979 -1 3 5 61.96 0.60 1.4977 -2 5 2 61.98 1.77 1.4972 -1 5 3 62.20 2.98 1.4925 4 0 2 62.25 0.48 1.4914 1 4 4 62.55 0.30 1.4850 -4 1 3 62.71 1.10 1.4816 0 6 0 63.67 4.44 1.4615 1 5 3 63.70 0.22 1.4610 2 1 5 63.71 0.21 1.4607 0 6 1 63.91 1.54 1.4567 0 0 6 63.91 3.79 1.4566 3 3 3 64.02 0.36 1.4544 3 1 4 64.21 4.96 1.4506 2 5 2 64.45 0.19 1.4456 1 6 0 64.46 1.46 1.4455 -3 0 5 64.52 0.12 1.4443 -4 3 1 64.65 9.15 1.4418 4 3 0 64.75 3.25 1.4396 1 3 5 64.83 1.14 1.4382 3 4 2 64.86 0.95 1.4375 0 1 6 64.93 0.09 1.4363 -1 1 6 65.00 0.62 1.4349 -3 3 4 65.16 2.63 1.4316 -1 6 1 65.41 0.87 1.4268 -3 1 5 65.42 0.78 1.4265 -4 2 3 65.59 1.23 1.4232 -3 4 3 65.71 1.25 1.4209 1 6 1 65.78 0.17 1.4197 -2 3 5 66.03 1.36 1.4148 4 2 2 66.35 0.03 1.4088 -2 5 3 66.36 2.76 1.4087 -4 3 2 66.55 0.33 1.4052 2 2 5 66.66 0.38 1.4031 0 6 2 66.72 0.57 1.4019 4 3 1 66.86 0.70 1.3993 3 2 4 67.38 4.63 1.3898 -4 0 4 67.46 0.02 1.3883 -2 0 6 67.69 0.76 1.3843 0 2 6 67.75 1.60 1.3831 -1 2 6 67.76 1.00 1.3829 3 5 0 67.81 0.29 1.3821 -1 6 2 67.91 3.52 1.3802 -3 5 1 67.98 0.44 1.3791 0 5 4 68.20 0.34 1.3750 1 1 6 68.22 1.39 1.3747 -3 2 5 68.26 0.28 1.3740 0 4 5 68.31 2.36 1.3731 -4 1 4 68.39 0.02 1.3716 -2 1 6 68.51 2.97 1.3695 2 4 4 68.58 0.46 1.3684 -1 5 4 68.60 0.02 1.3681 -1 4 5 68.88 0.07 1.3631 1 6 2 69.14 0.36 1.3586 4 1 3 69.52 1.02 1.3521 3 5 1 69.55 0.26 1.3517 2 6 0 69.60 0.35 1.3508 2 5 3 69.97 0.17 1.3446 -2 6 1 70.08 1.19 1.3427 -4 3 3 70.46 0.01 1.3364 3 4 3 70.72 0.05 1.3322 1 5 4 70.96 0.92 1.3282 1 2 6 71.04 0.02 1.3269 -4 4 1 71.07 0.21 1.3265 -4 2 4 71.07 0.11 1.3264 -5 0 1 71.15 1.35 1.3251 -2 2 6 71.16 0.08 1.3250 4 4 0 71.17 0.34 1.3248 2 3 5 71.26 1.07 1.3233 1 4 5 71.43 1.04 1.3206 0 6 3 71.48 0.94 1.3199 3 3 4 71.49 0.42 1.3196 -3 4 4 71.89 1.56 1.3134 4 2 3 71.98 0.17 1.3119 -5 1 1 72.24 0.71 1.3078 -2 4 5 72.26 1.76 1.3075 -2 6 2 72.27 1.01 1.3073 0 3 6 72.28 3.57 1.3071 -1 6 3 72.33 0.10 1.3063 -1 3 6 72.36 0.61 1.3060 5 1 0 72.49 6.85 1.3039 -2 5 4 72.55 5.40 1.3030 3 0 5 72.80 0.16 1.2992 -3 3 5 72.80 1.02 