Wollastonite R120122 - RRUFF Database: Raman, X-ray, Infrared, and Chemistry

Important Update News

The RRUFF Project is being updated to improve its interface and content. The beta version of the update is accessible to the public at RRUFF.net. New data is only being added to the beta site. Please note that it is in development, and some components are not functional. Existing RRUFF.info links will resolve to the new site after RRUFF.net is officially released.

We are grateful to NASA for the funding of this effort.

Wollastonite R120122

Name: Wollastonite
RRUFF ID: R120122
Ideal Chemistry: CaSiO₃
Locality: Fuka mine, Bicchu-cho, Okayama Prefecture, Japan
Source: Marcus Origlieri
Owner: RRUFF
Description: Colorless platy, frozen in matrix, polytype 2M, associated with perovskite R120121, spurrite and gehlenite
Status: The identification of this mineral has been confirmed by single-crystal X-ray diffraction.

Mineral Group: [ Wollastonite (6) ]

Quick search: [ All Wollastonite samples (4) ]

RAMAN SPECTRUM

RRUFF ID:

Sample Description:

Unoriented sample

DOWNLOADS:

To download sample data,
please select a specific
orientation angle.

BROAD SCAN WITH SPECTRAL ARTIFACTS

RRUFF ID:

R120122

Wavelength:

Sample Description:

Unoriented sample

Instrument settings:

Thermo Almega XR 532nm @ 100% of 150mW

DOWNLOADS:

	Raman Data (Processed)
	RRUFF File

POWDER DIFFRACTION

RRUFF ID:

R120122.9

Sample Description:

Single crystal, powder profile is calculated

Cell Refinement Output:

a: 15.440(1)Å b: 7.3288(8)Å c: 7.0757(7)Å
alpha: 90° beta: 95.409(6)° gamma: 90° Volume: 797.1(2)Å³ Crystal System: monoclinic

File Type Information

Calculated diffraction file.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

DOWNLOADS:

