##NAMES=Pirquitasite ##RRUFFID=R061016 ##IDEAL CHEMISTRY=Ag^1+^_2_Zn^2+^Sn^4+^S^2-^_4_ ##LOCALITY=Pirquitas, Jujuy Province, Argentina ##OWNER=RRUFF ##SOURCE=Michael Scott (small piece), Bob Jenkins (large piece) ##DESCRIPTION=Steel gray metallic massive, associated with rhodostannite, R120139. This sample was used in the Schumer et al (2013) study. ##STATUS=The identification of this mineral is confirmed by single-crystal X-ray diffraction and chemical analysis. ##URL=rruff.info/R061016 ##MEASURED CHEMISTRY=(Ag_1.90_Cu_0.10_)(Zn_0.61_Fe_0.33_Cu_0.03_Cd_0.03_)(Sn_0.97_Fe_0.03_)S_3.87_; normalized to four cations 122.6887, 288.4148 124.6172, 328.5449 126.5457, 364.9774 128.4741, 394.8832 130.4026, 416.6094 132.3311, 428.7361 134.2595, 440.6693 136.1880, 452.4285 138.1165, 464.2098 140.0449, 476.1593 141.9734, 491.7235 143.9019, 504.7377 145.8303, 510.9395 147.7588, 509.3671 149.6873, 509.4461 151.6157, 514.3046 153.5442, 523.0370 155.4727, 530.3697 157.4011, 536.8030 159.3296, 541.7485 161.2581, 544.6304 163.1865, 544.1660 165.1150, 544.6251 167.0435, 547.8042 168.9719, 554.5318 170.9004, 558.9974 172.8289, 560.0542 174.7573, 558.8969 176.6858, 557.0005 178.6143, 550.9503 180.5427, 546.9771 182.4712, 548.1971 184.3997, 555.7565 186.3281, 561.7178 188.2566, 562.4733 190.1851, 560.4256 192.1135, 562.3542 194.0420, 571.6299 195.9705, 582.3689 197.8989, 591.6439 199.8274, 599.4170 201.7559, 606.5031 203.6843, 613.5285 205.6128, 620.3782 207.5413, 624.9792 209.4697, 624.7327 211.3982, 623.7969 213.3267, 625.5733 215.2551, 632.1428 217.1836, 637.5759 219.1121, 641.1862 221.0405, 642.9238 222.9690, 640.9111 224.8975, 629.9626 226.8259, 617.3245 228.7544, 610.2794 230.6829, 614.1902 232.6113, 618.9878 234.5398, 622.5794 236.4683, 624.8635 238.3967, 625.8839 240.3252, 622.5718 242.2537, 618.1669 244.1821, 618.5022 246.1106, 626.9601 248.0391, 637.1763 249.9675, 646.4241 251.8960, 654.2079 253.8245, 665.3411 255.7529, 684.5427 257.6814, 708.4041 259.6099, 726.7255 261.5384, 737.4895 263.4668, 745.3251 265.3953, 752.2634 267.3238, 758.7061 269.2522, 763.0231 271.1807, 764.4449 273.1092, 763.4077 275.0376, 761.9122 276.9661, 759.5306 278.8946, 757.0182 280.8230, 754.0380 282.7515, 749.0903 284.6800, 747.9592 286.6084, 753.8882 288.5369, 765.3014 290.4654, 772.6154 292.3938, 774.5364 294.3223, 773.2449 296.2508, 769.4031 298.1792, 758.3151 300.1077, 753.8032 302.0362, 755.5969 303.9646, 765.6959 305.8931, 786.2557 307.8216, 816.0561 309.7500, 858.9589 311.6785, 915.2750 313.6070, 982.8634 315.5354, 1069.798 317.4639, 1188.086 319.3924, 1329.018 321.3208, 1461.770 323.2493, 1594.457 325.1778, 1707.630 327.1062, 1791.935 329.0347, 1846.474 330.9632, 1869.078 332.8916, 1849.181 334.8201, 1795.218 336.7486, 1730.345 338.6770, 1647.861 340.6055, 1560.888 342.5340, 1475.773 344.4624, 1393.884 346.3909, 1310.411 348.3194, 1220.223 