) R050370 - RRUFF Database: Raman, X-ray, Infrared, and Chemistry

Dolomite R050370

Name: Dolomite
RRUFF ID: R050370
Ideal Chemistry: CaMg(CO₃)₂
Locality: Morro Velho mine, Nova Lima, Minas Gerais, Brazil
Source: Eugene Schlepp
Owner: RRUFF
Description: Colorless bladed crystals associated with pyrrhotite and albite
Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis

Quick search: [ All Dolomite samples (10) ]

CHEMISTRY

RRUFF ID:	R050370.2
Sample Description:	Microprobe fragment
Measured Chemistry:	(Ca_0.84Fe_0.16)(Mg_0.98Mn_0.02)(CO₃)₂ ; CO₂ estimated by difference
Microprobe Data File:	[ Download Excel File ]

RAMAN SPECTRUM

RRUFF ID:

Sample Description:

Sample is oriented and mounted on a pin

Pin ID:

L01076

Orientation:

Laser parallel to a* (1 0 0). Fiducial mark perpendicular to laser is parallel to c [0 0 1].

DOWNLOADS:

To download sample data,
please select a specific
orientation angle.

BROAD SCAN WITH SPECTRAL ARTIFACTS

RRUFF ID:

R050370

Wavelength:

Sample Description:

Unoriented sample

Instrument settings:

Thermo Almega XR 532nm @ 100% of 150mW

DOWNLOADS:

	Raman Data (Processed)
	RRUFF File
	Raman Data (RAW)
	RRUFF File

INFRARED SPECTRUM (Attenuated Total Reflectance)

RRUFF ID:

R050370.1

Instrument settings:

SensIR Durascope on a Nicolet Magna 860 FTIR

Resolution:

DOWNLOADS:

	Infrared Data (Processed)
	RRUFF File

POWDER DIFFRACTION

RRUFF ID:

R050370.1

Sample Description:

Powder

Cell Refinement Output:

a: 4.8169(2)Å b: 4.8169(2)Å c: 16.0733(10)Å
alpha: 90.° beta: 90.° gamma: 120.° Volume: 322.98(3)Å³ Crystal System: hexagonal

File Type Information

Calculated diffraction file.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

DOWNLOADS:

	Cell Refinement Data
	Cell Refinement Output Data
	DIF File
	X-ray Data (XY - Processed)
	RRUFF File
	X-ray Data (XY - RAW)
	RRUFF File

