Ferrosilite R070386

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Record 57 of 79  


Name: Ferrosilite
RRUFF ID: R070386
Ideal Chemistry: Fe2+2Si2O6
Locality: Greenland
Source: Subrata Ghose, collected by Ramberg [view label]
Owner: RRUFF
Description: Unconsolidated brown transparent cleavage fragments
Status: The identification of this mineral is confirmed by single-crystal X-ray diffraction and chemical analysis.
Mineral Group: [ pyroxene (79) ]
Quick search: [ All Ferrosilite samples (3) ]
CHEMISTRY 
RRUFF ID: R070386.2
Sample Description: Microprobe Fragment
Measured Chemistry: (Fe2+1.64Mg0.32Al0.02Ca0.02)Σ=2(Si1.98Al0.02)Σ=2O6
Microprobe Data File: [ Download Excel File ]
RAMAN SPECTRUM 
RRUFF ID:
Sample Description: Unoriented sample
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Direction of polarization of laser relative to fiducial mark:
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BROAD SCAN WITH SPECTRAL ARTIFACTS
RRUFF ID: R070386
Wavelength:
Sample Description: Unoriented sample
Instrument settings: Thermo Almega XR 532nm @ 100% of 150mW
POWDER DIFFRACTION 
RRUFF ID: R070386.9
Sample Description: Single crystal, powder profile is calculated
Cell Refinement Output: a: 18.383(1)Å    b: 9.012(1)Å    c: 5.2344(6)Å
alpha: 90°    beta: 90°    gamma: 90°   Volume: 867.2(3)Å3    Crystal System: orthorhombic
  File Type Information Close
Calculated diffraction file.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

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REFERENCES for Ferrosilite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Bowen N L (1935) “Ferrosilite” as a natural mineral, American Journal of Science, 30, 481-494   [view file]

Henry N F M (1935) Some data on the iron-rich hypersthenes, Mineralogical Magazine, 24, 221-226   [view file]

Tsurc K, Henry N F M (1937) An iron-rich optically-positive hypersthene from Manchuria, Mineralogical Magazine, 24, 527-528   [view file]

Ramberg H, DeVore G (1951) The distribution of Fe++ and Mg++ in coexisting olivines and pyroxenes, The Journal of Geology, 59, 193-210

Saxena S K, Ghose S (1971) Mg2+-Fe2+ order-disorder and the thermodynamics of the orthopyroxene crystalline solution, American Mineralogist, 56, 532-559   [view file]

Smyth J R, Burnham C W (1972) The crystal structures of high and low clinohypersthene, Earth and Planetary Science Letters, 14, 183-189

Turnock A C, Lindsley D H, Grover J E (1973) Synthesis and unit cell parameters of Ca-Mg-Fe pyroxenes, American Mineralogist, 58, 50-59   [view file]

Kjekshus A, Rakke T, Andresen A (1974) Compounds of the marcasite type crystal structure. IX. Structural data for FeAs2, FeSe2, NiAs2, NiSb2, and CuSe2, Acta Chemica Scandinavica, A28, 996-1000

Ohashi Y, Burnham C W, Finger L W (1975) The effect of Ca-Fe on the clinopyroxene crystal structure, American Mineralogist, 60, 423-434   [view file]

Sueno S, Cameron M, Prewitt C T (1976) Orthoferrosilite: High-temperature crystal chemistry, American Mineralogist, 61, 38-53   [view file]

Cameron M, Papike J J (1981) Structural and chemical variations in pyroxenes, American Mineralogist, 66, 1-50   [view file]

Sueno S, Prewitt C T (1983) Models for the phase transition between orthoferrosilite and high clinoferrosilite, Fortschritte der Mineralogie, 61, 223-241

Weber H P (1983) Ferrosilite III, the high-temperature polymorph of FeSiO3, Acta Crystallographica, C39, 1-3

