R070557 - RRUFF Database: Raman, X-ray, Infrared, and Chemistry

Haüyne R070557

Name: Haüyne
RRUFF ID: R070557
Ideal Chemistry: Na₃Ca(Si₃Al₃)O₁₂(SO₄)
Locality: Badakhshan, Afghanistan
Source: Farooq Hashmi [view label]
Owner: RRUFF
Description: Sky blue fragment
Status: The identification of this mineral is confirmed by single-crystal X-ray diffraction and chemical analysis.

Mineral Groups: [ sodalite (24) ] [ cancrinite-sodalite (37) ]

Quick search: [ All Haüyne samples (5) ]

CHEMISTRY

RRUFF ID:	R070557.2
Sample Description:	Microprobe Fragment
Measured Chemistry:	Na_3.00(Ca_0.84Na_0.16)_Σ=1(Si_3.05Al_2.95)O₁₂((SO₄)_0.89Cl_0.11)_Σ=1
Microprobe Data File:	[ Download Excel File ]

RAMAN SPECTRUM

RRUFF ID:

Sample Description:

Sample is oriented and mounted on a pin

Pin ID:

M01358

Orientation:

Laser parallel to a* (1 0 0). Fiducial mark perpendicular to laser is parallel to c [0 0 1].

DOWNLOADS:

To download sample data,
please select a specific
orientation angle.

BROAD SCAN WITH SPECTRAL ARTIFACTS

RRUFF ID:

R070557

Wavelength:

Sample Description:

Unoriented sample

Instrument settings:

Thermo Almega XR 532nm @ 100% of 150mW

DOWNLOADS:

	Raman Data (Processed)
	RRUFF File
	Raman Data (RAW)
	RRUFF File

POWDER DIFFRACTION

RRUFF ID:

R070557.9

Sample Description:

Single crystal, powder profile is calculated

Cell Refinement Output:

a: 9.070(3)Å b: 9.070(3)Å c: 9.070(3)Å
alpha: 90° beta: 90° gamma: 90° Volume: 746.1(3)Å³ Crystal System: cubic

File Type Information

Calculated diffraction file.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

DOWNLOADS:

	DIF File
	X-ray Data (XY - RAW)
	RRUFF File

REFERENCES for Haüyne
American Mineralogist Crystal Structure Database Record: [view record]
Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]
Bruun-Neergard T C (1807) De la haüyne, nouvelle substance minerale, Journal des Mines, 21, 365-380 [view file]
Bruun-Neergard T C (1807) Ueber den hauyn (la hauyne), eine neue mineralische substanz, Journal of Chemical Physics, 4, 417-429 [view file]
Van Peteghem J K, Burley B J (1963) Studies on solid solution between sodalite, nosean and hauyne, The Canadian Mineralogist, 7, 808-813 [view file]
Leoni L, Mellini M, Merlino S, Orlandi P (1979) Cancrinite-like minerals: new data and crystal chemical considerations, Rendiconti della Società Italiana di Mineralogia e Petrologia, 35, 713-719 [view file]
Hassan I, Grundy H D (1984) The crystal structures of sodalite-group minerals, Acta Crystallographica, B40, 6-13
Hassan I, Grundy H D (1991) The crystal structure of hauyne at 293 and 153 K, The Canadian Mineralogist, 29, 123-130 [view file]
Ballirano P, Maras A, Buseck P R (1996) Crystal chemistry and IR spectroscopy of Cl- and SO₄-bearing cancrinite-like minerals, American Mineralogist, 81, 1003-1012 [view file]
Hassan I, Antao S M, Parise J B (2004) Haüyne: phase transition and high-temperature structures obtained from synchrotron radiation and Rietveld refinements, Mineralogical Magazine, 68, 499-513
Nasti V (2009) L'olotipo della haüyna, Il Cercapietre, 2009, issue 1-2 16-43 [view file]
Hettmann K, Wenzel T, Marks M, Markl G (2012) The sulfur speciation in S-bearing minerals: New constraints by a combination of electron microprobe analysis and DFT calculations with special reference to sodalite-group minerals, American Mineralogist, 97, 1653-1661 [view file]
Baudouin C, Parat F (2015) Role of volatiles (S, Cl, H₂O) and silica activity on the crystallization of haüyne and nosean in phonolitic magmas (Eifel, Germany and Saghro, Morocco), American Mineralogist, 100, 2308-2322
Balassone G, Bellatreccia F, Ottolini L, Mormone A, Petti C, Ghiara M R, Altomare A, Saviano M, Rizi R, D'Orazio L (2016) Sodalite-group minerals, from the Somma-Vesuvius volcano (Naples, Italy): A combined EPMA, SIMS, and FTIR crystal-chemical study, The Canadian Mineralogist, 54, 583-604
Farsang S, Caracas R, Adachi T B M, Schnyder C, Zajacz Z (2023) S₂^- and S₃^- radicals and the S₄^2- polysulfide ion in lazurite, haüyne, and synthetic ultramarine blue revealed by resonance Raman spectroscopy, American Mineralogist, 108, 2234-2243

