Dolerophanite R070652

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Record 4 of 13  

Name: Dolerophanite
RRUFF ID: R070652
Ideal Chemistry: Cu2O(SO4)
Locality: First scoria cone, Northern Breakthrough (North Breach), Great Fissure (Main Fracture) eruption, Tolbachik volcano, Kamchatka Oblast', Far-Eastern Region, Russia
Source: Michael Scott S102948 [view label]
Owner: RRUFF
Description: Very dark brown prismatic crystal to golden brown crystal fragments associated with euchlorine
Status: The identification of this mineral has been confirmed by single-crystal X-ray diffraction.
Mineral Group: [ Natrochalcite (13) ]
Quick search: [ All Dolerophanite samples (2) ]
Sample Description: Unoriented sample

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RRUFF ID: R070652
Sample Description: Unoriented sample
Instrument settings: Thermo Almega XR 532nm @ 100% of 150mW
RRUFF ID: R070652.9
Sample Description: Single crystal, powder profile is calculated
Cell Refinement Output: a: 9.38(2)Å    b: 6.33(1)Å    c: 7.63(2)Å
alpha: 90°    beta: 122.35(6)°    gamma: 90°   Volume: 383(1)Å3    Crystal System: monoclinic
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Calculated diffraction file.

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Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

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REFERENCES for Dolerophanite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Scacchi A (1873) Nuove specie di solfati di rame, Atti Dell'Accademia delle Scienze Fisiche e Matematiche, 5, 22-29   [view file]

Richmond W E (1940) Crystal chemistry of the phosphates, arsenates and vanadates of the type A2XO4(Z), American Mineralogist, 25, 441-478   [view file]

Flügel-Kahler E (1963) Die kristallstruktur von dolerophanit, Cu2O(SO4), Acta Crystallographica, 16, 1009-1014

Effenberger H (1985) Cu2O(SO4), dolerophanite: Refinement of the crystal structure with a comparison of [OCu(II)4] tetrahedra in inorganic compounds, Monatshefte für Chemie, 116, 927-931

Nazarchuk E V, Siidra O I, Filatov S K, Charkin D O, Zhdanova L R (2023) Thermal expansion of anhydrous copper sulfate minerals determined by single crystal X‑ray diffraction: chalcocyanite CuSO4, dolerophanite Cu2OSO4 and kamchatkite KCu3O(SO4)2Cl, Physics and Chemistry of Minerals, 50, 11