) R050489 - RRUFF Database: Raman, X-ray, Infrared, and Chemistry

Vesuvianite R050489

Name: Vesuvianite
RRUFF ID: R050489
Ideal Chemistry: (Ca,Na)₁₉(Al,Mg,Fe)₁₃(SiO₄)₁₀(Si₂O₇)₄(OH,F,O)₁₀
Locality: Crestmore Quarry, Riverside County, California, USA
Source: California Institute of Technology W-20938
Owner: RRUFF
Description: Green prismatic crystal
Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis

Mineral Group: [ Vesuvianite (12) ]

Quick search: [ All Vesuvianite samples (9) ]

CHEMISTRY

RRUFF ID:	R050489.2
Sample Description:	Microprobe Fragment
Measured Chemistry:	Ca_19.00(Al_9.56Mg_2.36Fe²⁺_0.86Ti_0.22)_Σ=13Si_18.00O₆₈((OH)_9.59F_0.41)_Σ=10 ; B not measured

RAMAN SPECTRUM

RRUFF ID:

Sample Description:

Unoriented sample

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To download sample data,
please select a specific
orientation angle.

BROAD SCAN WITH SPECTRAL ARTIFACTS

RRUFF ID:

R050489

Wavelength:

Sample Description:

Unoriented sample

Instrument settings:

Thermo Almega XR 532nm @ 80% of 150mW

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	Raman Data (Processed)
	RRUFF File
	Raman Data (RAW)
	RRUFF File

INFRARED SPECTRUM (Attenuated Total Reflectance)

RRUFF ID:

R050489.1

Sample Description:

Powder

Instrument settings:

SensIR Durascope on a Nicolet Magna 860 FTIR

Resolution:

DOWNLOADS:

	Infrared Data (Processed)
	RRUFF File

RRUFF ID:

R050489.1

Sample Description:

Powder

Instrument settings:

PIKE GladiATR - Far-IR on a Nicolet Magna 860 FTIR

Resolution:

DOWNLOADS:

	Infrared Data (Processed)
	RRUFF File

POWDER DIFFRACTION

RRUFF ID:

R050489.1

Sample Description:

Powder

Cell Refinement Output:

a: 15.5943(8)Å b: 15.5943(8)Å c: 11.829(1)Å
alpha: 90.° beta: 90.° gamma: 90.° Volume: 2876.7(2)Å³ Crystal System: tetragonal

File Type Information

Calculated diffraction file.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

DOWNLOADS:

	Cell Refinement Data
	Cell Refinement Output Data
	DIF File
	X-ray Data (XY - Processed)
	RRUFF File
	X-ray Data (XY - RAW)
	RRUFF File

