----- R060668 - RRUFF Database: Raman, X-ray, Infrared, and Chemistry

Löllingite R060668

Name: Löllingite
RRUFF ID: R060668
Ideal Chemistry: FeAs₂
Locality: Aghbar near Bou-Azzer, Morocco
Source: Michael Scott S101325 [view label]
Owner: RRUFF
Description: Gray metallic spears radiating in spherical aggregates, associated with arsenopyrite and skutterudite
Status: The identification of this mineral is confirmed by single-crystal X-ray diffraction and chemical analysis.

Mineral Group: [ Lollingite (8) ]

Quick search: [ All Löllingite samples (3) ]

CHEMISTRY

RRUFF ID:	R060668.2
Sample Description:	Microprobe Fragment
Measured Chemistry:	(Fe_0.80Co_0.20)(As_1.85S_0.15)
Microprobe Data File:	[ Download Excel File ]

RAMAN SPECTRUM

RRUFF ID:

Sample Description:

Unoriented primary sampe

DOWNLOADS:

To download sample data,
please select a specific
orientation angle.

BROAD SCAN WITH SPECTRAL ARTIFACTS

RRUFF ID:

R060668

Wavelength:

Sample Description:

Unoriented primary sampe

Instrument settings:

Thermo Almega XR 532nm @ 100% of 150mW

DOWNLOADS:

	Raman Data (Processed)
	RRUFF File

POWDER DIFFRACTION

RRUFF ID:

R060668.9

Sample Description:

Single crystal, powder profile is calculated

Cell Refinement Output:

a: 5.255(4)Å b: 5.943(3)Å c: 2.890(2)Å
alpha: 90° beta: 90° gamma: 90° Volume: 90.25(4)Å³ Crystal System: orthorhombic

File Type Information

Calculated diffraction file.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

DOWNLOADS:

	DIF File
	X-ray Data (XY - RAW)
	RRUFF File

REFERENCES for Löllingite
American Mineralogist Crystal Structure Database Record: [view record]
Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]
Haidinger W (1845) Zweite Klasse: Geogenide. XIII. Ordnung. Kiese II. Arsenikkies. Lölingit., in Handbuch der Bestimmenden Mineralogie Bei Braumüller and Seidel Wien 559-562 [view file]
Hillebrand W F (1884) On an interesting variety of löllingite and other minerals, American Journal of Science, 27, 343-358 [view file]
Clark L A (1962) X-ray method for rapid determination of sulfur and cobalt in loellingite, The Canadian Mineralogist, 7, 306-311 [view file]
Holseth H, Kjekshus A (1968) Compounds with the marcasite type crystal structure. I. Compositions of the binary pnictides, Acta Chemica Scandinavica, 22, 3273-3283
Nickel E H (1968) Structural stability of minerals with the pyrite, marcasite, arsenopyrite and löllingite structures, The Canadian Mineralogist, 9, 311-321 [view file]
Fleischer M (1969) New mineral names, American Mineralogist, 54, 1495-1499 [view file]
Nickel E H (1969) The application of ligand-field concepts to an understanding of the structural stabilities and solid-solution limits of sulphides and related minerals, Chemical Geology, 5, 233-241
Holseth H, Kjekshus A, Andresen A F (1970) Compounds with the marcasite type crystal structure. VI. Neutron diffraction studies of CrSb₂ and FeSb₂, Acta Chemica Scandinavica, 24, 3309-3316
Petruk W, Harris D C, Stewart J M (1971) Characteristics of the arsenides, sulpharsenides, and antimonides, The Canadian Mineralogist, 11, 150-186 [view file]
Kjekshus A, Rakke T, Andresen A (1974) Compounds of the marcasite type crystal structure. IX. Structural data for FeAs₂, FeSe₂, NiAs₂, NiSb₂, and CuSe₂, Acta Chemica Scandinavica, A28, 996-1000
Kjekshus A, Peterzéns P G, Rakke T, Andresen A F (1979) Compounds with the marcasite type crystal structure. XIII. Structural and magnetic properties of Cr_tFe_1-tAs₂, Cr_tFe_1-tSb₂, Fe_1-tNi_tAs₂ and Fe_1-t Ni_tSb₂, Acta Chemica Scandinavica, A33, 469-480
Lutz H D, Jung M, Wäschenbach G (1987) Kristallstrukturen des löllingits FeAs₂ und des pyrits RuTe₂, Zeitschrift für Anorganische und Allgemeine Chemie, 554, 87-91
Lutz H D, Muller B (1991) Lattice vibration spectra. LXVIII. Single-crystal Raman spectra of marcasite-type iron chalcogenides and pnictides, FeX₂ (X=S,Se,Te;P,As,Sb), Physics and Chemistry of Minerals, 18, 265-268
Hem S R, Makovicky E, Gervilla F (2001) Compositional trends in Fe, Co, and Ni sulfarsenides and their crystal-chemical implications: results from the Arroyo de la Cueva deposits, Ronda peridotite, southern Spain, The Canadian Mineralogist, 39, 831-853 [view file]
Ondruš P, Vavrín I, Skála R, Veselovský F (2001) Low-temperature Ni-rich löllingite from Háje, Príbram, Czech Republic. Rietveld crystal structure refinement, Neues Jahrbuch für Mineralogie, Monatshefte, 2001, 169-185
Wagner T, Lerenz J (2002) Mineralogy of complex Co-Ni-Bi vein mineralization, Bieber deposit, Spessart, Germany, Mineralogical Magazine, 66, 385-407 [view file]
Ondruš P, Veselovský F, Gabašová A, Hloušek J, Šrein V, Vavrín I, Skála R, Sejkora J, Drábek M (2003) Primary minerals of the Jáchymov ore district, Journal of the Czech Geological Society, 48, 19-147 [view file]
Hem S R, Makovicky E (2004) The system Fe-Co-Ni-As-S. II. Phase relations at in the (Fe,Co,Ni)As_1.5S_0.5 section at 650° and 500°C, The Canadian Mineralogist, 42, 63-86 [view file]
Gritzenko Y D, Spiridonov E M (2005) Minerals of continuous series rammelsbergite—loellingite and rammelsbergite—safflorite in metamorphic—hydrothermal veins of Norilsk ore field, Zapiski Rossiiskogo Mineralogicheskogo Obshchetstva, 134, issue 1 53-68 [view file]