Tazzoli V, Domeneghetti M C (1987) Crystal-Chemistry of Natural and Heated Aluminous Orthopyroxenes, Physics and Chemistry of Minerals, 15, 131-139

Morimoto N (1988) Nomenclature of pyroxenes, Mineralogical Magazine, 52, 535-550   [view file]

Domeneghetti M C, Molin G M, Stimpfl M, Tribaudino M (1995) Orthopyroxene from the Serra de Mage meteorite: Structure refinement and estimation of C2/c pyroxene contributions to apparent Pbca diffraction violations, American Mineralogist, 80, 923-929   [view file]

Huang E, Chen C H, Huang T, Lin E H, Xu J (2000) Raman spectroscopic characteristics of Mg-Fe-Ca pyroxenes, American Mineralogist, 85, 473-479   [view file]

Wang A, Jolliff B L, Haskin L A, Kuebler K E, Viskupic K M (2001) Characterization and comparison of structural and compositional features of planetary quadrilateral pyroxenes by Raman spectroscopy, American Mineralogist, 86, 790-806   [view file]

Nestola F, Ballaran T B, Balić-Žunić T, Secco L, Dal Negro A (2008) The high-pressure behavior of an Al- and Fe-rich natural orthopyroxene, American Mineralogist, 93, 644-652   [view file]

Papike J J, Karner J M, Shearer C K, Burger P V (2009) Silicate mineralogy of martian meteorites, Geochimica et Cosmochimica Acta, 73, 7443-7485

Stalder R, Kronz A, Schmidt B C (2009) Raman spectroscopy of synthetic (Mg,Fe)SiO3 single crystals. An analytical tool for natural orthopyroxenes, European Journal of Mineralogy, 21, 27-32

Abdu Y A, Hawthorne F C (2013) Local structure in C2/c clinopyroxenes on the hedenbergite (CaFeSi2O6)-ferrosilite (Fe2Si2O6) join: A new interpretation for the Mössbauer spectra of Ca-rich C2/c clinopyroxenes and implications for pyroxene exsolution, American Mineralogist, 98, 1227-1234

Dera P, Finkelstein G, Duffy T S, Downs R T, Meng Y, Prakapenka V, Tkachev S (2013) Metastable high-pressure transformations of orthoferrosilite Fs82, Physics of The Earth and Planetary Interiors, 181, 2914-2917   [view file]

Dohmen R, Heege J H, Becker H, Chakraborty S (2016) Fe-Mg interdiffusion in orthopyroxene, American Mineralogist, 101, 2210-2221

Nespolo M, Aroyo M I (2016) The modular structure of pyroxenes, European Journal of Mineralogy, 28, 189-203

Ohi S, Miyake A (2016) Phase transitions between high- and low-temperature orthopyroxene in the Mg2Si2O6-Fe2Si2O6 system, American Mineralogist, 101, 1414-1422

Morrison S M, Downs R T, Blake D F, Prabhu A, Eleish A, Vaniman D T, Ming D W, Rampe E B, Hazen R M, Achilles C N, Treiman A H, Yen A S, Morris R V, Bristow T F, Chipera S J, Sarrazin P C, Fendrich K V, Morookian J M, Farmer J D, Des Marais D J, Craig P I (2018) Relationships between unit-cell parameters and composition for rock-forming minerals on Earth, Mars, and other extraterrestrial bodies, American Mineralogist, 103, 848-856

Morrison S M, Downs R T, Blake D F, Vaniman D T, Ming D W, Hazen R M, Treiman A H, Achilles C N, Yen A S, Morris R V, Rampe E B, Bristow T F, Chipera S J, Sarrazin P C, Gellert R, Fendrich K V, Morookian J M, Farmer J D, Des Marais D J, Craig P I (2018) Crystal chemistry of martian minerals from Bradbury Landing through Naukluft Plateau, Gale crater, Mars, American Mineralogist, 103, 857-871