350.2478, 1128.069 352.1763, 1043.978 354.1048, 970.1324 356.0332, 904.4835 357.9617, 847.7142 359.8902, 801.7966 361.8186, 760.4274 363.7471, 725.9957 365.6756, 695.7873 367.6040, 665.3126 369.5325, 629.6945 371.4610, 597.9163 373.3894, 573.3719 375.3179, 556.7555 377.2464, 543.0732 379.1748, 533.2209 381.1033, 525.6499 383.0318, 518.4736 384.9602, 511.4212 386.8887, 505.0249 388.8172, 500.2436 390.7456, 497.0755 392.6741, 492.1143 394.6026, 482.3501 396.5310, 472.0064 398.4595, 464.8125 400.3880, 464.7650 402.3164, 463.9477 404.2449, 460.5440 406.1734, 455.1886 408.1018, 451.5701 410.0303, 452.4225 411.9588, 453.3233 413.8872, 451.5453 415.8157, 443.4359 417.7442, 437.0722 419.6726, 433.5905 421.6011, 432.1222 423.5296, 430.3252 425.4580, 427.6795 427.3865, 425.0550 429.3150, 422.9550 431.2434, 422.1093 433.1719, 419.9995 435.1004, 415.1591 437.0288, 409.5139 438.9573, 405.6130 440.8858, 404.5719 442.8142, 403.7337 444.7427, 402.5098 446.6712, 400.9473 448.5996, 398.5325 450.5281, 393.5439 452.4566, 389.0041 454.3850, 387.3113 456.3135, 389.5581 458.2420, 391.8411 460.1705, 393.6773 462.0989, 394.9365 464.0274, 395.0562 465.9559, 392.0442 467.8843, 389.6139 469.8128, 390.1617 471.7413, 394.2953 473.6697, 395.8905 475.5982, 391.6651 477.5267, 385.1681 479.4551, 382.0882 481.3836, 386.2962 483.3121, 387.8635 485.2405, 380.9155 487.1690, 367.4182 489.0975, 358.7335 491.0259, 359.5317 492.9544, 362.9779 494.8829, 365.4463 496.8113, 366.7095 498.7398, 367.6448 500.6683, 368.6077 502.5967, 369.1792 504.5252, 368.6210 506.4537, 365.0583 508.3821, 362.1048 510.3106, 361.0647 512.2391, 362.1949 514.1675, 362.5031 516.0960, 362.3493 518.0245, 361.1041 519.9529, 357.9970 521.8814, 350.9036 523.8099, 347.0865 525.7383, 349.7058 527.6668, 356.3860 529.5953, 360.2697 531.5237, 360.1809 533.4522, 359.0839 535.3807, 357.3066 537.3091, 354.5289 539.2376, 354.1869 541.1661, 358.9064 543.0945, 364.3730 545.0230, 366.7924 546.9515, 365.5944 548.8799, 363.7675 550.8084, 361.0383 552.7369, 358.2357 554.6653, 357.1657 556.5938, 361.2668 558.5223, 363.9806 560.4507, 362.5061 562.3792, 356.7093 564.3077, 353.4977 566.2361, 354.5651 568.1646, 357.2636 570.0931, 360.1579 572.0215, 364.2878 573.9500, 365.7908 575.8785, 362.0161 577.8069, 355.9430 579.7354, 353.2887 581.6639, 355.2926 583.5923, 358.1488 585.5208, 360.5987 587.4493, 362.7398 589.3777, 365.4815 591.3062, 371.3739 593.2347, 375.8138 595.1631, 375.0675 597.0916, 367.8685 599.0201, 363.7107 600.9485, 365.7130 602.8770, 370.5074 604.8055, 374.8729 606.7339, 379.2699 608.6624, 382.4679 610.5909, 384.1747 612.5193, 384.5699 614.4478, 384.2372 616.3763, 382.1516 618.3047, 380.7201 620.2332, 381.0547 622.1617, 383.0623 624.0901, 385.1617 626.0186, 388.5366 627.9471, 391.0483 629.8755, 390.8535 631.8040, 387.2326 633.7325, 384.5538 635.6609, 383.0977 637.5894, 383.2415 639.5179, 