REFERENCES for Löllingite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Haidinger W (1845) Zweite Klasse: Geogenide. XIII. Ordnung. Kiese II. Arsenikkies. Lölingit., in Handbuch der Bestimmenden Mineralogie Bei Braumüller and Seidel Wien 559-562 [view file]

Hillebrand W F (1884) On an interesting variety of löllingite and other minerals, American Journal of Science, 27, 343-358 [view file]

Clark L A (1962) X-ray method for rapid determination of sulfur and cobalt in loellingite, The Canadian Mineralogist, 7, 306-311 [view file]

Holseth H, Kjekshus A (1968) Compounds with the marcasite type crystal structure. I. Compositions of the binary pnictides, Acta Chemica Scandinavica, 22, 3273-3283

Nickel E H (1968) Structural stability of minerals with the pyrite, marcasite, arsenopyrite and löllingite structures, The Canadian Mineralogist, 9, 311-321 [view file]

Fleischer M (1969) New mineral names, American Mineralogist, 54, 1495-1499 [view file]

Nickel E H (1969) The application of ligand-field concepts to an understanding of the structural stabilities and solid-solution limits of sulphides and related minerals, Chemical Geology, 5, 233-241

Holseth H, Kjekshus A, Andresen A F (1970) Compounds with the marcasite type crystal structure. VI. Neutron diffraction studies of CrSb₂ and FeSb₂, Acta Chemica Scandinavica, 24, 3309-3316

Petruk W, Harris D C, Stewart J M (1971) Characteristics of the arsenides, sulpharsenides, and antimonides, The Canadian Mineralogist, 11, 150-186 [view file]

Kjekshus A, Rakke T, Andresen A (1974) Compounds of the marcasite type crystal structure. IX. Structural data for FeAs₂, FeSe₂, NiAs₂, NiSb₂, and CuSe₂, Acta Chemica Scandinavica, A28, 996-1000

Kjekshus A, Peterzéns P G, Rakke T, Andresen A F (1979) Compounds with the marcasite type crystal structure. XIII. Structural and magnetic properties of Cr_tFe_1-tAs₂, Cr_tFe_1-tSb₂, Fe_1-tNi_tAs₂ and Fe_1-t Ni_tSb₂, Acta Chemica Scandinavica, A33, 469-480

Lutz H D, Jung M, Wäschenbach G (1987) Kristallstrukturen des löllingits FeAs₂ und des pyrits RuTe₂, Zeitschrift für Anorganische und Allgemeine Chemie, 554, 87-91

Lutz H D, Muller B (1991) Lattice vibration spectra. LXVIII. Single-crystal Raman spectra of marcasite-type iron chalcogenides and pnictides, FeX₂ (X=S,Se,Te;P,As,Sb), Physics and Chemistry of Minerals, 18, 265-268

Hem S R, Makovicky E, Gervilla F (2001) Compositional trends in Fe, Co, and Ni sulfarsenides and their crystal-chemical implications: results from the Arroyo de la Cueva deposits, Ronda peridotite, southern Spain, The Canadian Mineralogist, 39, 831-853 [view file]

Ondruš P, Vavrín I, Skála R, Veselovský F (2001) Low-temperature Ni-rich löllingite from Háje, Príbram, Czech Republic. Rietveld crystal structure refinement, Neues Jahrbuch für Mineralogie, Monatshefte, 2001, 169-185

Wagner T, Lerenz J (2002) Mineralogy of complex Co-Ni-Bi vein mineralization, Bieber deposit, Spessart, Germany, Mineralogical Magazine, 66, 385-407 [view file]

Ondruš P, Veselovský F, Gabašová A, Hloušek J, Šrein V, Vavrín I, Skála R, Sejkora J, Drábek M (2003) Primary minerals of the Jáchymov ore district, Journal of the Czech Geological Society, 48, 19-147 [view file]

Hem S R, Makovicky E (2004) The system Fe-Co-Ni-As-S. II. Phase relations at in the (Fe,Co,Ni)As_1.5S_0.5 section at 650° and 500°C, The Canadian Mineralogist, 42, 63-86 [view file]

Gritzenko Y D, Spiridonov E M (2005) Minerals of continuous series rammelsbergite—loellingite and rammelsbergite—safflorite in metamorphic—hydrothermal veins of Norilsk ore field, Zapiski Rossiiskogo Mineralogicheskogo Obshchetstva, 134, issue 1 53-68 [view file]