REFERENCES for Haüyne

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Bruun-Neergard T C (1807) De la haüyne, nouvelle substance minerale, Journal des Mines, 21, 365-380 [view file]

Bruun-Neergard T C (1807) Ueber den hauyn (la hauyne), eine neue mineralische substanz, Journal of Chemical Physics, 4, 417-429 [view file]

Van Peteghem J K, Burley B J (1963) Studies on solid solution between sodalite, nosean and hauyne, The Canadian Mineralogist, 7, 808-813 [view file]

Leoni L, Mellini M, Merlino S, Orlandi P (1979) Cancrinite-like minerals: new data and crystal chemical considerations, Rendiconti della Società Italiana di Mineralogia e Petrologia, 35, 713-719 [view file]

Hassan I, Grundy H D (1984) The crystal structures of sodalite-group minerals, Acta Crystallographica, B40, 6-13

Hassan I, Grundy H D (1991) The crystal structure of hauyne at 293 and 153 K, The Canadian Mineralogist, 29, 123-130 [view file]

Ballirano P, Maras A, Buseck P R (1996) Crystal chemistry and IR spectroscopy of Cl- and SO₄-bearing cancrinite-like minerals, American Mineralogist, 81, 1003-1012 [view file]

Hassan I, Antao S M, Parise J B (2004) Haüyne: phase transition and high-temperature structures obtained from synchrotron radiation and Rietveld refinements, Mineralogical Magazine, 68, 499-513

Nasti V (2009) L'olotipo della haüyna, Il Cercapietre, 2009, issue 1-2 16-43 [view file]

Hettmann K, Wenzel T, Marks M, Markl G (2012) The sulfur speciation in S-bearing minerals: New constraints by a combination of electron microprobe analysis and DFT calculations with special reference to sodalite-group minerals, American Mineralogist, 97, 1653-1661 [view file]

Baudouin C, Parat F (2015) Role of volatiles (S, Cl, H₂O) and silica activity on the crystallization of haüyne and nosean in phonolitic magmas (Eifel, Germany and Saghro, Morocco), American Mineralogist, 100, 2308-2322

Balassone G, Bellatreccia F, Ottolini L, Mormone A, Petti C, Ghiara M R, Altomare A, Saviano M, Rizi R, D'Orazio L (2016) Sodalite-group minerals, from the Somma-Vesuvius volcano (Naples, Italy): A combined EPMA, SIMS, and FTIR crystal-chemical study, The Canadian Mineralogist, 54, 583-604

Farsang S, Caracas R, Adachi T B M, Schnyder C, Zajacz Z (2023) S₂^- and S₃^- radicals and the S₄^2- polysulfide ion in lazurite, haüyne, and synthetic ultramarine blue revealed by resonance Raman spectroscopy, American Mineralogist, 108, 2234-2243