R130713 - RRUFF Database: Raman, X-ray, Infrared, and Chemistry

Hydroxylapatite R130713

Name: Hydroxylapatite
RRUFF ID: R130713
Ideal Chemistry: Ca₅(PO₄)₃OH
Locality: Wessels mine, Kalahari manganese field, Northern Cape Province, South Africa
Source: Robert Lavinsky
Owner: RRUFF
Description: Transparent pale green hexagonal tablets
Status: The identification of this mineral has been confirmed only by single crystal X-ray diffraction.

Mineral Group: [ Apatite (56) ]

Quick search: [ All Hydroxylapatite samples (4) ]

RAMAN SPECTRUM

RRUFF ID:

Sample Description:

Unoriented sample

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To download sample data,
please select a specific
orientation angle.

BROAD SCAN WITH SPECTRAL ARTIFACTS

RRUFF ID:

R130713

Wavelength:

Sample Description:

Unoriented sample

Instrument settings:

Thermo Almega XR 532nm @ 100% of 150mW

DOWNLOADS:

	Raman Data (Processed)
	RRUFF File

POWDER DIFFRACTION

RRUFF ID:

R130713.9

Sample Description:

Single crystal, powder profile is calculated

Cell Refinement Output:

a: 9.4378(8)Å b: 9.4378(8)Å c: 6.9109(8)Å
alpha: 90° beta: 90° gamma: 120° Volume: 533.10(7)Å³ Crystal System: hexagonal

File Type Information

Calculated diffraction file.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

DOWNLOADS:

	DIF File
	X-ray Data (XY - RAW)
	RRUFF File

REFERENCES for Hydroxylapatite
American Mineralogist Crystal Structure Database Record: [view record]
Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]
Damour A A (1856) Sur l'hydro-apatite, espèce minérale, Annales des Mines, 10, 65-68 [view file]
Schaller W T (1912) Mineralogical notes, Series 2. Mineralogy of the French phosphorites, U.S. Geological Survey Bulletin, 509, 89-100 [view file]
Foshag W F (1936) New mineral names, American Mineralogist, 21, 269-272 [view file]
Kay M I, Young R A, Posner A S (1964) Crystal structure of hydroxyapatite, Nature, 204, 1050-1052
Jullmann H, Mosebach R (1966) Zur Synthese, Licht- und Doppelbrechung des Hydroxylapatits, Zeitschrift für Naturforschung B Chemical Science, 21, 493-494 [view file]
Sudarsanan K, Young R A (1969) Significant precision in crystal structural details: Holly Springs hydroxyapatite, Acta Crystallographica, B25, 1534-1543
Dickens B, Brown W E, Kruger G J, Stewart J M (1973) Ca₄(PO₄)₂O, tetracalcium diphosphate monooxide. Crystal structure and relationships to Ca₅(PO₄)₃OH and K₃Na(SO₄)₂, Acta Crystallographica, B29, 2046-2056
Elliot J C, Mackie P E, Young R A (1973) Monoclinic hydroxyapatite, Science, 180, 1055-1057
Fiore S, Lavanio R (1991) Brushite, hydroxylapatite, and taranakite from Apulian caves (southern Italy): New mineralogical data, American Mineralogist, 76, 1722-1727 [view file]
Nasdala L (1992) A Raman study on the so-called “pseudoapatite” from Halsbrücke near Freiberg/Saxony, Neues Jahrbuch für Mineralogie, Abhandlungen, 164, 211-227
Jeanjean J, Vincent U, Fedorov M (1994) Structural modification of calcium hydroxyapatite induced by sorption of cadmium ions, Journal of Solid State Chemistry, 108, 68-72
Kikuchi M, Yamazaki A, Otsuka R, Akao M, Aoki H (1994) Crystal structure of Sr-substituted hydroxyapatite synthesized by hydrothermal method, Journal of Solid State Chemistry, 113, 373-378
Jeanjean J, McGrellis S, Rouchaud J C, Fedorov M, Rondeau A, Perocheau S, Dubis A (1996) A crystallographic study of the sorption of cadmium on calcium hydroxyapatites: incidence of cationic vacancies, Journal of Solid State Chemistry, 126, 195-201
Chakhmouradian A R, Mitchell R H (1999) Niobian ilmenite, hydroxylapatite and sulfatian monazite: alternative hosts for incompatible elements in calcite kimberlite from Internatsional'naya, Yakutia, The Canadian Mineralogist, 37, 1177-1189 [view file]
Ikoma T, Yamazaki A (1999) Preparation and structure refinement of monoclinic hydroxyapatite, Journal of Solid State Chemistry, 144, 272-276
Fleet M E, Liu X (2000) Site preference of rare earth elements in hydroxyapatite [Ca₁₀(PO₄)₆(OH)₂], Journal of Solid State Chemistry, 149, 391-398
Ivanova T I, Frank-Kamenetskaya O V, Kol'tsov A B, Ugolkov V L (2001) Crystal structure of calcium-deficient carbonated hydroxyapatite. thermal decomposition, Journal of Solid State Chemistry, 160, 340-349
Takagi S, Mathew M (2001) Structures of biological minerals in dental research, Journal of Research of the National Bureau of Standards, 106, 1035-1044 [view file]
Wilson R M, Elliott J C, Dowker S E P (2003) Formate incorporation in the structure of Ca–deficient apatite: Rietveld structure refinement, Journal of Solid State Chemistry, 174, 132-140
Roth P (2007) Hydroxylapatite, in Minerals first discovered in Switzerland and minerals named after Swiss individuals Kristallografik Verlag Achberg Germany 86-87
Burke E A J (2008) Tidying up mineral names: an IMA-CNMNC scheme for suffixes, hyphens and diacritical marks, The Mineralogical Record, 39, 131-135 [view file]
Oxmann J F, Pham Q H, Lara R J (2008) Quantification of individual phosphorus species in sediment: a sequential conversion and extraction method, European Journal of Soil Science, 59, 1177-1190 [view file]
Lee Y J, Stephens P W, Tang Y, Li W, Phillips B L, Parise J B, Reeder R J (2009) Arsenate substitution in hydroxylapatite: Structural characterization of the Ca₅(P_xAs_1-xO₄)₃OH solid solution, American Mineralogist, 94, 666-675 [view file]
Pasero M, Kampf A R, Ferraris C, Pekov I V, Rakovan J R, White T J (2010) Nomenclature of the apatite supergroup minerals, European Journal of Mineralogy, 22, 163-179 [view file]
Biagioni C, Pasero M (2013) The crystal structure of johnbaumite, Ca₅(AsO₄)₃OH, the arsenate analogue of hydroxylapatite, American Mineralogist, 98, 1580-1584
Ulian G, Valdrè G, Corno M, Ugliengo P (2013) The vibrational features of hydroxylapatite and type A carbonated apatite: A first principle contribution, American Mineralogist, 98, 752-759
Hovis G L, McCubbin F M, Nekvasil H, Ustunisik G, Woerner W R, Lindsley D H (2014) A novel technique for fluorapatite synthesis and the thermodynamic mixing behavior of F-OH apatite crystalline solutions, American Mineralogist, 99, 890-897
Hovis G L, Scott B T, Altomare C M, Leaman A R, Morris M D, Tomaino G P, McCubbin F M (2014) Thermal expansion of fluorapatite-hydroxylapatite crystalline solutions, American Mineralogist, 99, 2171-2175
Hughes J M (2015) The many facets of apatite, American Mineralogist, 100, 1033-1039
Banno Y, Miyawaki R, Momma K, Bunno M (2016) A CO₃-bearing member of the hydroxylapatite-hydroxylellestadite series from Tadano, Fukushima Prefecture, Japan: CO₃-SO₄ substitution in the apatite-ellestadite series, Mineralogical Magazine, 80, 363-370
Hughes J M, Harlov D, Kelly S R, Rakovan J, Wilke M (2016) Solid solution in the apatite OH-Cl binary system: Compositional dependence of solid-solution mechanisms in calcium phosphate apatites along the Cl-OH binary, American Mineralogist, 101, 1783-1791
Antonakos A, Liarokapis E, Kyriacou A, Leventouri T (2017) Raman and IR studies of the effect of Fe substitution in hydroxyapatites and deuterated hydroxyapatite, American Mineralogist, 102, 85-91
Hughes J M, Harlov D, Rakovan J F (2018) Structural variations along the apatite F-OH join, American Mineralogist, 103, 1981-1987
Fau A, Beyssac O, Gauthier M, Panczer G, Gasnault O, Meslin P Y, Bernard S, Maurice S, Forni O, Boulliard J C, Bosc F, Drouet C (2022) Time-resolved Raman and luminescence spectroscopy of synthetic REE-doped hydroxylapatites and natural apatites, American Mineralogist, 107, 1341-1352