	DIF File
	X-ray Data (XY - RAW)
	RRUFF File

REFERENCES for Wollastonite
American Mineralogist Crystal Structure Database Record: [view record]
Campmas P J L (1818) Chapitre CX. Des substances cristallisées renfermées dans les laves, in Institution Géologiques par Scipion Breislak, Volume 3 Milan 192-215 [view file]
Leman J (1818) Meionite, Nouveau Dictionnaire d'Histoire Naturelle, 20, 28-31 [view file]
von Kobell F (1843) Ueber den Spadaït, eine neue Mineralspecies, und über den Wollastonit von Capo di bove, Journal für Praktische Chemie, 30, 467-471 [view file]
von Kobell F (1843) Ueber den Spadait, eine neue Mineral-species, und über den Wollastonit von Capo di bove, Gelehrte Anzeigen der Königlich Bayerischen Akademie der Wissenschaften, 17, 945-950 [view file]
Vogt I H L (1892) Hexagonales Kalksilikat (CaSiO₃) und Wollastonit (CaSiO₃), 1, in Beiträge zur Kenntniss der Gesetze der Mineralbildung in Schmelzmassen und in den Neovulkanischen Ergussgesteinen Alb. Cammermeyer Verlag Kristiania [Oslo] 56-71 [view file]
Allen E T, White W P, Wright F E (1906) On wollastonite and psuedo-wollastonite. Polymorphic forms of calcium metasilicate, with optical study by F. E. Wright, American Journal of Science, 21, 89-108 [view file]
Bowen N L (1922) Two corrections to new data, American Mineralogist, 7, 64-66 [view file]
Simonen A (1952) Mineralogy of the wollastonites found in Finland, Bulletin de la Commission Géologique de Findlande, 27, 9-18 [view file]
Mamedov K S, Belov N V (1956) The crystal structure of wollastonite, Doklady Akademii Nauk SSSR, 107, 463-466 [view file]
International Mineralogical Association (1962) International Mineralogical Association: Commission on new minerals and mineral names, Mineralogical Magazine, 33, 260-263 [view file]
Ringwood A E, Major A (1967) Some high-pressure transformations of geophysical significance, Earth and Planetary Science Letters, 2, 106-110
Trojer F J (1967) Crystal structure of parawollastonite, Naturwissenschaften, 54, 536-536
Trojer F J (1968) The crystal structure of parawollastonite, Zeitschrift für Kristallographie, 127, 291-308 [view file]
Trojer F J (1969) The crystal structure of a high pressure polymorph of CaSiO₃, Zeitschrift für Kristallographie, 130, 185-206 [view file]
Essene E (1974) High-pressure transformations in CaSiO3, Contributions to Mineralogy and Petrology, 45, 247-250
Bailey S W (1977) Report of the I.M.A-I.U.Cr. Joint Committee on Nomenclature, American Mineralogist, 62, 411-415 [view file]
Ohashi Y, Finger L W (1978) The role of octahedral cations in pyroxenoid crystal chemistry. I. Bustamite, wollastonite, and the pectolite–schizolite–serandite series, American Mineralogist, 63, 274-288 [view file]
Fleischer M, Mandarino J A, Chao G Y (1979) New mineral names, American Mineralogist, 64, 652-659 [view file]
Machida K, Adachi G, Shiokawa J, Shimada M, Zoizumi M, Suito K, Onodera A (1982) High-pressure synthesis, crystal structures, and luminescence properties of europium (II) metasilicate and europium (II)-activated calcium and strontium metasilicates, Inorganic Chemistry, 21, 1512-1519
Henmi C, Kawahara A, Henmi K, Kusachi I, Takéuchi Y (1983) The 3T, 4T and 5T polytypes of wollastonite from Kushiro, Hiroshima Prefecture, Japan, American Mineralogist, 68, 156-163 [view file]
Ohashi, Y. (1984) Polysynthetically-twinned structures of enstatite and wollastonite, Physics and Chemistry of Minerals, 10, 217-229
Kanzaki M, Stebbins J F, Xue X (1991) Characterization of quenched high pressure phases in CaSiO3 system by XRD and 29Si NMR, Geophysical Research Letters, 18, 463-466
Nickel E H (1993) Standardization of polytype suffixes, Mineralogical Magazine, 57, 756-756 [view file]
Serghiou G C, Hammack W S (1993) Pressure-induced amorphization of wollastonite (CaSiO3) at room temperature, The Journal of Chemical Physics, 98, 9830
Nickel E H (1994) Standardisation of polytype suffixes, Mineralogy and Petrology, 50, issue 4 293-294
Barbier J, Lévy D (1997) Crystal structures of Ca₅Ge₃O₁₁ and wollastonite-type GaGeO₃, Zeitschrift für Kristallographie, 212, 519-528
Swamy V, Dubrovinsky L S, Tutti F (1997) High-temperature Raman spectra and thermal expansion of wollastonite, Journal of the American Ceramic Society, 80, issue 9 2237-2247
Swamy V, Dubrovinsky L S (1997) Thermodynamic data for the phases in the CaSiO3 system, Geochimica et Cosmochimica Acta, 61, 1181-1191
Richet P, Mysen B, Ingrin J (1998) High-temperature X-ray diffraction and Raman spectroscopy of diopside and pseudowollastonite, Physics and Chemistry of Minerals, 25, 401-414 [link]
Huang E, Chen C H, Huang T, Lin E H, Xu J (2000) Raman spectroscopic characteristics of Mg-Fe-Ca pyroxenes, American Mineralogist, 85, 473-479 [view file]
Akaogi M, Yano M, Tejima Y, Iijima M, Kojitani H (2004) High-pressure transition of diopside and wollastonite: phase equilibria and thermochemistry of CaMgSi2O6, CaSiO3 and CaSi2O5--CaTiSiO5 system, Physics of The Earth and Planetary Interiors, 143, 145-156
Brenker F E, Vollmer C, Vincze L, Vekemans B, Szymanski A, Janssens K, Szaloki I, Nasdala L, Joswig W, Kaminsky F (2006) CO2-recycling to the deep convecting mantle, Goldschmidt Conference Abstracts 2006, 2006, A39
Buzatu A, Buzgar N (2010) The Raman study of single-chain silicates, Analele Stiintifice Ale Universitatii, Al. I. Cuza Iasi Geologie, 56, 107-125 [view file]
Barkley M C, Downs R T, Yang H (2011) Structure of walstromite, BaCa₂Si₃O₉, and its relationship to CaSiO₃-walstromite and wollastonite-II, American Mineralogist, 96, 797-801 [view file]
Thompson R M, Yang H, Downs R T (2016) Ideal wollastonite and the structural relationship between the pyroxenoids and pyroxenes, American Mineralogist, 101, 2544-2553
Grey I E, Keck E, Macrae C M, Glenn A M, Mumme W G, Kampf A R, Cashion J D (2018) Secondary Zn-bearing phosphate minerals associated with alteration of phosphophyllite at Hagendorf-Süd, Bavaria, European Journal of Mineralogy, 30, 1007-1020