REFERENCES for Vesuvianite
American Mineralogist Crystal Structure Database Record: [view record]
Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]
Klaproth M H (1795) Vesuvian, hellbrauner, Beiträge zur Chemischen Kenntniss der Mineralkörper, 1, 34-35 [view file]
Manning P G, Tricker M J (1975) Optical-absorption and Mössbauer spectral studies of iron and titanium site-populations in vesuvianites, The Canadian Mineralogist, 13, 259-265 [view file]
Manning P G (1975) Charge-transfer processes and the origin of colour and pleochroism of some titanium-rich vesuvianites, The Canadian Mineralogist, 13, 110-116 [view file]
Rucklidge J C, Kocman V, Whitlow S H, Gabe E J (1975) The crystal structures of three Canadian vesuvianites, The Canadian Mineralogist, 13, 15-21 [view file]
Manning P G (1976) Ferrous-ferric interaction on adjacent face-sharing anti-prismatic sites in vesuvianites: Evidence for ferric ion in eight coordination, The Canadian Mineralogist, 14, 216-220 [view file]
Manning P G (1977) Charge-transfer interactions and the origin of color in brown vesuvianite, The Canadian Mineralogist, 15, 508-511 [view file]
Watters W A, Brooks R R (1982) Idocrase from the Boutadiol Valley, near Quérigut, France, Mineralogical Magazine, 46, 510-512 [view file]
Nickel E H, Mandarino J A (1987) Procedures involving the IMA Commission on New Minerals and Mineral Names and guidelines on mineral nomenclature, American Mineralogist, 72, 1031-1042 [view file]
Allen F M, Burnham C W (1992) A comprehensive structure-model for vesuvianite: symmetry variations and crystal growth, The Canadian Mineralogist, 30, 1-18 [view file]
Groat L A, Hawthorne F C, Ercit T S (1992) The chemistry of vesuvianite, The Canadian Mineralogist, 30, 19-48 [view file]
Groat L A, Hawthorne F C, Ercit T S (1992) The role of fluorine in vesuvianite: a crystal-structure study, The Canadian Mineralogist, 30, 1065-1075 [view file]
Ohkawa M, Yoshiasa A, Takeno S (1992) Crystal chemistry of vesuvianite: site preferences of square-pyramidal coordinated sites, American Mineralogist, 77, 945-953 [view file]
Eby R K, Janeczek J, Ewing R C, Ercit T S, Groat L A, Chakoumakos B C, Hawthorne F C, Rossman G R (1993) Metamict and chemically altered vesuvianite, The Canadian Mineralogist, 31, 357-369 [view file]
Groat L A, Hawthorne F C, Ercit T S, Putnis A (1993) The symmetry of vesuvianite, The Canadian Mineralogist, 31, 617-635 [view file]
Groat L A, Hawthorne F C, Ercit T S (1994) Excess Y-group cations in the crystal structure of vesuvianite, The Canadian Mineralogist, 32, 497-504 [view file]
Groat L A, Hawthorne F C, Ercit T S (1994) The incorporation of boron into the vesuvianite structure, The Canadian Mineralogist, 32, 505-523 [view file]
Gibson R L, Wallmach T, De Bruin D (1995) Complex zoning in vesuvianite from the Conigou massif, Pyrénées, France, The Canadian Mineralogist, 33, 77-84 [view file]
Groat L A, Hawthorne F C, Rossman G R, Ercit T S (1995) The infrared spectroscopy of vesuvianite in the OH region, The Canadian Mineralogist, 33, 609-626 [view file]
Groat L A, Hawthorne F C, Lager G A, Schultz A J, Ercit T S (1996) X-ray and neutron crystal-structure refinements of a boron-bearing vesuvianite, The Canadian Mineralogist, 34, 1059-1070 [view file]
Bogoch R, Kumarapeli S, Matthews A (1997) High-pressure K-feldspar – vesuvianite-bearing assemblage in the Central Metasedimentary Belt of the Grenville Province, Saint Jovite area, Quebec, The Canadian Mineralogist, 35, 1269-1275 [view file]
Pavese A, Prencipe M, Tribaudino M, Aagaard S S (1998) X-ray and neutron single-crystal study of P4/n vesuvianite, The Canadian Mineralogist, 36, 1029-1037 [view file]