385.6629 641.4464, 393.0152 643.3748, 397.8744 645.3033, 396.0569 647.2318, 389.9232 649.1602, 388.9362 651.0887, 395.5687 653.0172, 403.5095 654.9456, 412.3716 656.8741, 421.8130 658.8026, 425.4811 660.7310, 416.9803 662.6595, 407.5396 664.5880, 402.9568 666.5164, 404.8846 668.4449, 406.8607 670.3734, 409.5293 672.3018, 411.4207 674.2303, 411.2867 676.1588, 408.4569 678.0872, 404.7574 680.0157, 400.4732 681.9442, 395.5893 683.8726, 390.0235 685.8011, 383.1836 687.7296, 376.6362 689.6580, 369.7842 691.5865, 363.4796 693.5150, 360.7001 695.4434, 366.9569 697.3719, 370.6592 699.3004, 365.6420 701.2288, 350.0446 703.1573, 340.0266 705.0858, 340.3523 707.0142, 342.1917 708.9427, 340.1847 710.8712, 334.3716 712.7996, 328.1169 714.7281, 319.8257 716.6566, 312.7296 718.5850, 309.5383 720.5135, 314.5677 722.4420, 317.9536 724.3704, 319.1353 726.2989, 318.6714 728.2274, 317.4171 730.1558, 315.0817 732.0843, 312.5544 734.0128, 309.7317 735.9412, 306.8807 737.8697, 304.8319 739.7982, 307.0889 741.7266, 306.3721 743.6551, 298.3100 745.5836, 285.0943 747.5120, 276.6429 749.4405, 273.9141 751.3690, 275.3869 753.2974, 282.0807 755.2259, 294.6598 757.1544, 301.8834 759.0828, 300.2794 761.0113, 296.4420 762.9398, 293.7101 764.8682, 292.2496 766.7967, 288.5771 768.7252, 278.8399 770.6536, 269.7871 772.5821, 266.2548 774.5106, 269.9626 776.4390, 271.9105 778.3675, 268.7655 780.2960, 264.9599 782.2244, 265.3796 784.1529, 272.7931 786.0814, 276.3092 788.0098, 270.0735 789.9383, 261.4626 791.8668, 258.3228 793.7952, 262.8361 795.7237, 267.0155 797.6522, 270.2586 799.5806, 271.9725 801.5091, 270.8345 803.4376, 263.4013 805.3660, 258.1009 807.2945, 257.1631 809.2230, 258.8643 811.1514, 260.2081 813.0799, 261.1756 815.0084, 261.5549 816.9368, 260.7806 818.8653, 259.3848 820.7938, 258.9873 822.7222, 260.5239 824.6507, 262.0900 826.5792, 264.1721 828.5077, 266.0710 830.4362, 265.7218 832.3646, 261.8532 834.2931, 257.8566 836.2216, 255.2888 838.1500, 253.7827 840.0785, 251.3205 842.0070, 245.0255 843.9354, 240.7958 845.8639, 240.9765 847.7924, 245.1019 849.7208, 248.9355 851.6493, 252.9832 853.5778, 256.1159 855.5062, 257.5355 857.4347, 257.5573 859.3632, 257.4117 861.2916, 257.0405 863.2201, 256.5743 865.1486, 255.8678 867.0770, 254.9408 869.0055, 254.5495 870.9340, 255.8868 872.8624, 256.5662 874.7909, 254.3047 876.7194, 250.3139 878.6478, 249.7334 880.5763, 256.0088 882.5048, 261.8652 884.4332, 264.6450 886.3617, 264.3541 888.2902, 262.4912 890.2186, 256.2339 892.1471, 251.3741 894.0756, 250.6382 896.0040, 253.4847 897.9325, 255.9526 899.8610, 258.0851 901.7894, 259.5688 903.7179, 260.1710 905.6464, 259.9764 907.5748, 259.5185 909.5033, 257.6695 911.4318, 256.7296 913.3602, 258.5860 915.2887, 262.5149 917.2172, 262.9684 919.1456, 255.7655 921.0741, 250.6863 923.0026, 253.1890 924.9310, 260.5581 926.8595, 266.1549 928.7880, 270.3273 930.7164, 