----- R050289 - RRUFF Database: Raman, X-ray, Infrared, and Chemistry

Natrojarosite R050289

Name: Natrojarosite
RRUFF ID: R050289
Ideal Chemistry: NaFe³⁺₃(SO₄)₂(OH)₆
Locality: Bristol mine, Pioche, Lincoln County, Nevada, USA
Source: Marcus Origlieri
Owner: RRUFF
Description: Mustard-colored massive
Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis

Mineral Groups: [ alunite (46) ] [ Alunite (20) ]

Quick search: [ All Natrojarosite samples (3) ]

CHEMISTRY

RRUFF ID:	R050289.2
Sample Description:	Microprobe Fragment
Measured Chemistry:	(Na_0.99K_0.01)_Σ=1Fe³⁺_3.00(S_1.00O₄)₂(OH)₆

RAMAN SPECTRUM

RRUFF ID:

Sample Description:

Unoriented sample

DOWNLOADS:

To download sample data,
please select a specific
orientation angle.

BROAD SCAN WITH SPECTRAL ARTIFACTS

RRUFF ID:

R050289

Wavelength:

Sample Description:

Unoriented sample

Instrument settings:

Thermo Almega XR 532nm @ 100% of 150mW

DOWNLOADS:

	Raman Data (RAW)
	RRUFF File

INFRARED SPECTRUM (Attenuated Total Reflectance)

RRUFF ID:

R050289.1

Sample Description:

Powder

Instrument settings:

SensIR Durascope on a Nicolet Magna 860 FTIR

Resolution:

DOWNLOADS:

	Infrared Data (Processed)
	RRUFF File

POWDER DIFFRACTION

RRUFF ID:

R050289.1

Sample Description:

Powder

Cell Refinement Output:

a: 7.3156(4)Å b: 7.3156(4)Å c: 16.6097(8)Å
alpha: 90° beta: 90° gamma: 120° Volume: 769.83(8)Å³ Crystal System: hexagonal

File Type Information

Calculated diffraction file.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

DOWNLOADS:

	Cell Refinement Data
	Cell Refinement Output Data
	DIF File
	X-ray Data (XY - Processed)
	RRUFF File
	X-ray Data (XY - RAW)
	RRUFF File

REFERENCES for Natrojarosite
American Mineralogist Crystal Structure Database Record: [view record]
Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]
Hillebrand W F, Penfield S L (1902) Some additions to the alunite-jarosite group of minerals, American Journal of Science, 164, 211-220 [view file]
Larsen E S (1921) The microscopic determination of the nonopaque minerals, U.S. Geological Survey Bulletin, 671, 5-294 [view file]
Brophy G P, Sheridan M F (1965) Sulfate studies IV: the jarosite—natrojarosite—hydronium jarosite solid solution series, American Mineralogist, 50, 1595-1607 [view file]
Menchetti S, Sabelli C (1976) Crystal chemistry of the alunite series: crystal structure refinement of alunite and synthetic jarosite, Neues Jahrbuch für Mineralogie, Monatshefte, 1976, 406-417
Scott K M (1987) Solid solution in, and classification of, gossan-derived members of the alunite-jarosite family, northwest Queensland, Australia, American Mineralogist, 72, 178-187 [view file]
Sasaki K, Tanaike O, Konno H (1998) Distinction of jarosite-group compounds by Raman spectroscopy, The Canadian Mineralogist, 36, 1225-1235 [view file]
Jambor J L (1999) Nomenclature of the alunite supergroup, The Canadian Mineralogist, 37, 1323-1341 [view file]
Frost R L, Wills R, Weier M L, Martens W (2005) Comparison of the Raman spectra of natural and synthetic K- and Na-jarosites at 298 and 77 K, Journal of Raman Spectroscopy, 36, 435-444
Frost R L, Wills R A, Weier M L, Martens W, Mills S (2006) A Raman spectroscopic study of selected natural jarosites, Spectrochimica Acta, A63, 1-8
Lane M D (2007) Mid-infrared emission spectroscopy of sulfate and sulfate-bearing minerals, American Mineralogist, 92, 1-18 [view file]
Basciano L C, Peterson R C (2008) Crystal chemistry of the natrojarosite-jarosite and natrojarosite-hydronium jarosite solid-solution: A synthetic study with full Fe site occupancy, American Mineralogist, 93, 853-862 [view file]
Murphy P J, Smith A M L, Hudson-Edwards K A, Dubbin W E, Wright K (2009) Raman and IR spectroscopic studies of alunite-supergroup compounds containing Al, Cr³⁺, Fe³⁺ and V³⁺ at the B site, The Canadian Mineralogist, 47, 663-681 [view file]
Bayliss P, Kolitsch U, Nickel E H, Pring A (2010) Alunite supergroup: recommended nomenclature, Mineralogical Magazine, 74, 919-927 [view file]
Nestola F, Mills S J, Periotto B, Scandolo L (2013) The alunite supergroup under high pressure: the case of natrojarosite, NaFe₃(SO₄)₂(OH)₆, Mineralogical Magazine, 77, 3007-3017
McCollom T M, Ehlmann B L, Wang A, Hynek B M, Moskowitz B, Berquó T S (2014) Detection of iron substitution in natroalunite-natrojarosite solid solutions and potential implications for Mars, American Mineralogist, 99, 948-964
Pitman K M, Noe Dobrea E Z, Jamieson C S, Dalton J B, Abbey W J, Joseph E C S (2014) Reflectance spectroscopy and optical functions for hydrated Fe-sulfates, American Mineralogist, 99, 1593-1603
Liu Y, Wang A (2015) Dehydration of Na-jarosite, ferricopiapite, and rhomboclase at temperatures of 50 and 95°C: implications for Martian ferric sulfates, Journal of Raman Spectroscopy, 46, 493-500
Sklute E C, Glotch T D, Piatek J L, Woerner W R, Martone A A, Kraner M L (2015) Optical constants of synthetic potassium, sodium, and hydronium jarosite, American Mineralogist, 100, 1110-1122
Cruells M, Roca A (2022) Jarosites: Formation, structure, reactivity and environmental, Metals, 12, 802 [view file]
Whitworth A J, Brand H E A, Wilson S, Grey I E, Stephen N R, Gozukara Y, Frierdich A J (2023) The occurrence of monoclinic jarosite in natural environments, American Mineralogist, 108, 584-594