REFERENCES for Dolomite
American Mineralogist Crystal Structure Database Record: [view record]
Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]
Saussure H B (1792) Analyse de la dolomie, Observations sur la Physique, sur l’Histoire Naturelle et sur les Arts, 40, 161-173 [view file]
Goldsmith J R, Graf D L (1958) Relation between lattice constants and compositions of the Ca-Mg carbonates, American Mineralogist, 43, 84-101 [view file]
Howie R A, Broadhurst F M (1958) X-ray data for dolomite and ankerite, American Mineralogist, 43, 1210-1216
Graf D L (1961) Crystallographic tables for the rhombohedral carbonates, American Mineralogist, 46, 1283-1316 [view file]
McKie D (1962) Goyazite and florencite from two African carbonatites, Mineralogical Magazine, 33, 281-297 [view file]
Trendall A F (1965) Technique for optical identification of iron-bearing dolomites: A modification and an evaluation, The Canadian Mineralogist, 8, 253-255 [view file]
Beran A, Zemann J (1977) Refinement and comparison of the crystal structures of a dolomite and of an Fe-rich ankerite, Tschermaks Mineralogische und Petrographische Mitteilungen, 24, 279-286
Jansen J B H, Feenstra A, Schuiling R D (1978) A spinel-forming reaction in aluminous dolomitic marbles of Naxos, Greece, Neues Jahrbuch für Mineralogie, Monatshefte, 1978, 145-158
Rossi P L, Rinaldi R, Simboli G (1979) Heterogeneous feldspars in the Mid–Triassic volcanic rocks of the Dolomites, The Canadian Mineralogist, 17, 33-38 [view file]
Effenberger H, Mereiter K, Zemann J (1981) Crystal structure refinements of magnesite, calcite, rhodochrosite, siderite, smithonite, and dolomite, with discussion of some aspects of the stereochemistry of calcite type carbonates, Zeitschrift für Kristallographie, 156, 233-243 [view file]
Spear F S (1982) Phase equilibria of amphibolites from the post pond volcanics, Mt. cube quadrangle, Vermont, Journal of Petrology, 23, 383-426
Meunier A, Clement J Y, Bouchet A, Beaufort D (1988) Chlorite-calcite and corrensite-dolomite crystallization during two superimposed events of hydrothermal alteration in the "Les Crêtes" granite, Vosges, France, The Canadian Mineralogist, 26, 413-422 [view file]
Milodowski A E, Morgan D J, Warne S S J (1989) Thermal analysis studies of the dolomite-ferroan dolomite-ankerite series. ΙΙ. Decomposition mechanism in flowing CO₂ atmosphere, Thermochimica Acta, 152, 279-297 [view file]
Mozley P S, Hoernle K (1990) Geochemistry of carbonate cements in the Sag River and Shublik Formation (Triassic/Jurassic), North Slope, Alaska: implications for the geochemical evolution of formation waters, Sedimentology, 37, 817-836
Lüttge A, Metz P (1991) Mechanism and kinetics of the reaction 1 dolomite + 2 quartz = 1 diopside + 2 CO₂ investigated by powder experiments, The Canadian Mineralogist, 29, 803-821 [view file]
Ondruš P, Veselovský F, Gabašová A, Hloušek J, Šrein V, Vavrín I, Skála R, Sejkora J, Drábek M (2003) Primary minerals of the Jáchymov ore district, Journal of the Czech Geological Society, 48, 19-147 [view file]
Drits V A, McCarty D K, Sakharov B, Milliken K L (2005) New insight into structural and compositional variability in some ancient excess-Ca dolomite, The Canadian Mineralogist, 43, 1255-1290 [view file]
Gunasekaran S, Anbalagan G, Pandi S (2006) Raman and infrared spectra of carbonates of calcite structure, Journal of Raman Spectroscopy, 37, 892-899
Gunter M E (2010) Defining asbestos: differences between the built and natural environments, Chimia, 64, 747-752
Rividi N, van Zuilen M, Philippot P, Ménez B, Godard G, Poidatz E (2010) Calibration of carbonate composition using micro-Raman analysis: Application to planetary surface exploration, Astrobiology, 10, 293-309
Franzolin E, Merlini M, Poli S, Schmidt M W (2012) The temperature and compositional dependence of disordering in Fe-bearing dolomites, American Mineralogist, 97, 1676-1684 [view file]
Barton I F, Yang H, Barton M D (2014) The mineralogy, geochemistry, and metallurgy of cobalt in the rhombohedral carbonates, The Canadian Mineralogist, 52, 653-669
Poli S (2014) Dolomite discloses a hidden history of subducting slabs, American Mineralogist, 99, 879-880
Merlini M, Sapelli F, Fumagalli P, Gatta G D, Lotti P, Tumiati S, Abdellatief M, Lausi A, Plaisier J, Hanfland M, Crichton W, Chantel J, Guignard J, Meneghini C, Pavese A, Poli S (2016) High-temperature and high-pressure behavior of carbonates in the ternary diagram CaCO₃-MgCO₃-FeCO₃, American Mineralogist, 101, 1423-1430
Perrin J, Vielzeuf D, Laporte D, Ricolleau A, Rossman G R, Floquet N (2016) Raman characterization of synthetic magnesian calcites, American Mineralogist, 101, 2525-2538
Giebel R J, Gauert C D K, Marks M A W, Costin G, Markl G (2017) Multi-stage formation of REE minerals in the Palabora Carbonatite Complex, South Africa, American Mineralogist, 102, 1218-1233
Solomatova N V, Asimow P D (2017) Ab initio study of the structure and stability of CaMg(CO₃)₂ at high pressure, American Mineralogist, 102, 210-215
Zucchini A, Prencipe M, Belmonte D, Comodi P (2017) Ab initio study of the dolomite to dolomite-II high-pressure phase transition, European Journal of Mineralogy, 29, 227-238
Farsang S, Facq S, Redfern S A T (2018) Raman modes of carbonate minerals as pressure and temperature gauges up to 6 GPa and 500 °C, American Mineralogist, 103, 1988-1998
Perchiazzi N, Barton I F, Vignola P (2018) Incorporation of Co in the dolomite structure: couples EPMA and single crystal structural studies of Co-rich dolomite from the Tenke-Fungurme district, Democratic Republic of Congo, The Canadian Mineralogist, 56, 151-158
Shatskiy A, Podborodnikov I V, Arefiev A V, Minin D A, Chanyshev A D, Litasov K D (2018) Revision of the CaCO₃-MgCO₃ phase diagram at 3 and 6 GPa, American Mineralogist, 103, 441-452
Zhang F, Xu H, Shelobolina E S, Konishi H, Roden E E (2021) Precipitation of low-temperature disordered dolomite induced by extracellular polymeric substances of methanogenic Archaea Methanosarcina barkeri: Implications for sedimentary dolomite formation, American Mineralogist, 106, 69-81
Wang F, Zhao C, Xu L, Liu J (2022) Effects of hydrostaticity and Mn-substitution on dolomite stability at high pressure, American Mineralogist, 107, 2234-2241

