) R060218 - RRUFF Database: Raman, X-ray, Infrared, and Chemistry

Ancylite-(Ce) R060218

Name: Ancylite-(Ce)
RRUFF ID: R060218
Ideal Chemistry: CeSr(CO₃)₂(OH)·H₂O
Locality: Mont Saint-Hilaire, Rouville County, Quebec, Canada
Source: Royal Ontario Museum M40089 [view label]
Owner: RRUFF
Description: Pale pink prismatic crystals
Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis

Mineral Group: [ Ancylite (6) ]

CHEMISTRY

RRUFF ID:	R060218.2
Sample Description:	Microprobe fragment
Measured Chemistry:	(Ce_0.40(La,Pr)_0.23Ca_0.18Nd_0.10Sr_0.09)_Σ=1CO₃((OH)_0.67(H₂O)_0.27F_0.06)_Σ=1
Microprobe Data File:	[ Download Excel File ]

RAMAN SPECTRUM

RRUFF ID:

Sample Description:

Unoriented sample

DOWNLOADS:

To download sample data,
please select a specific
orientation angle.

BROAD SCAN WITH SPECTRAL ARTIFACTS

RRUFF ID:

R060218

Wavelength:

Sample Description:

Unoriented sample

Instrument settings:

Thermo Almega XR 532nm @ 100% of 150mW

DOWNLOADS:

	Raman Data (RAW)
	RRUFF File

POWDER DIFFRACTION

RRUFF ID:

R060218.9

Sample Description:

Single crystal, powder profile is calculated

Cell Refinement Output:

a: 4.992(3)Å b: 8.479(4)Å c: 7.247(4)Å
alpha: 90° beta: 90° gamma: 90° Volume: 306.74(15)Å³ Crystal System: orthorhombic

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

DOWNLOADS:

	X-ray Data (XY - Processed)
	RRUFF File

REFERENCES for Ancylite-(Ce)
American Mineralogist Crystal Structure Database Record: [view record]
Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]
Flink G (1898) Berättelse om en Mineralogisk Resa i Syd-Grönland sommaren 1897. 4. Gult anataslikt, Meddelelser om Grønland, 14, 235-235 [view file]
Flink G (1901) On the minerals from Narsarsuk on the Firth of Tunugdliarfik in Southern Greenland. 11 Ancylite, Meddelelser om Grønland, 24, 49-56 [view file]
Palache C, Berman H, Frondel C (1951) 16.2.10 Ancylite [(Ce,La)₄(Sr,Ca)₃(CO₃)₇(OH)₄·3H₂O], in Dana's System of Mineralogy, Volume II, Seventh Edition John Wiley and Sons, Inc New York 291-293
Sawyer J, Caro P, Eyring L (1973) Hydroxy-carbonates of the lanthanide elements, Revue de Chimie Minérale, 10, 93-103
Dal Negro A, Rossi G, Tazzoli V (1975) The crystal structure of ancylite, (REE)_x(Ca,Sr)_2-x(CO₃)₂(OH)_x·(2-x)H₂O, American Mineralogist, 60, 280-284 [view file]
Szymanski J T, Chao G Y (1986) The crystal structure of monoclinic ancylite, Annual Meeting of the American Crystallographic Association, 1986, 19-19 [view file]
Nickel E H, Mandarino J A (1987) Procedures involving the IMA Commission on New Minerals and Mineral Names and guidelines on mineral nomenclature, American Mineralogist, 72, 1031-1042 [view file]
Pekov I V, Petersen O V, Voloshin A V (1997) Calcio-ancylite-(Ce) from Ilímaussaq and Narssârssuk, Greenland, Kola peninsula and Polar Urals, Russia; ancylite-(Ce) - calcio-ancylite-(Ce) an isomorphous series, Neues Jahrbuch für Mineralogie, Abhandlungen, 171, 309-322
Bulakh A G, Le Bas M J, Wall F, Zaitsev A N (1998) Ancylite-bearing carbonatites of the Seblyavr massif, Kola peninsula, Russia, Neues Jahrbuch für Mineralogie, Monatshefte, 1998, 171-192
Zaitsev A N, Wall F, Le Bas M J (1998) REE-Sr-Ba minerals from the Khibina carbonatites, Kola Peninsula, Russia: their mineralogy, paragenesis and evolution, Mineralogical Magazine, 62(2), 225-250 [view file]
Belovitskaya Y V, Pekov I V, Gobechiya E R, Yamnova N A, Kabalov Y K, Chukanov N V, Schneider J (2002) Crystal structures of two ancylite modifications, Crystallography Reports, 47, issue 2 223-228
Xu Y, Ding S-H, Feng W-J, Zhou G-P, Liu Y-G (2006) Samarium(III) carbonate hydroxide, Acta Crystallographica, E62, i147-i149
Tahara T, Nakai I, Miyawaki R, Matsubara S (2007) Crystal chemistry of RE(CO₃)OH, Zeitschrift für Kristallographie, 222, 326-334
Xiong D-B, Zhao Y-F, Gulay L D, Zhao J-T (2009) Lanthanum phosphite microspheres: hydrothermal synthesis, ab initio structure determination, morphology and photoluminescence of La(HO)(HPO₃), European Journal of Inorganic Chemistry, 2009, 4522–4527
Sheu H S, Shih W J, Chuang W T, Li I F, Yeh C S (2010) Crystal structure and phase transitions of Gd(CO₃)OH studied by synchrotron powder diffraction, Journal of the Chinese Chemical Society, 57, 938-945
Giebel R J, Gauert C D K, Marks M A W, Costin G, Markl G (2017) Multi-stage formation of REE minerals in the Palabora Carbonatite Complex, South Africa, American Mineralogist, 102, 1218-1233