Lager G A, Xie Q, Ross F K, Rossman G R, Armbruster T, Rotella F J, Schultz A J (1999) Hydrogen-atom positions in P4/nnc vesuvianite, The Canadian Mineralogist, 37, 763-768 [view file]
Armbruster T, Gnos E (2000) Tetrahedral vacancies and cation ordering in low-temperature Mn-bearing vesuvianites: Indication of a hydrogarnet-like substitution, American Mineralogist, 85, 570-577
Tribaudino M, Prencipe M (2001) The compressional behavior of P4/n vesuvianite, The Canadian Mineralogist, 39, 145-151 [view file]
Shannon R D, Shannon R C, Medenbach O, Fischer R X (2002) Refractive index and dispersion of fluorides and oxides, Journal of Physical and Chemical Reference Data, 31, 931-970 [view file]
Tanaka T, Akizuki M, Kudoh Y (2002) Optical properties and crystal structure of triclinic growth sectors in vesuvianite, Mineralogical Magazine, 66, 261-274 [view file]
Galuskin E V, Galuskina I O, Sitarz M, Stadnicka K (2003) Si-deficient, OH-substituted, boron-bearing vesuvianite from the Wiluy River, Yakutia, Russia, The Canadian Mineralogist, 41, 833-842 [view file]
Kurazhkovskaya V S, Borovikova E Y, Dorokhova G I, Kononov O V, Stefanovich S Y (2003) IR spectra of high-symmetric and low-symmetric vesuvianites, Zapiski Vserossijskogo Mineralogicheskogo Obshchestva, 132, issue 1 109-121 [view file]
Kurazhkovskaya V S, Borovikova Y Y (2003) OH groups in vesuvianites from skarns and rodingites: infrared spectroscopy research, Zapiski Vserossijskogo Mineralogicheskogo Obshchestva, 132, issue 6 54-59 [view file]
Gnos E, Armbruster T (2006) Relationship among metamorphic grade, vesuvianite "rod polytypism," and vesuvianite composition, American Mineralogist, 91, 862-870 [view file]
Galuskin E V, Galuskina I O, Stadnicka K, Armbruster T, Kozanecki M (2007) The crystal structure of Si-deficient, OH-substituted, boron-bearing vesuvianite from the Wiluy River, Sakha-Yakutia, Russia, The Canadian Mineralogist, 45, 239-248 [view file]
Balassone G, Talla D, Beran A, Mormone A, Altomare A, Moliterni A, Mondillo N, Saviano M, Petti C (2011) Vesuvianite from Somma-Vesuvius volcano (southern Italy): chemical, X-ray diffraction and single-crystal polarized FTIR investigations, Periodico di Mineralogia, 80, 369-384
Groat L A, Evans R J (2012) Crystal chemistry of Bi- and Mn-bearing vesuvianite from Långban, Sweden, American Mineralogist, 97, 1627-1634 [view file]
Groat L A, Evans R J, Cempírek J, McCammon C, Houzar S (2013) Fe-rich and As-bearing vesuvianite and wiluite from Kozlov, Czech Republic, American Mineralogist, 98, 1330-1337
Hålenius U, Bosi F, Gatedal K (2013) Crystal structure and chemistry of skarn-associated bismuthian vesuvianite, American Mineralogist, 98, 566-573
Lai X, Zhu F, Qin S, Li Y, Liu J, Wu X (2013) Compressibility of a natural P4/nnc vesuvianite, European Journal of Mineralogy, 25, 631-637
Fitzgerald S, Leavens P B, Rossman G R, Yap G P A, Rose T (2016) Vesuvianite from Pajsberg, Sweden, and the role of Be in the vesuvianite structure, The Canadian Mineralogist, 54, 1525-1537
Panikorovskii T L, Krivovichev S V, Galuskin E V, Shilovskikh V V, Mazur A S, Bazai A V (2016) Si-deficient, OH-substituted, boron-bearing vesuvianite from Sakha-Yakutia, Russia: a combined single-crystal, ¹H MAS-NMR and IR spectroscopic study, European Journal of Mineralogy, 28, 931-941
Panikorovskii T L, Chukanov N V, Aksenov S M, Mazur A S, Avdontseva E Y, Shilovskikh V V, Krivovichev S V (2017) Alumovesuvianite, Ca₁₉Al(Al,Mg)₁₂Si₁₈O₆₉(OH)₉, a new vesuvianite-group member from the Jeffrey mine, Asbestos, Estrie region, Québec, Mineralogy and Petrology, 6, 833-842 [view file]

