15 R070515 - RRUFF Database: Raman, X-ray, Infrared, and Chemistry

Glaucophane R070515

Name: Glaucophane
RRUFF ID: R070515
Ideal Chemistry: ◻Na₂(Mg₃Al₂)Si₈O₂₂(OH)₂
Locality: La Beaume, near Turin, Piedmont, Italy
Source: James Shigley [view label]
Owner: RRUFF
Description: Black, prismatic crystals in a calcite matrix
Status: The identification of this mineral is confirmed by single-crystal X-ray diffraction and chemical analysis.

Mineral Group: [ amphibole (107) ]

Quick search: [ All Glaucophane samples (3) ]

CHEMISTRY

RRUFF ID:	R070515.2
Sample Description:	Microprobe Fragment
Measured Chemistry:	(◻_0.96Na_0.04)_Σ=1(Na_1.93Ca_0.07)_Σ=2((Mg_1.63Fe²⁺_1.41)_Σ=3.04(Al_1.00Fe³⁺_0.96)_Σ=1.96)(Si_7.93Al_0.07)_Σ=8O₂₂((OH)_1.90F_0.10)_Σ=2; OH estimated by difference and charge balance
Microprobe Data File:	[ Download Excel File ]

RAMAN SPECTRUM

RRUFF ID:

Sample Description:

Unoriented sample

DOWNLOADS:

To download sample data,
please select a specific
orientation angle.

BROAD SCAN WITH SPECTRAL ARTIFACTS

RRUFF ID:

R070515

Wavelength:

Sample Description:

Unoriented sample

Instrument settings:

Thermo Almega XR 532nm @ 100% of 150mW

DOWNLOADS:

	Raman Data (RAW)
	RRUFF File

POWDER DIFFRACTION

RRUFF ID:

R070515.9

Sample Description:

Single crystal, powder profile is calculated

Cell Refinement Output:

a: 9.622(2)Å b: 17.850(3)Å c: 5.3036(7)Å
alpha: 90° beta: 103.59(1)° gamma: 90° Volume: 885.5(2)Å³ Crystal System: monoclinic

File Type Information

Calculated diffraction file.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

DOWNLOADS:

	DIF File
	X-ray Data (XY - RAW)
	RRUFF File

REFERENCES for Glaucophane
American Mineralogist Crystal Structure Database Record: [view record]
Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]
Hausmann J F L (1845) Beiträge zur Oryktographie von Syra, Journal für Praktische Chemie, 1845, 238–241 [view file]
Borg I Y (1967) Optical properties and cell parameters in the glaucophane-riebeckite series, Contributions to Mineralogy and Petrology, 15, 67-92 [view file]
Papike J J, Clark J R, (1968) The crystal structure and cation distribution of glaucophane, American Mineralogist, 53, 1156-1173
Leake B E (1978) Nomenclature of amphiboles, American Mineralogist, 63, 1023-1052 [view file]
Leake B E, Woolley A R, Arps C E S, Birch W D, Gilbert M C, Grice J D, Hawthorne F C, Kato A, Kisch H J, Krivovichev V G, Linthout K, Laird J, Mandarino J A, Maresch W V, Nickel E H, Rock N M S, Schumacher J C, Smith D C, Stephenson N C N, Ungaretti L, Whittaker E J W, Youzhi G (1997) Nomenclature of amphiboles: report of the Subcommittee on Amphiboles of the International Mineralogical Association, Commission on New Minerals and Mineral Names, The Canadian Mineralogist, 35, 219-246 [view file]
Huang E P (2002) Raman spectroscopic study of amphiboles, Doctoral Dissertation, 1, 1-138 [view file]
Leake B E, Woolley A R, Birch W D, Burke E A J, Ferraris G, Grice J D, Hawthorne F C, Kisch H J, Krivovichev V G, Schumacher J C, Stephenson N C N, Whittaker E J W (2003) Nomenclature of amphiboles: additions and revisions to the International Mineralogical Association’s 1997 recommendations, The Canadian Mineralogist, 41, 1355-1362 [view file]
Apopei A I, Buzgar N (2010) The Raman study of amphiboles, Analele Stiintifice Ale Universitatii, Al. I. Cuza Iasi Geologie, 56, 57-83 [view file]
Jenkins D M, Ventura G D, Orberti R, Bozhilov K (2013) Synthesis and characterization of amphiboles along the tremolite-glaucophane join, American Mineralogist, 98, 588-600
Brown J M, Abramson E H (2016) Elasticity of calcium and calcium-sodium amphiboles, Physics of The Earth and Planetary Interiors, 261, 161-171
Thompson E C, Campbell A J, Liu Z (2016) In-situ infrared spectroscopic studies of hydroxyl in amphiboles at high pressure, American Mineralogist, 101, 706-712
Howe H, Pawley A R, Welch M D (2018) Sodium amphibole in the post-glaucophane high-pressure domain: The role of eckermannite, American Mineralogist, 103, 989-992
Vigliaturo R, Elkassas S M, Ventura G, Redhammer G, Ruiz-Zepeda F, O’Shea M J, Drasic G, Gieré R (2021) Multi-scale characterization of glaucophane from Chiavolino (Biella, Italy): implications for international regulations on elongate mineral particles, European Journal of Mineralogy, 33, 77-112
Tribaudino M, Hovis G L, Almer C, Leaman A (2022) Thermal expansion of minerals in the amphibole supergroup, American Mineralogist, 107, 1302-1312