REFERENCES for Ancylite-(Ce)

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Flink G (1898) Berättelse om en Mineralogisk Resa i Syd-Grönland sommaren 1897. 4. Gult anataslikt, Meddelelser om Grønland, 14, 235-235 [view file]

Flink G (1901) On the minerals from Narsarsuk on the Firth of Tunugdliarfik in Southern Greenland. 11 Ancylite, Meddelelser om Grønland, 24, 49-56 [view file]

Palache C, Berman H, Frondel C (1951) 16.2.10 Ancylite [(Ce,La)₄(Sr,Ca)₃(CO₃)₇(OH)₄·3H₂O], in Dana's System of Mineralogy, Volume II, Seventh Edition John Wiley and Sons, Inc New York 291-293

Sawyer J, Caro P, Eyring L (1973) Hydroxy-carbonates of the lanthanide elements, Revue de Chimie Minérale, 10, 93-103

Dal Negro A, Rossi G, Tazzoli V (1975) The crystal structure of ancylite, (REE)_x(Ca,Sr)_2-x(CO₃)₂(OH)_x·(2-x)H₂O, American Mineralogist, 60, 280-284 [view file]

Szymanski J T, Chao G Y (1986) The crystal structure of monoclinic ancylite, Annual Meeting of the American Crystallographic Association, 1986, 19-19 [view file]

Nickel E H, Mandarino J A (1987) Procedures involving the IMA Commission on New Minerals and Mineral Names and guidelines on mineral nomenclature, American Mineralogist, 72, 1031-1042 [view file]

Pekov I V, Petersen O V, Voloshin A V (1997) Calcio-ancylite-(Ce) from Ilímaussaq and Narssârssuk, Greenland, Kola peninsula and Polar Urals, Russia; ancylite-(Ce) - calcio-ancylite-(Ce) an isomorphous series, Neues Jahrbuch für Mineralogie, Abhandlungen, 171, 309-322

Bulakh A G, Le Bas M J, Wall F, Zaitsev A N (1998) Ancylite-bearing carbonatites of the Seblyavr massif, Kola peninsula, Russia, Neues Jahrbuch für Mineralogie, Monatshefte, 1998, 171-192

Zaitsev A N, Wall F, Le Bas M J (1998) REE-Sr-Ba minerals from the Khibina carbonatites, Kola Peninsula, Russia: their mineralogy, paragenesis and evolution, Mineralogical Magazine, 62(2), 225-250 [view file]

Belovitskaya Y V, Pekov I V, Gobechiya E R, Yamnova N A, Kabalov Y K, Chukanov N V, Schneider J (2002) Crystal structures of two ancylite modifications, Crystallography Reports, 47, issue 2 223-228

Xu Y, Ding S-H, Feng W-J, Zhou G-P, Liu Y-G (2006) Samarium(III) carbonate hydroxide, Acta Crystallographica, E62, i147-i149

Tahara T, Nakai I, Miyawaki R, Matsubara S (2007) Crystal chemistry of RE(CO₃)OH, Zeitschrift für Kristallographie, 222, 326-334

Xiong D-B, Zhao Y-F, Gulay L D, Zhao J-T (2009) Lanthanum phosphite microspheres: hydrothermal synthesis, ab initio structure determination, morphology and photoluminescence of La(HO)(HPO₃), European Journal of Inorganic Chemistry, 2009, 4522–4527

Sheu H S, Shih W J, Chuang W T, Li I F, Yeh C S (2010) Crystal structure and phase transitions of Gd(CO₃)OH studied by synchrotron powder diffraction, Journal of the Chinese Chemical Society, 57, 938-945

Giebel R J, Gauert C D K, Marks M A W, Costin G, Markl G (2017) Multi-stage formation of REE minerals in the Palabora Carbonatite Complex, South Africa, American Mineralogist, 102, 1218-1233