271.2047 932.6449, 265.0768 934.5734, 254.6418 936.5018, 251.3041 938.4303, 261.8319 940.3588, 271.0232 942.2872, 276.4277 944.2157, 278.3234 946.1442, 277.5679 948.0726, 272.9487 950.0011, 268.7039 951.9296, 265.6304 953.8580, 263.9902 955.7865, 264.8536 957.7150, 271.2960 959.6434, 274.7226 961.5719, 270.6835 963.5004, 264.0651 965.4288, 263.1672 967.3573, 271.7251 969.2858, 276.5264 971.2142, 271.2774 973.1427, 263.7893 975.0712, 262.4103 976.9996, 268.4977 978.9281, 273.1794 980.8566, 272.9293 982.7850, 271.6162 984.7135, 272.2983 986.6420, 276.8144 988.5704, 278.7772 990.4989, 274.7397 992.4274, 271.1608 994.3558, 274.2561 996.2843, 284.0314 998.2128, 288.8350 1000.141, 283.9971 1002.070, 277.7987 1003.998, 274.1446 1005.927, 272.8862 1007.855, 273.0325 1009.784, 276.5555 1011.712, 279.1279 1013.641, 278.3089 1015.569, 274.7982 1017.497, 273.8564 1019.426, 278.7045 1021.354, 282.0253 1023.283, 281.3513 1025.211, 278.1827 1027.140, 275.2827 1029.068, 272.0893 1030.997, 270.8746 1032.925, 274.5950 1034.854, 279.6509 1036.782, 281.3806 1038.711, 277.7076 1040.639, 275.1710 1042.568, 275.7331 1044.496, 276.6893 1046.424, 275.3167 1048.353, 270.8953 1050.281, 267.7902 1052.210, 267.3243 1054.138, 267.3790 1056.067, 266.8401 1057.995, 265.7611 1059.924, 264.3219 1061.852, 261.8082 1063.781, 259.8308 1065.709, 258.4160 1067.638, 257.7860 1069.566, 259.5298 1071.495, 267.2291 1073.423, 272.9470 1075.351, 274.4088 1077.280, 273.2470 1079.208, 272.8949 1081.137, 274.2549 1083.065, 273.7584 1084.994, 268.3270 1086.922, 262.2345 1088.851, 259.5305 1090.779, 260.6128 1092.708, 261.2522 1094.636, 261.2623 1096.565, 260.1826 1098.493, 257.1839 1100.422, 252.0264 1102.350, 248.4537 1104.278, 246.0710 1106.207, 245.5051 1108.135, 247.9967 1110.064, 252.5269 1111.992, 255.6464 1113.921, 256.5821 1115.849, 257.8460 1117.778, 261.4665 1119.706, 265.1201 1121.635, 265.7701 1123.563, 262.6674 1125.492, 260.4386 1127.420, 261.4489 1129.349, 262.4161 1131.277, 261.0264 1133.205, 256.7804 1135.134, 253.7952 1137.062, 252.8594 1138.991, 252.1681 1140.919, 251.0111 1142.848, 249.5895 1144.776, 248.3172 1146.705, 246.0979 1148.633, 246.4550 1150.562, 254.9469 1152.490, 264.0290 1154.419, 263.8445 1156.347, 252.1811 1158.276, 245.3253 1160.204, 252.2045 1162.132, 259.6348 1164.061, 259.6698 1165.989, 251.7420 1167.918, 247.1902 1169.846, 247.9663 1171.775, 249.7157 1173.703, 252.2505 1175.632, 254.8513 1177.560, 255.4252 1179.489, 252.8893 1181.417, 251.4900 1183.346, 252.7761 1185.274, 255.0286 1187.203, 256.7920 1189.131, 258.0944 1191.059, 259.7763 1192.988, 262.9847 1194.916, 265.2967 1196.845, 266.1289 1198.773, 265.3885 1200.702, 262.2777 1202.630, 252.6605 1204.559, 246.9377 1206.487, 249.4074 1208.416, 254.7249 1210.344, 256.4473 1212.273, 252.8256 1214.201, 251.5280 1216.130, 255.2319 1218.058, 258.8855 1219.986, 259.4398 