REFERENCES for Wollastonite

American Mineralogist Crystal Structure Database Record: [view record]

Campmas P J L (1818) Chapitre CX. Des substances cristallisées renfermées dans les laves, in Institution Géologiques par Scipion Breislak, Volume 3 Milan 192-215 [view file]

Leman J (1818) Meionite, Nouveau Dictionnaire d'Histoire Naturelle, 20, 28-31 [view file]

von Kobell F (1843) Ueber den Spadaït, eine neue Mineralspecies, und über den Wollastonit von Capo di bove, Journal für Praktische Chemie, 30, 467-471 [view file]

von Kobell F (1843) Ueber den Spadait, eine neue Mineral-species, und über den Wollastonit von Capo di bove, Gelehrte Anzeigen der Königlich Bayerischen Akademie der Wissenschaften, 17, 945-950 [view file]

Vogt I H L (1892) Hexagonales Kalksilikat (CaSiO₃) und Wollastonit (CaSiO₃), 1, in Beiträge zur Kenntniss der Gesetze der Mineralbildung in Schmelzmassen und in den Neovulkanischen Ergussgesteinen Alb. Cammermeyer Verlag Kristiania [Oslo] 56-71 [view file]

Allen E T, White W P, Wright F E (1906) On wollastonite and psuedo-wollastonite. Polymorphic forms of calcium metasilicate, with optical study by F. E. Wright, American Journal of Science, 21, 89-108 [view file]

Bowen N L (1922) Two corrections to new data, American Mineralogist, 7, 64-66 [view file]

Simonen A (1952) Mineralogy of the wollastonites found in Finland, Bulletin de la Commission Géologique de Findlande, 27, 9-18 [view file]

Mamedov K S, Belov N V (1956) The crystal structure of wollastonite, Doklady Akademii Nauk SSSR, 107, 463-466 [view file]

International Mineralogical Association (1962) International Mineralogical Association: Commission on new minerals and mineral names, Mineralogical Magazine, 33, 260-263 [view file]

Ringwood A E, Major A (1967) Some high-pressure transformations of geophysical significance, Earth and Planetary Science Letters, 2, 106-110

Trojer F J (1967) Crystal structure of parawollastonite, Naturwissenschaften, 54, 536-536

Trojer F J (1968) The crystal structure of parawollastonite, Zeitschrift für Kristallographie, 127, 291-308 [view file]

Trojer F J (1969) The crystal structure of a high pressure polymorph of CaSiO₃, Zeitschrift für Kristallographie, 130, 185-206 [view file]

Essene E (1974) High-pressure transformations in CaSiO3, Contributions to Mineralogy and Petrology, 45, 247-250

Bailey S W (1977) Report of the I.M.A-I.U.Cr. Joint Committee on Nomenclature, American Mineralogist, 62, 411-415 [view file]

Ohashi Y, Finger L W (1978) The role of octahedral cations in pyroxenoid crystal chemistry. I. Bustamite, wollastonite, and the pectolite–schizolite–serandite series, American Mineralogist, 63, 274-288 [view file]