REFERENCES for Vesuvianite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Klaproth M H (1795) Vesuvian, hellbrauner, Beiträge zur Chemischen Kenntniss der Mineralkörper, 1, 34-35 [view file]

Manning P G, Tricker M J (1975) Optical-absorption and Mössbauer spectral studies of iron and titanium site-populations in vesuvianites, The Canadian Mineralogist, 13, 259-265 [view file]

Manning P G (1975) Charge-transfer processes and the origin of colour and pleochroism of some titanium-rich vesuvianites, The Canadian Mineralogist, 13, 110-116 [view file]

Rucklidge J C, Kocman V, Whitlow S H, Gabe E J (1975) The crystal structures of three Canadian vesuvianites, The Canadian Mineralogist, 13, 15-21 [view file]

Manning P G (1976) Ferrous-ferric interaction on adjacent face-sharing anti-prismatic sites in vesuvianites: Evidence for ferric ion in eight coordination, The Canadian Mineralogist, 14, 216-220 [view file]

Manning P G (1977) Charge-transfer interactions and the origin of color in brown vesuvianite, The Canadian Mineralogist, 15, 508-511 [view file]

Watters W A, Brooks R R (1982) Idocrase from the Boutadiol Valley, near Quérigut, France, Mineralogical Magazine, 46, 510-512 [view file]

Nickel E H, Mandarino J A (1987) Procedures involving the IMA Commission on New Minerals and Mineral Names and guidelines on mineral nomenclature, American Mineralogist, 72, 1031-1042 [view file]

Allen F M, Burnham C W (1992) A comprehensive structure-model for vesuvianite: symmetry variations and crystal growth, The Canadian Mineralogist, 30, 1-18 [view file]

Groat L A, Hawthorne F C, Ercit T S (1992) The chemistry of vesuvianite, The Canadian Mineralogist, 30, 19-48 [view file]

Groat L A, Hawthorne F C, Ercit T S (1992) The role of fluorine in vesuvianite: a crystal-structure study, The Canadian Mineralogist, 30, 1065-1075 [view file]

Ohkawa M, Yoshiasa A, Takeno S (1992) Crystal chemistry of vesuvianite: site preferences of square-pyramidal coordinated sites, American Mineralogist, 77, 945-953 [view file]

Eby R K, Janeczek J, Ewing R C, Ercit T S, Groat L A, Chakoumakos B C, Hawthorne F C, Rossman G R (1993) Metamict and chemically altered vesuvianite, The Canadian Mineralogist, 31, 357-369 [view file]

Groat L A, Hawthorne F C, Ercit T S, Putnis A (1993) The symmetry of vesuvianite, The Canadian Mineralogist, 31, 617-635 [view file]

Groat L A, Hawthorne F C, Ercit T S (1994) Excess Y-group cations in the crystal structure of vesuvianite, The Canadian Mineralogist, 32, 497-504 [view file]

Groat L A, Hawthorne F C, Ercit T S (1994) The incorporation of boron into the vesuvianite structure, The Canadian Mineralogist, 32, 505-523 [view file]

Gibson R L, Wallmach T, De Bruin D (1995) Complex zoning in vesuvianite from the Conigou massif, Pyrénées, France, The Canadian Mineralogist, 33, 77-84 [view file]

Groat L A, Hawthorne F C, Rossman G R, Ercit T S (1995) The infrared spectroscopy of vesuvianite in the OH region, The Canadian Mineralogist, 33, 609-626 [view file]

Groat L A, Hawthorne F C, Lager G A, Schultz A J, Ercit T S (1996) X-ray and neutron crystal-structure refinements of a boron-bearing vesuvianite, The Canadian Mineralogist, 34, 1059-1070 [view file]

Bogoch R, Kumarapeli S, Matthews A (1997) High-pressure K-feldspar – vesuvianite-bearing assemblage in the Central Metasedimentary Belt of the Grenville Province, Saint Jovite area, Quebec, The Canadian Mineralogist, 35, 1269-1275 [view file]

Pavese A, Prencipe M, Tribaudino M, Aagaard S S (1998) X-ray and neutron single-crystal study of P4/n vesuvianite, The Canadian Mineralogist, 36, 1029-1037 [view file]

Lager G A, Xie Q, Ross F K, Rossman G R, Armbruster T, Rotella F J, Schultz A J (1999) Hydrogen-atom positions in P4/nnc vesuvianite, The Canadian Mineralogist, 37, 763-768 [view file]

Armbruster T, Gnos E (2000) Tetrahedral vacancies and cation ordering in low-temperature Mn-bearing vesuvianites: Indication of a hydrogarnet-like substitution, American Mineralogist, 85, 570-577