1221.915, 257.8847 1223.843, 257.6437 1225.772, 259.7545 1227.700, 261.1075 1229.629, 259.1008 1231.557, 256.6030 1233.486, 257.4638 1235.414, 262.7033 1237.343, 265.5173 1239.271, 261.9675 1241.200, 258.7964 1243.128, 259.8351 1245.057, 264.3751 1246.985, 266.6531 1248.913, 264.8745 1250.842, 263.1821 1252.770, 261.3170 1254.699, 260.2249 1256.627, 261.6400 1258.556, 265.9321 1260.484, 269.0978 1262.413, 271.0122 1264.341, 271.5709 1266.270, 269.5176 1268.198, 266.1425 1270.127, 264.6535 1272.055, 265.4969 1273.984, 267.1764 1275.912, 271.2088 1277.840, 274.4195 1279.769, 272.9815 1281.697, 265.6592 1283.626, 263.0327 1285.554, 270.8186 1287.483, 277.4633 1289.411, 279.0205 1291.340, 277.1204 1293.268, 275.6037 1295.197, 275.3362 1297.125, 273.7421 1299.054, 268.3563 1300.982, 263.6047 1302.911, 263.0734 1304.839, 266.3068 1306.767, 269.3118 1308.696, 272.4787 1310.624, 274.4957 1312.553, 273.9276 1314.481, 272.4976 1316.410, 272.2009 1318.338, 273.0894 1320.267, 273.4259 1322.195, 271.7692 1324.124, 271.0636 1326.052, 273.8325 1327.981, 278.4359 1329.909, 279.6711 1331.838, 274.9825 1333.766, 272.9176 1335.694, 277.3993 1337.623, 282.0349 1339.551, 282.5532 1341.480, 279.0171 1343.408, 274.5996 1345.337, 265.1256 1347.265, 260.2852 1349.194, 265.2168 1351.122, 273.4915 1353.051, 278.0697 1354.979, 278.8331 1356.908, 278.2692 1358.836, 275.5823 1360.765, 272.9874 1362.693, 271.4577 1364.621, 270.6288 1366.550, 269.6083 1368.478, 268.1758 1370.407, 268.5005 1372.335, 273.8536 1374.264, 277.4496 1376.192, 273.0063 1378.121, 263.8427 1380.049, 262.2007 1381.978, 272.2482 1383.906, 278.5957 1385.835, 274.9780 1387.763, 269.5702 1389.692, 267.1794 1391.620, 267.7349 1393.548, 269.2470 1395.477, 273.2228 1397.405, 276.2121 1399.334, 278.4455 1401.262, 279.1431 1403.191, 276.8785 1405.119, 271.2936 1407.048, 267.4069 1408.976, 264.8856 1410.905, 264.3054 1412.833, 268.0859 1414.762, 272.5891 1416.690, 272.7500 1418.619, 268.4254 1420.547, 265.4066 1422.475, 265.0625 1424.404, 264.6631 1426.332, 261.6160 1428.261, 258.6753 1430.189, 260.4614 1432.118, 267.2465 1434.046, 270.7780 1435.975, 267.5526 1437.903, 264.3567 1439.832, 265.0801 1441.760, 267.5783 1443.689, 268.3264 1445.617, 267.0669 1447.546, 266.4813 1449.474, 267.1626 1451.402, 268.4637 1453.331, 271.7923 1455.259, 275.0618 1457.188, 273.2567 1459.116, 263.9543 1461.045, 257.6656 1462.973, 255.6912 1464.902, 256.3209 1466.830, 260.9702 1468.759, 267.3326 1470.687, 270.2900 1472.616, 269.1650 1474.544, 266.0244 1476.473, 257.2452 1478.401, 250.7910 1480.329, 250.8017 1482.258, 255.3563 1484.186, 260.8909 1486.115, 269.2330 1488.043, 273.3458 1489.972, 271.5575 1491.900, 267.1379 1493.829, 258.2538 1495.757, 248.5209 1497.686, 246.5586 1499.614, 254.1014 1501.543, 257.4746 1503.471, 250.4925 1505.400, 245.1768 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