Fleischer M, Mandarino J A, Chao G Y (1979) New mineral names, American Mineralogist, 64, 652-659 [view file]

Machida K, Adachi G, Shiokawa J, Shimada M, Zoizumi M, Suito K, Onodera A (1982) High-pressure synthesis, crystal structures, and luminescence properties of europium (II) metasilicate and europium (II)-activated calcium and strontium metasilicates, Inorganic Chemistry, 21, 1512-1519

Henmi C, Kawahara A, Henmi K, Kusachi I, Takéuchi Y (1983) The 3T, 4T and 5T polytypes of wollastonite from Kushiro, Hiroshima Prefecture, Japan, American Mineralogist, 68, 156-163 [view file]

Ohashi, Y. (1984) Polysynthetically-twinned structures of enstatite and wollastonite, Physics and Chemistry of Minerals, 10, 217-229

Kanzaki M, Stebbins J F, Xue X (1991) Characterization of quenched high pressure phases in CaSiO3 system by XRD and 29Si NMR, Geophysical Research Letters, 18, 463-466

Nickel E H (1993) Standardization of polytype suffixes, Mineralogical Magazine, 57, 756-756 [view file]

Serghiou G C, Hammack W S (1993) Pressure-induced amorphization of wollastonite (CaSiO3) at room temperature, The Journal of Chemical Physics, 98, 9830

Nickel E H (1994) Standardisation of polytype suffixes, Mineralogy and Petrology, 50, issue 4 293-294

Barbier J, Lévy D (1997) Crystal structures of Ca₅Ge₃O₁₁ and wollastonite-type GaGeO₃, Zeitschrift für Kristallographie, 212, 519-528

Swamy V, Dubrovinsky L S, Tutti F (1997) High-temperature Raman spectra and thermal expansion of wollastonite, Journal of the American Ceramic Society, 80, issue 9 2237-2247

Swamy V, Dubrovinsky L S (1997) Thermodynamic data for the phases in the CaSiO3 system, Geochimica et Cosmochimica Acta, 61, 1181-1191

Richet P, Mysen B, Ingrin J (1998) High-temperature X-ray diffraction and Raman spectroscopy of diopside and pseudowollastonite, Physics and Chemistry of Minerals, 25, 401-414 [link]

Huang E, Chen C H, Huang T, Lin E H, Xu J (2000) Raman spectroscopic characteristics of Mg-Fe-Ca pyroxenes, American Mineralogist, 85, 473-479 [view file]

Akaogi M, Yano M, Tejima Y, Iijima M, Kojitani H (2004) High-pressure transition of diopside and wollastonite: phase equilibria and thermochemistry of CaMgSi2O6, CaSiO3 and CaSi2O5--CaTiSiO5 system, Physics of The Earth and Planetary Interiors, 143, 145-156

Brenker F E, Vollmer C, Vincze L, Vekemans B, Szymanski A, Janssens K, Szaloki I, Nasdala L, Joswig W, Kaminsky F (2006) CO2-recycling to the deep convecting mantle, Goldschmidt Conference Abstracts 2006, 2006, A39

Buzatu A, Buzgar N (2010) The Raman study of single-chain silicates, Analele Stiintifice Ale Universitatii, Al. I. Cuza Iasi Geologie, 56, 107-125 [view file]

Barkley M C, Downs R T, Yang H (2011) Structure of walstromite, BaCa₂Si₃O₉, and its relationship to CaSiO₃-walstromite and wollastonite-II, American Mineralogist, 96, 797-801 [view file]

Thompson R M, Yang H, Downs R T (2016) Ideal wollastonite and the structural relationship between the pyroxenoids and pyroxenes, American Mineralogist, 101, 2544-2553

Grey I E, Keck E, Macrae C M, Glenn A M, Mumme W G, Kampf A R, Cashion J D (2018) Secondary Zn-bearing phosphate minerals associated with alteration of phosphophyllite at Hagendorf-Süd, Bavaria, European Journal of Mineralogy, 30, 1007-1020