REFERENCES for Hydroxylapatite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Damour A A (1856) Sur l'hydro-apatite, espèce minérale, Annales des Mines, 10, 65-68 [view file]

Schaller W T (1912) Mineralogical notes, Series 2. Mineralogy of the French phosphorites, U.S. Geological Survey Bulletin, 509, 89-100 [view file]

Foshag W F (1936) New mineral names, American Mineralogist, 21, 269-272 [view file]

Kay M I, Young R A, Posner A S (1964) Crystal structure of hydroxyapatite, Nature, 204, 1050-1052

Jullmann H, Mosebach R (1966) Zur Synthese, Licht- und Doppelbrechung des Hydroxylapatits, Zeitschrift für Naturforschung B Chemical Science, 21, 493-494 [view file]

Sudarsanan K, Young R A (1969) Significant precision in crystal structural details: Holly Springs hydroxyapatite, Acta Crystallographica, B25, 1534-1543

Dickens B, Brown W E, Kruger G J, Stewart J M (1973) Ca₄(PO₄)₂O, tetracalcium diphosphate monooxide. Crystal structure and relationships to Ca₅(PO₄)₃OH and K₃Na(SO₄)₂, Acta Crystallographica, B29, 2046-2056

Elliot J C, Mackie P E, Young R A (1973) Monoclinic hydroxyapatite, Science, 180, 1055-1057

Fiore S, Lavanio R (1991) Brushite, hydroxylapatite, and taranakite from Apulian caves (southern Italy): New mineralogical data, American Mineralogist, 76, 1722-1727 [view file]

Nasdala L (1992) A Raman study on the so-called “pseudoapatite” from Halsbrücke near Freiberg/Saxony, Neues Jahrbuch für Mineralogie, Abhandlungen, 164, 211-227

Jeanjean J, Vincent U, Fedorov M (1994) Structural modification of calcium hydroxyapatite induced by sorption of cadmium ions, Journal of Solid State Chemistry, 108, 68-72

Kikuchi M, Yamazaki A, Otsuka R, Akao M, Aoki H (1994) Crystal structure of Sr-substituted hydroxyapatite synthesized by hydrothermal method, Journal of Solid State Chemistry, 113, 373-378

Jeanjean J, McGrellis S, Rouchaud J C, Fedorov M, Rondeau A, Perocheau S, Dubis A (1996) A crystallographic study of the sorption of cadmium on calcium hydroxyapatites: incidence of cationic vacancies, Journal of Solid State Chemistry, 126, 195-201

Chakhmouradian A R, Mitchell R H (1999) Niobian ilmenite, hydroxylapatite and sulfatian monazite: alternative hosts for incompatible elements in calcite kimberlite from Internatsional'naya, Yakutia, The Canadian Mineralogist, 37, 1177-1189 [view file]

Ikoma T, Yamazaki A (1999) Preparation and structure refinement of monoclinic hydroxyapatite, Journal of Solid State Chemistry, 144, 272-276

Fleet M E, Liu X (2000) Site preference of rare earth elements in hydroxyapatite [Ca₁₀(PO₄)₆(OH)₂], Journal of Solid State Chemistry, 149, 391-398

