Natrolite R040022

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Record 8 of 13  

Name: Natrolite
RRUFF ID: R040022
Ideal Chemistry: Na2(Si3Al2)O10·2H2O
Locality: Patterson, Passaic County, New Jersey, USA
Source: University of Arizona Mineral Museum 2108 [view label]
Owner: RRUFF
Description: White fine fibrous mass
Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis
Mineral Group: [ Natrolite (13) ]
Quick search: [ All Natrolite samples (6) ]
CHEMISTRY 
RRUFF ID: R040022.2
Sample Description: Microprobe Fragment
Measured Chemistry: (Na1.87Ca0.080.05)(Si2.97Al2.03)O10·1.95H2O ; H2O estimated by difference
Microprobe Data File: [ Download Excel File ]
RAMAN SPECTRUM 
RRUFF ID:
Sample Description: Laser beam parallel to fiber axes
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BROAD SCAN WITH SPECTRAL ARTIFACTS
RRUFF ID: R040022
Wavelength:
Sample Description: Unoriented sample
Instrument settings: Thermo Almega XR 532nm @ 100% of 150mW
INFRARED SPECTRUM (Attenuated Total Reflectance) 
RRUFF ID: R040022.1
Instrument settings: SensIR Durascope on a Nicolet Magna 860 FTIR
Resolution:
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POWDER DIFFRACTION 
RRUFF ID: R040022.1
Sample Description: Powder
Cell Refinement Output: a: 18.2955(6)Å    b: 18.6353(6)Å    c: 6.5813(6)Å
alpha: 90.°    beta: 90.°    gamma: 90.°   Volume: 2243.8(2)Å3    Crystal System: orthorhombic
  File Type Information Close
Calculated diffraction file.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

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REFERENCES for Natrolite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Klaproth M H (1803) Chemische Untersuchung des Natroliths, Naturforschender Freunde zu Berlin, Neue Schriften, 4, 243-248   [view file]

Pauling L (1930) The structure of some sodium and calcium aluminosilicates, Proceedings of the National Academy of Sciences, 16, 453-459   [view file]

Murdoch J (1942) Crystallographic notes: cristobalite, stephanite, natrolite, American Mineralogist, 27, 500-506   [view file]

Fleischer M (1954) New mineral names, American Mineralogist, 39, 402-408   [view file]

Fleischer M (1957) New mineral names, American Mineralogist, 42, 919-921   [view file]

Meier W M (1960) The crystal structure of natrolite, Zeitschrift für Kristallographie, 113, 430-444   [view file]

Gabuda S P, Lundin A G, Mikhailov G M, Aleksandrov K S (1963) The position of hydrogen atoms in natrolite, Soviet Physics - Crystallography, 8, 305-307   [view file]

Alberti A, Vezzalini G (1983) How the structure of natrolite is modified through the heating-induced dehydration, Neues Jahrbuch für Mineralogie, Monatshefte, 1983, 135-144

Pechar F, Rykl D (1983) Study of the vibrational spectra of natural natrolite, The Canadian Mineralogist, 21, 689-695   [view file]

Baur W H, Kassner D, Kim C, Sieber N H W (1990) Flexibility and distortion of the framework of natrolite: crystal structures of ion-exchanged natrolites, European Journal of Mineralogy, 2, 761-769

Krogh Andersen E, Krogh Andersen IG, Ploug-Sorensen G (1990) Disorder in natrolites: structure determinations of three disordered natrolites and one lithium-exchanged disordered natrolite, European Journal of Mineralogy, 2, 799-807

Gunter M E, Knowles C R, Schalck D K (1993) Composite natrolite–mesolite crystals from the Columbia River Basalt Group, Clarkston, Washington, The Canadian Mineralogist, 31, 467-470   [view file]

Alberti A, Cruciani G, Dauru I (1995) Order-disorder in natrolite-group minerals, European Journal of Mineralogy, 7, 501-508

Goryainov S V, Belitsky I A (1995) Raman spectroscopy of water tracer diffusion of zeolite single crystals, Physics and Chemistry of Minerals, 22, 443-452   [link]

Joswig W, Baur W H (1995) The extreme collapse of a framework of NAT topology: the crystal structure of a metanatrolite (dehydrated natrolite) at 548K, Neues Jahrbuch für Mineralogie, Monatshefte, 1995, 26-38

Baur W H, Joswig W (1996) The phases of natrolite occurring during dehydration and rehydration studied by single crystal X-ray diffraction methods between room temperature and 923 K, Neues Jahrbuch für Mineralogie, Monatshefte, 1996, 171-187

Stuckenschmidt E, Joswig W, Baur W H (1996) Flexibility and distortion of the collapsible framework of NAT topology: the crystal structure of H3O-natrolite, European Journal of Mineralogy, 8, 85-92

Coombs D S, Alberti A, Armbruster T, Artioli G, Colella C, Galli E, Grice J D, Liebau F, Mandarino J A, Minato H, Nickel E H, Passaglia E, Peacor D R, Quartieri S, Rinaldi R, Ross M, Sheppard R A, Tillmanns E, Vezzalini G, (1997) Recommended nomenclature for zeolite minerals: report of the Subcommittee on Zeolites of the International Mineralogical Association, Commission on New Minerals and Mineral Names, The Canadian Mineralogist, 35, 1571-1606   [view file]

Hamilton V E, McSween H Y, Hapke B (2005) Mineralogy of Martian atmospheric dust inferred from thermal infrared spectra of aerosols, Journal of Geophysical Research, 110, E12006   [link]

Seryotkin Y V, Bakakin V V, Fursenko B A, Belitsky I A, Joswig W, Radaelli P G (2005) Structural evolution of natrolite during over-hydration: a high-pressure neutron diffraction study, European Journal of Mineralogy, 17, 305-313

Wang H, Bish D L (2008) A PH2O-dependent structural phase transition in the zeolite natrolite, American Mineralogist, 93, 1191-1194   [view file]

Liu D, Liu Z, Lee Y, Seoung D, Lee Y (2012) Spectroscopic characterization of alkali-metal exchanged natrolites, American Mineralogist, 97, 419-424   [view file]

Hwang H, Seoung D, Gatta G D, Blom D A, Vogt T, Lee Y (2015) Topotactic and reconstructive changes at high pressures and temperatures from Cs-natrolite to Cs-hexacelsian, American Mineralogist, 100, 1562-1567

Lee Y, Ahn D, Vogt T, Lee Y (2017) Dehydration studies of natrolites: Role of monovalent extra-framework cations and degree of hydration, American Mineralogist, 102, 1462-1469