Stibnite R050066



Name: Stibnite
RRUFF ID: R050066
Ideal Chemistry: Sb2S3
Locality: Wuling, Jiangxi Province, China
Source: Rock Currier
Owner: RRUFF
Description: Lead-gray prismatic crystal
Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis
Mineral Group: [ Stibnite (10) ]
Quick search: [ All Stibnite samples (3) ]
CHEMISTRY 
RRUFF ID: R050066.2
Sample Description: Microprobe Fragment
Measured Chemistry: Sb2.00S3.00
RAMAN SPECTRUM 
RRUFF ID:
Sample Description: Unoriented sample. The sample burned under the laser.
Instrument settings: Thermo Almega XR 532nm @ 100% of 150mW
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BROAD SCAN WITH SPECTRAL ARTIFACTS
RRUFF ID: R050066
Wavelength:
Sample Description: Unoriented sample
Instrument settings: Thermo Almega XR 532nm @ 100% of 150mW
INFRARED SPECTRUM (Attenuated Total Reflectance) 
RRUFF ID: R050066.1
Sample Description: Powder
Instrument settings: SensIR Durascope on a Nicolet Magna 860 FTIR
Resolution:
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POWDER DIFFRACTION 
RRUFF ID: R050066.1
Sample Description: Powder
Cell Refinement Output: a: 11.3118(3)Å    b: 3.8365(6)Å    c: 11.2276(7)Å
alpha: 90.°    beta: 90.°    gamma: 90.°   Volume: 487.26(8)Å3    Crystal System: orthorhombic
  File Type Information Close
Calculated diffraction file.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

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REFERENCES for Stibnite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Beudant F S (1832) Stibine, antinoine sulfuré, in Traité Élémentaire de Minéralogie, 2nd Edition Paris 421-424   [view file]

Hofmann W (1933) Die struktur der minerale der animonitgruppe, Zeitschrift für Kristallographie, 86, 225-245   [view file]

Šćavnicar S (1960) The crystal structure of stibnite. A redetermination of atomic positions, Zeitschrift für Kristallographie, 114, 85-97   [view file]

Bayliss P, Nowacki W (1972) Refinement of the crystal structure of stibnite, Sb2S3, Zeitschrift für Kristallographie, 135, 308-315   [view file]

McKee D O, McMullan J T (1975) Comment on the structure of antimony trisulfide, Zeitschrift für Kristallographie, 142, 447-449   [view file]

Olivier-Fourcade J, Maurin M, Philippot E (1983) Étude cristallochimique de système Li2S-Sb2S3, Revue de Chimie Minérale, 20, 196-213

Bonazzi P, Menchetti S, Sabelli C (1987) Structure refinement of kermesite: symmetry, twinning, and comparison with stibnite, Neues Jahrbuch für Mineralogie, Monatshefte, 1987, 557-567

Arun P, Vedeshwar A G (1996) On the structure of stibnite (Sb2S3), Journal of Materials Science, 31, 6507-6510

Lukaszewicz K, Pietraszko A, Stepien-Damm J, Grigas J, Kajokas A (1997) Crystal structure of stibnite Sb2S3 in phase II at 320 K, Polish Journal of Chemistry, 71, 390-395

Berlepsch P, Makovicky E, Balić-Žunić T (2001) Crystal chemistry of meneghinite homologues and related sulfosalts, Neues Jahrbuch für Mineralogie, Monatshefte, 2001, 115-135

Kyono A, Kimata M (2004) Structural variations induced by difference of the inert pair effect in the stibnite-bismuthinite solid solution series (Sb,Bi)2S3, American Mineralogist, 89, 932-940   [view file]

Liu J, Liu J, Li J, Xie H, Wang J, Deng J, Feng C, Qi F, Zhang N (2008) Experimental synthesis of the stibnite-antimonselite solid solution series, International Geology Review, 50, 163-176

Kharbish S, Libowitzky E, Beran A (2009) Raman spectra of isolated and interconnected pyramidal XS3 groups (X = Sb, Bi) in stibnite, bismuthinite, kermesite, stephanite and bournonite, European Journal of Mineralogy, 21, 325-333