Ivanova T I, Frank-Kamenetskaya O V, Kol'tsov A B, Ugolkov V L (2001) Crystal structure of calcium-deficient carbonated hydroxyapatite. thermal decomposition, Journal of Solid State Chemistry, 160, 340-349

Takagi S, Mathew M (2001) Structures of biological minerals in dental research, Journal of Research of the National Bureau of Standards, 106, 1035-1044 [view file]

Wilson R M, Elliott J C, Dowker S E P (2003) Formate incorporation in the structure of Ca–deficient apatite: Rietveld structure refinement, Journal of Solid State Chemistry, 174, 132-140

Roth P (2007) Hydroxylapatite, in Minerals first discovered in Switzerland and minerals named after Swiss individuals Kristallografik Verlag Achberg Germany 86-87

Burke E A J (2008) Tidying up mineral names: an IMA-CNMNC scheme for suffixes, hyphens and diacritical marks, The Mineralogical Record, 39, 131-135 [view file]

Oxmann J F, Pham Q H, Lara R J (2008) Quantification of individual phosphorus species in sediment: a sequential conversion and extraction method, European Journal of Soil Science, 59, 1177-1190 [view file]

Lee Y J, Stephens P W, Tang Y, Li W, Phillips B L, Parise J B, Reeder R J (2009) Arsenate substitution in hydroxylapatite: Structural characterization of the Ca₅(P_xAs_1-xO₄)₃OH solid solution, American Mineralogist, 94, 666-675 [view file]

Pasero M, Kampf A R, Ferraris C, Pekov I V, Rakovan J R, White T J (2010) Nomenclature of the apatite supergroup minerals, European Journal of Mineralogy, 22, 163-179 [view file]

Biagioni C, Pasero M (2013) The crystal structure of johnbaumite, Ca₅(AsO₄)₃OH, the arsenate analogue of hydroxylapatite, American Mineralogist, 98, 1580-1584

Ulian G, Valdrè G, Corno M, Ugliengo P (2013) The vibrational features of hydroxylapatite and type A carbonated apatite: A first principle contribution, American Mineralogist, 98, 752-759

Hovis G L, McCubbin F M, Nekvasil H, Ustunisik G, Woerner W R, Lindsley D H (2014) A novel technique for fluorapatite synthesis and the thermodynamic mixing behavior of F-OH apatite crystalline solutions, American Mineralogist, 99, 890-897

Hovis G L, Scott B T, Altomare C M, Leaman A R, Morris M D, Tomaino G P, McCubbin F M (2014) Thermal expansion of fluorapatite-hydroxylapatite crystalline solutions, American Mineralogist, 99, 2171-2175

Hughes J M (2015) The many facets of apatite, American Mineralogist, 100, 1033-1039

Banno Y, Miyawaki R, Momma K, Bunno M (2016) A CO₃-bearing member of the hydroxylapatite-hydroxylellestadite series from Tadano, Fukushima Prefecture, Japan: CO₃-SO₄ substitution in the apatite-ellestadite series, Mineralogical Magazine, 80, 363-370

Hughes J M, Harlov D, Kelly S R, Rakovan J, Wilke M (2016) Solid solution in the apatite OH-Cl binary system: Compositional dependence of solid-solution mechanisms in calcium phosphate apatites along the Cl-OH binary, American Mineralogist, 101, 1783-1791

Antonakos A, Liarokapis E, Kyriacou A, Leventouri T (2017) Raman and IR studies of the effect of Fe substitution in hydroxyapatites and deuterated hydroxyapatite, American Mineralogist, 102, 85-91

Hughes J M, Harlov D, Rakovan J F (2018) Structural variations along the apatite F-OH join, American Mineralogist, 103, 1981-1987

Fau A, Beyssac O, Gauthier M, Panczer G, Gasnault O, Meslin P Y, Bernard S, Maurice S, Forni O, Boulliard J C, Bosc F, Drouet C (2022) Time-resolved Raman and luminescence spectroscopy of synthetic REE-doped hydroxylapatites and natural apatites, American Mineralogist, 107, 1341-1352