Tribaudino M, Prencipe M (2001) The compressional behavior of P4/n vesuvianite, The Canadian Mineralogist, 39, 145-151 [view file]

Shannon R D, Shannon R C, Medenbach O, Fischer R X (2002) Refractive index and dispersion of fluorides and oxides, Journal of Physical and Chemical Reference Data, 31, 931-970 [view file]

Tanaka T, Akizuki M, Kudoh Y (2002) Optical properties and crystal structure of triclinic growth sectors in vesuvianite, Mineralogical Magazine, 66, 261-274 [view file]

Galuskin E V, Galuskina I O, Sitarz M, Stadnicka K (2003) Si-deficient, OH-substituted, boron-bearing vesuvianite from the Wiluy River, Yakutia, Russia, The Canadian Mineralogist, 41, 833-842 [view file]

Kurazhkovskaya V S, Borovikova E Y, Dorokhova G I, Kononov O V, Stefanovich S Y (2003) IR spectra of high-symmetric and low-symmetric vesuvianites, Zapiski Vserossijskogo Mineralogicheskogo Obshchestva, 132, issue 1 109-121 [view file]

Kurazhkovskaya V S, Borovikova Y Y (2003) OH groups in vesuvianites from skarns and rodingites: infrared spectroscopy research, Zapiski Vserossijskogo Mineralogicheskogo Obshchestva, 132, issue 6 54-59 [view file]

Gnos E, Armbruster T (2006) Relationship among metamorphic grade, vesuvianite "rod polytypism," and vesuvianite composition, American Mineralogist, 91, 862-870 [view file]

Galuskin E V, Galuskina I O, Stadnicka K, Armbruster T, Kozanecki M (2007) The crystal structure of Si-deficient, OH-substituted, boron-bearing vesuvianite from the Wiluy River, Sakha-Yakutia, Russia, The Canadian Mineralogist, 45, 239-248 [view file]

Balassone G, Talla D, Beran A, Mormone A, Altomare A, Moliterni A, Mondillo N, Saviano M, Petti C (2011) Vesuvianite from Somma-Vesuvius volcano (southern Italy): chemical, X-ray diffraction and single-crystal polarized FTIR investigations, Periodico di Mineralogia, 80, 369-384

Groat L A, Evans R J (2012) Crystal chemistry of Bi- and Mn-bearing vesuvianite from Långban, Sweden, American Mineralogist, 97, 1627-1634 [view file]

Groat L A, Evans R J, Cempírek J, McCammon C, Houzar S (2013) Fe-rich and As-bearing vesuvianite and wiluite from Kozlov, Czech Republic, American Mineralogist, 98, 1330-1337

Hålenius U, Bosi F, Gatedal K (2013) Crystal structure and chemistry of skarn-associated bismuthian vesuvianite, American Mineralogist, 98, 566-573

Lai X, Zhu F, Qin S, Li Y, Liu J, Wu X (2013) Compressibility of a natural P4/nnc vesuvianite, European Journal of Mineralogy, 25, 631-637

Fitzgerald S, Leavens P B, Rossman G R, Yap G P A, Rose T (2016) Vesuvianite from Pajsberg, Sweden, and the role of Be in the vesuvianite structure, The Canadian Mineralogist, 54, 1525-1537

Panikorovskii T L, Krivovichev S V, Galuskin E V, Shilovskikh V V, Mazur A S, Bazai A V (2016) Si-deficient, OH-substituted, boron-bearing vesuvianite from Sakha-Yakutia, Russia: a combined single-crystal, ¹H MAS-NMR and IR spectroscopic study, European Journal of Mineralogy, 28, 931-941

Panikorovskii T L, Chukanov N V, Aksenov S M, Mazur A S, Avdontseva E Y, Shilovskikh V V, Krivovichev S V (2017) Alumovesuvianite, Ca₁₉Al(Al,Mg)₁₂Si₁₈O₆₉(OH)₉, a new vesuvianite-group member from the Jeffrey mine, Asbestos, Estrie region, Québec, Mineralogy and Petrology, 6, 833-842 [view file]