R110179 - RRUFF Database: Raman, X-ray, Infrared, and Chemistry

Hausmannite R110179

Name: Hausmannite
RRUFF ID: R110179
Ideal Chemistry: Mn²⁺Mn³⁺₂O₄
Locality: Cumbria, England
Source: Smithsonian [view label]
Owner: RRUFF
Description: Druse of sharp black octahedra
Status: The identification of this mineral has been confirmed by single-crystal X-ray diffraction.

Mineral Group: [ Spinel (66) ]

Quick search: [ All Hausmannite samples (4) ]

RAMAN SPECTRUM

RRUFF ID:

Sample Description:

Unoriented Raman on the primary sample

DOWNLOADS:

To download sample data,
please select a specific
orientation angle.

BROAD SCAN WITH SPECTRAL ARTIFACTS

RRUFF ID:

R110179

Wavelength:

Sample Description:

Unoriented Raman on the primary sample

Instrument settings:

Thermo Almega XR 532nm @ 100% of 150mW

DOWNLOADS:

	Raman Data (Processed)
	RRUFF File

POWDER DIFFRACTION

RRUFF ID:

R110179.9

Sample Description:

Single crystal, powder profile is calculated

Cell Refinement Output:

a: 5.769(1)Å b: 5.769(1)Å c: 9.448(2)Å
alpha: 90° beta: 90° gamma: 90° Volume: 314.42(8)Å³ Crystal System: tetragonal

File Type Information

Calculated diffraction file.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

DOWNLOADS:

	DIF File
	X-ray Data (XY - RAW)
	RRUFF File

REFERENCES for Hausmannite
American Mineralogist Crystal Structure Database Record: [view record]
Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]
Turner E (1828) Chemical examination of the oxides of manganese. Part II. On the composition of the ores of manganese described by Mr. Haidinger, The Philosophical Magazine, 4, 96-104 [view file]
Haidinger M W (1831) II. Pyramidal Manganese-ore Hausmannite, Transactions of the Royal Society of Edinburgh, 11, 127-129 [view file]
Aminoff G (1926) On the crystal structure of hausmannite (MnMn2O4), Zeitschrift für Kristallographie, 64, 475-490
Gavarri J R, Arabski J, Jasienska S, Janowski J, Garel C (1985) Structural evolution of manganosite: comparison of properties of nonstoichiometric manganese and iron monoxides, Journal of Solid State Chemistry, 58, 56-70
Jarosch D (1987) Crystal structure refinement and reflectance measurements of hausmannite, Mineralogy and Petrology, 37, 15-23
Baron V, Gutzmer J, Rundlöf H, Tellgren R (1998) The influence of iron substitution on the magnetic properties of hausmannite, Mn²⁺(Fe,Mn)³⁺₂O₄, American Mineralogist, 83, 786-793 [view file]
Gillot B, El Guendouzi M, Laarj M (2001) Particle size effects on the oxidation-reduction behavior of Mn₃O₄ hausmannite, Materials Chemistry and Physics, 70, 54-60
Antao S M, Cruickshank L A, Hazrah K S (2019) Structural trends and solid-solutions based on the crystal chemistry of two hausmannite (Mn₃O₄) samples from the Kalahari manganese field, Minerals, 9, 343 [view file]
Bosi F, Biagioni C, Pasero M (2019) Nomenclature and classification of the spinel supergroup, European Journal of Mineralogy, 31, 183-192 [view file]
Post J E, McKeown D A, Heaney, P J (2020) Raman spectroscopy study of manganese oxides: Tunnel structures, American Mineralogist, 105, 1175-1190 [view file]

REFERENCES for Hausmannite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Turner E (1828) Chemical examination of the oxides of manganese. Part II. On the composition of the ores of manganese described by Mr. Haidinger, The Philosophical Magazine, 4, 96-104 [view file]

Haidinger M W (1831) II. Pyramidal Manganese-ore Hausmannite, Transactions of the Royal Society of Edinburgh, 11, 127-129 [view file]

Aminoff G (1926) On the crystal structure of hausmannite (MnMn2O4), Zeitschrift für Kristallographie, 64, 475-490

Gavarri J R, Arabski J, Jasienska S, Janowski J, Garel C (1985) Structural evolution of manganosite: comparison of properties of nonstoichiometric manganese and iron monoxides, Journal of Solid State Chemistry, 58, 56-70

Jarosch D (1987) Crystal structure refinement and reflectance measurements of hausmannite, Mineralogy and Petrology, 37, 15-23

Baron V, Gutzmer J, Rundlöf H, Tellgren R (1998) The influence of iron substitution on the magnetic properties of hausmannite, Mn²⁺(Fe,Mn)³⁺₂O₄, American Mineralogist, 83, 786-793 [view file]

Gillot B, El Guendouzi M, Laarj M (2001) Particle size effects on the oxidation-reduction behavior of Mn₃O₄ hausmannite, Materials Chemistry and Physics, 70, 54-60

Antao S M, Cruickshank L A, Hazrah K S (2019) Structural trends and solid-solutions based on the crystal chemistry of two hausmannite (Mn₃O₄) samples from the Kalahari manganese field, Minerals, 9, 343 [view file]

Bosi F, Biagioni C, Pasero M (2019) Nomenclature and classification of the spinel supergroup, European Journal of Mineralogy, 31, 183-192 [view file]

Post J E, McKeown D A, Heaney, P J (2020) Raman spectroscopy study of manganese oxides: Tunnel structures, American Mineralogist, 105, 1175-1190 [view file]