REFERENCES for Dolomite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Saussure H B (1792) Analyse de la dolomie, Observations sur la Physique, sur l’Histoire Naturelle et sur les Arts, 40, 161-173 [view file]

Goldsmith J R, Graf D L (1958) Relation between lattice constants and compositions of the Ca-Mg carbonates, American Mineralogist, 43, 84-101 [view file]

Howie R A, Broadhurst F M (1958) X-ray data for dolomite and ankerite, American Mineralogist, 43, 1210-1216

Graf D L (1961) Crystallographic tables for the rhombohedral carbonates, American Mineralogist, 46, 1283-1316 [view file]

McKie D (1962) Goyazite and florencite from two African carbonatites, Mineralogical Magazine, 33, 281-297 [view file]

Trendall A F (1965) Technique for optical identification of iron-bearing dolomites: A modification and an evaluation, The Canadian Mineralogist, 8, 253-255 [view file]

Beran A, Zemann J (1977) Refinement and comparison of the crystal structures of a dolomite and of an Fe-rich ankerite, Tschermaks Mineralogische und Petrographische Mitteilungen, 24, 279-286

Jansen J B H, Feenstra A, Schuiling R D (1978) A spinel-forming reaction in aluminous dolomitic marbles of Naxos, Greece, Neues Jahrbuch für Mineralogie, Monatshefte, 1978, 145-158

Rossi P L, Rinaldi R, Simboli G (1979) Heterogeneous feldspars in the Mid–Triassic volcanic rocks of the Dolomites, The Canadian Mineralogist, 17, 33-38 [view file]

Effenberger H, Mereiter K, Zemann J (1981) Crystal structure refinements of magnesite, calcite, rhodochrosite, siderite, smithonite, and dolomite, with discussion of some aspects of the stereochemistry of calcite type carbonates, Zeitschrift für Kristallographie, 156, 233-243 [view file]

Spear F S (1982) Phase equilibria of amphibolites from the post pond volcanics, Mt. cube quadrangle, Vermont, Journal of Petrology, 23, 383-426

Meunier A, Clement J Y, Bouchet A, Beaufort D (1988) Chlorite-calcite and corrensite-dolomite crystallization during two superimposed events of hydrothermal alteration in the "Les Crêtes" granite, Vosges, France, The Canadian Mineralogist, 26, 413-422 [view file]

Milodowski A E, Morgan D J, Warne S S J (1989) Thermal analysis studies of the dolomite-ferroan dolomite-ankerite series. ΙΙ. Decomposition mechanism in flowing CO₂ atmosphere, Thermochimica Acta, 152, 279-297 [view file]

Mozley P S, Hoernle K (1990) Geochemistry of carbonate cements in the Sag River and Shublik Formation (Triassic/Jurassic), North Slope, Alaska: implications for the geochemical evolution of formation waters, Sedimentology, 37, 817-836