1.2991 -4 4 2 73.14 0.26 1.2939 3 5 2 73.15 0.57 1.2938 4 4 1 73.45 0.05 1.2892 3 1 5 73.47 0.31 1.2890 -5 1 2 73.70 0.55 1.2855 5 0 1 73.84 0.30 1.2833 2 0 6 73.85 2.49 1.2831 1 6 3 73.87 0.86 1.2829 -3 5 3 74.36 1.27 1.2757 2 6 2 74.59 2.02 1.2722 5 1 1 74.68 0.92 1.2711 -5 2 1 74.74 1.65 1.2702 2 1 6 75.04 0.51 1.2657 -3 1 6 75.05 0.04 1.2656 5 2 0 75.47 0.16 1.2597 1 3 6 75.57 1.50 1.2583 -4 3 4 75.65 0.38 1.2571 -2 3 6 75.68 0.04 1.2567 0 7 1 75.70 0.26 1.2564 -4 1 5 75.84 0.30 1.2544 4 0 4 75.89 0.30 1.2537 -5 0 3 76.06 1.23 1.2514 -1 0 7 76.13 1.64 1.2504 3 2 5 76.15 0.03 1.2502 -5 2 2 76.37 0.08 1.2471 4 3 3 76.37 0.48 1.2471 1 7 0 76.37 0.25 1.2470 -2 6 3 76.39 0.01 1.2468 -4 4 3 76.41 0.27 1.2465 0 5 5 76.65 0.01 1.2432 2 5 4 76.73 1.01 1.2421 4 1 4 76.73 0.33 1.2421 -1 5 5 76.78 1.19 1.2414 -5 1 3 76.94 0.27 1.2391 -1 1 7 76.96 0.95 1.2390 4 4 2 77.03 0.77 1.2380 -1 7 1 77.14 0.14 1.2365 0 1 7 77.26 0.05 1.2349 5 2 1 77.40 0.05 1.2330 2 2 6 77.44 0.25 1.2325 2 4 5 77.54 0.30 1.2311 1 7 1 77.70 0.03 1.2290 3 6 0 77.74 0.23 1.2285 3 4 4 77.84 1.10 1.2271 -3 6 1 77.90 0.70 1.2263 0 6 4 78.35 0.36 1.2204 -4 2 5 78.42 1.66 1.2195 0 7 2 78.52 0.30 1.2182 3 5 3 78.57 0.46 1.2175 -1 4 6 78.63 0.20 1.2167 5 1 2 79.02 1.43 1.2118 -3 4 5 79.08 0.43 1.2110 -4 5 1 79.10 0.23 1.2107 -5 3 1 79.19 0.20 1.2096 4 5 0 79.29 0.86 1.2083 1 5 5 79.37 0.02 1.2073 4 2 4 79.38 0.12 1.2072 3 6 1 79.42 0.83 1.2066 -5 2 3 79.50 0.91 1.2056 -1 7 2 79.51 0.05 1.2055 -3 5 4 79.59 0.45 1.2045 -1 2 7 79.65 0.06 1.2037 1 0 7 79.78 0.31 1.2021 0 2 7 79.80 0.10 1.2018 -3 6 2 79.94 0.03 1.2001 -2 1 7 80.52 0.03 1.1930 1 6 4 80.52 1.59 1.1929 1 7 2 80.52 0.26 1.1929 1 1 7 80.53 0.23 1.1928 3 3 5 80.55 0.49 1.1926 -5 3 2 80.77 0.04 1.1898 -4 5 2 81.11 0.24 1.1857 4 5 1 81.15 0.50 1.1852 2 7 0 81.26 0.28 1.1839 5 2 2 81.54 0.11 1.1805 -2 7 1 81.62 0.63 1.1795 1 4 6 81.64 1.50 1.1793 5 3 1 81.72 0.12 1.1784 -4 4 4 81.78 0.43 1.1776 2 3 6 81.80 2.18 1.1774 -2 4 6 81.86 0.27 1.1768 -5 1 4 82.08 0.37 1.1741 -3 3 6 82.22 0.26 