REFERENCES for Natrojarosite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Hillebrand W F, Penfield S L (1902) Some additions to the alunite-jarosite group of minerals, American Journal of Science, 164, 211-220 [view file]

Larsen E S (1921) The microscopic determination of the nonopaque minerals, U.S. Geological Survey Bulletin, 671, 5-294 [view file]

Brophy G P, Sheridan M F (1965) Sulfate studies IV: the jarosite—natrojarosite—hydronium jarosite solid solution series, American Mineralogist, 50, 1595-1607 [view file]

Menchetti S, Sabelli C (1976) Crystal chemistry of the alunite series: crystal structure refinement of alunite and synthetic jarosite, Neues Jahrbuch für Mineralogie, Monatshefte, 1976, 406-417

Scott K M (1987) Solid solution in, and classification of, gossan-derived members of the alunite-jarosite family, northwest Queensland, Australia, American Mineralogist, 72, 178-187 [view file]

Sasaki K, Tanaike O, Konno H (1998) Distinction of jarosite-group compounds by Raman spectroscopy, The Canadian Mineralogist, 36, 1225-1235 [view file]

Jambor J L (1999) Nomenclature of the alunite supergroup, The Canadian Mineralogist, 37, 1323-1341 [view file]

Frost R L, Wills R, Weier M L, Martens W (2005) Comparison of the Raman spectra of natural and synthetic K- and Na-jarosites at 298 and 77 K, Journal of Raman Spectroscopy, 36, 435-444

Frost R L, Wills R A, Weier M L, Martens W, Mills S (2006) A Raman spectroscopic study of selected natural jarosites, Spectrochimica Acta, A63, 1-8

Lane M D (2007) Mid-infrared emission spectroscopy of sulfate and sulfate-bearing minerals, American Mineralogist, 92, 1-18 [view file]

Basciano L C, Peterson R C (2008) Crystal chemistry of the natrojarosite-jarosite and natrojarosite-hydronium jarosite solid-solution: A synthetic study with full Fe site occupancy, American Mineralogist, 93, 853-862 [view file]

Murphy P J, Smith A M L, Hudson-Edwards K A, Dubbin W E, Wright K (2009) Raman and IR spectroscopic studies of alunite-supergroup compounds containing Al, Cr³⁺, Fe³⁺ and V³⁺ at the B site, The Canadian Mineralogist, 47, 663-681 [view file]

Bayliss P, Kolitsch U, Nickel E H, Pring A (2010) Alunite supergroup: recommended nomenclature, Mineralogical Magazine, 74, 919-927 [view file]

Nestola F, Mills S J, Periotto B, Scandolo L (2013) The alunite supergroup under high pressure: the case of natrojarosite, NaFe₃(SO₄)₂(OH)₆, Mineralogical Magazine, 77, 3007-3017

McCollom T M, Ehlmann B L, Wang A, Hynek B M, Moskowitz B, Berquó T S (2014) Detection of iron substitution in natroalunite-natrojarosite solid solutions and potential implications for Mars, American Mineralogist, 99, 948-964

Pitman K M, Noe Dobrea E Z, Jamieson C S, Dalton J B, Abbey W J, Joseph E C S (2014) Reflectance spectroscopy and optical functions for hydrated Fe-sulfates, American Mineralogist, 99, 1593-1603

Liu Y, Wang A (2015) Dehydration of Na-jarosite, ferricopiapite, and rhomboclase at temperatures of 50 and 95°C: implications for Martian ferric sulfates, Journal of Raman Spectroscopy, 46, 493-500

Sklute E C, Glotch T D, Piatek J L, Woerner W R, Martone A A, Kraner M L (2015) Optical constants of synthetic potassium, sodium, and hydronium jarosite, American Mineralogist, 100, 1110-1122

Cruells M, Roca A (2022) Jarosites: Formation, structure, reactivity and environmental, Metals, 12, 802 [view file]

Whitworth A J, Brand H E A, Wilson S, Grey I E, Stephen N R, Gozukara Y, Frierdich A J (2023) The occurrence of monoclinic jarosite in natural environments, American Mineralogist, 108, 584-594