Lüttge A, Metz P (1991) Mechanism and kinetics of the reaction 1 dolomite + 2 quartz = 1 diopside + 2 CO₂ investigated by powder experiments, The Canadian Mineralogist, 29, 803-821 [view file]

Ondruš P, Veselovský F, Gabašová A, Hloušek J, Šrein V, Vavrín I, Skála R, Sejkora J, Drábek M (2003) Primary minerals of the Jáchymov ore district, Journal of the Czech Geological Society, 48, 19-147 [view file]

Drits V A, McCarty D K, Sakharov B, Milliken K L (2005) New insight into structural and compositional variability in some ancient excess-Ca dolomite, The Canadian Mineralogist, 43, 1255-1290 [view file]

Gunasekaran S, Anbalagan G, Pandi S (2006) Raman and infrared spectra of carbonates of calcite structure, Journal of Raman Spectroscopy, 37, 892-899

Gunter M E (2010) Defining asbestos: differences between the built and natural environments, Chimia, 64, 747-752

Rividi N, van Zuilen M, Philippot P, Ménez B, Godard G, Poidatz E (2010) Calibration of carbonate composition using micro-Raman analysis: Application to planetary surface exploration, Astrobiology, 10, 293-309

Franzolin E, Merlini M, Poli S, Schmidt M W (2012) The temperature and compositional dependence of disordering in Fe-bearing dolomites, American Mineralogist, 97, 1676-1684 [view file]

Barton I F, Yang H, Barton M D (2014) The mineralogy, geochemistry, and metallurgy of cobalt in the rhombohedral carbonates, The Canadian Mineralogist, 52, 653-669

Poli S (2014) Dolomite discloses a hidden history of subducting slabs, American Mineralogist, 99, 879-880

Merlini M, Sapelli F, Fumagalli P, Gatta G D, Lotti P, Tumiati S, Abdellatief M, Lausi A, Plaisier J, Hanfland M, Crichton W, Chantel J, Guignard J, Meneghini C, Pavese A, Poli S (2016) High-temperature and high-pressure behavior of carbonates in the ternary diagram CaCO₃-MgCO₃-FeCO₃, American Mineralogist, 101, 1423-1430

Perrin J, Vielzeuf D, Laporte D, Ricolleau A, Rossman G R, Floquet N (2016) Raman characterization of synthetic magnesian calcites, American Mineralogist, 101, 2525-2538

Giebel R J, Gauert C D K, Marks M A W, Costin G, Markl G (2017) Multi-stage formation of REE minerals in the Palabora Carbonatite Complex, South Africa, American Mineralogist, 102, 1218-1233

Solomatova N V, Asimow P D (2017) Ab initio study of the structure and stability of CaMg(CO₃)₂ at high pressure, American Mineralogist, 102, 210-215

Zucchini A, Prencipe M, Belmonte D, Comodi P (2017) Ab initio study of the dolomite to dolomite-II high-pressure phase transition, European Journal of Mineralogy, 29, 227-238

Farsang S, Facq S, Redfern S A T (2018) Raman modes of carbonate minerals as pressure and temperature gauges up to 6 GPa and 500 °C, American Mineralogist, 103, 1988-1998

Perchiazzi N, Barton I F, Vignola P (2018) Incorporation of Co in the dolomite structure: couples EPMA and single crystal structural studies of Co-rich dolomite from the Tenke-Fungurme district, Democratic Republic of Congo, The Canadian Mineralogist, 56, 151-158

Shatskiy A, Podborodnikov I V, Arefiev A V, Minin D A, Chanyshev A D, Litasov K D (2018) Revision of the CaCO₃-MgCO₃ phase diagram at 3 and 6 GPa, American Mineralogist, 103, 441-452

Zhang F, Xu H, Shelobolina E S, Konishi H, Roden E E (2021) Precipitation of low-temperature disordered dolomite induced by extracellular polymeric substances of methanogenic Archaea Methanosarcina barkeri: Implications for sedimentary dolomite formation, American Mineralogist, 106, 69-81

Wang F, Zhao C, Xu L, Liu J (2022) Effects of hydrostaticity and Mn-substitution on dolomite stability at high pressure, American Mineralogist, 107, 2234-2241