1.1725 -2 6 4 82.51 0.69 1.1691 4 4 3 82.56 0.23 1.1686 -2 2 7 82.56 0.40 1.1686 2 7 1 82.72 0.18 1.1667 -4 3 5 82.85 0.03 1.1652 3 6 2 82.94 0.28 1.1641 0 7 3 83.14 1.60 1.1619 1 2 7 83.55 0.02 1.1572 -3 6 3 83.73 2.03 1.1552 4 3 4 83.74 0.28 1.1551 -2 7 2 83.76 0.05 1.1549 -1 7 3 83.78 3.11 1.1546 -5 3 3 83.94 0.85 1.1528 -1 3 7 84.13 0.03 1.1506 0 3 7 84.23 0.70 1.1496 3 1 6 84.41 0.10 1.1476 5 1 3 84.46 0.04 1.1470 -5 2 4 84.64 0.38 1.1450 -4 1 6 84.82 0.01 1.1431 4 5 2 85.18 0.02 1.1391 -3 0 7 85.19 1.73 1.1390 -5 4 1 85.27 1.28 1.1382 1 7 3 85.56 1.05 1.1351 5 4 0 85.58 0.06 1.1348 3 5 4 85.75 1.22 1.1330 2 7 2 85.87 0.10 1.1318 4 1 5 86.01 0.13 1.1302 0 6 5 86.05 2.13 1.1299 -3 1 7 86.25 0.28 1.1278 2 6 4 86.32 0.05 1.1270 -1 6 5 86.34 0.80 1.1268 0 5 6 86.40 0.25 1.1262 -1 5 6 86.60 0.37 1.1241 3 4 5 86.62 0.03 1.1239 -5 4 2 86.82 0.41 1.1218 3 2 6 86.84 0.86 1.1216 -3 5 5 86.88 0.06 1.1211 -2 3 7 87.00 0.45 1.1199 5 2 3 87.01 0.48 1.1199 2 1 7 87.23 0.89 1.1176 -4 2 6 87.70 0.29 1.1128 -2 7 3 87.71 0.04 1.1127 5 4 1 87.79 0.90 1.1119 -5 0 5 87.85 0.04 1.1113 2 4 6 87.86 0.01 1.1112 0 8 0 88.07 0.60 1.1090 3 6 3 88.46 0.27 1.1052 4 2 5 88.62 0.14 1.1036 -4 6 1 88.64 0.20 1.1035 -3 2 7 88.66 0.01 1.1033 -5 1 5 88.73 0.02 1.1025 4 6 0 88.75 0.18 1.1023 0 8 1 88.77 0.20 1.1021 -4 4 5 88.78 0.12 1.1020 -5 3 4 88.96 0.10 1.1002 6 0 0 89.00 0.61 1.0999 3 7 0 89.05 0.10 1.0994 -3 6 4 89.14 0.67 1.0985 -3 7 1 89.20 0.17 1.0980 0 7 4 89.21 0.29 1.0978 -6 1 1 89.41 0.19 1.0959 1 5 6 89.42 0.03 1.0958 1 8 0 89.51 0.61 1.0950 -4 5 4 89.52 0.26 1.0948 -6 0 2 89.59 0.67 1.0942 -2 5 6 89.59 0.20 1.0941 2 2 7 89.76 0.87 1.0926 -1 7 4 89.76 0.03 1.0925 0 0 8 89.76 0.10 1.0925 -2 6 5 89.77 0.07 1.0924 4 4 4 89.82 0.39 1.0919 6 1 0 89.83 0.13 1.0919 -5 4 3 89.98 0.36 1.0904 -1 4 7 ================================================================================ XPOW Copyright 1993 Bob Downs, Ranjini Swaminathan and Kurt Bartelmehs For reference, see Downs et al. (1993) American Mineralogist 78, 1104-1107.