REFERENCES for Glaucophane

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Hausmann J F L (1845) Beiträge zur Oryktographie von Syra, Journal für Praktische Chemie, 1845, 238–241 [view file]

Borg I Y (1967) Optical properties and cell parameters in the glaucophane-riebeckite series, Contributions to Mineralogy and Petrology, 15, 67-92 [view file]

Papike J J, Clark J R, (1968) The crystal structure and cation distribution of glaucophane, American Mineralogist, 53, 1156-1173

Leake B E (1978) Nomenclature of amphiboles, American Mineralogist, 63, 1023-1052 [view file]

Leake B E, Woolley A R, Arps C E S, Birch W D, Gilbert M C, Grice J D, Hawthorne F C, Kato A, Kisch H J, Krivovichev V G, Linthout K, Laird J, Mandarino J A, Maresch W V, Nickel E H, Rock N M S, Schumacher J C, Smith D C, Stephenson N C N, Ungaretti L, Whittaker E J W, Youzhi G (1997) Nomenclature of amphiboles: report of the Subcommittee on Amphiboles of the International Mineralogical Association, Commission on New Minerals and Mineral Names, The Canadian Mineralogist, 35, 219-246 [view file]

Huang E P (2002) Raman spectroscopic study of amphiboles, Doctoral Dissertation, 1, 1-138 [view file]

Leake B E, Woolley A R, Birch W D, Burke E A J, Ferraris G, Grice J D, Hawthorne F C, Kisch H J, Krivovichev V G, Schumacher J C, Stephenson N C N, Whittaker E J W (2003) Nomenclature of amphiboles: additions and revisions to the International Mineralogical Association’s 1997 recommendations, The Canadian Mineralogist, 41, 1355-1362 [view file]

Apopei A I, Buzgar N (2010) The Raman study of amphiboles, Analele Stiintifice Ale Universitatii, Al. I. Cuza Iasi Geologie, 56, 57-83 [view file]

Jenkins D M, Ventura G D, Orberti R, Bozhilov K (2013) Synthesis and characterization of amphiboles along the tremolite-glaucophane join, American Mineralogist, 98, 588-600

Brown J M, Abramson E H (2016) Elasticity of calcium and calcium-sodium amphiboles, Physics of The Earth and Planetary Interiors, 261, 161-171

Thompson E C, Campbell A J, Liu Z (2016) In-situ infrared spectroscopic studies of hydroxyl in amphiboles at high pressure, American Mineralogist, 101, 706-712

Howe H, Pawley A R, Welch M D (2018) Sodium amphibole in the post-glaucophane high-pressure domain: The role of eckermannite, American Mineralogist, 103, 989-992

Vigliaturo R, Elkassas S M, Ventura G, Redhammer G, Ruiz-Zepeda F, O’Shea M J, Drasic G, Gieré R (2021) Multi-scale characterization of glaucophane from Chiavolino (Biella, Italy): implications for international regulations on elongate mineral particles, European Journal of Mineralogy, 33, 77-112

Tribaudino M, Hovis G L, Almer C, Leaman A (2022) Thermal expansion of minerals in the amphibole supergroup, American Mineralogist, 107, 1302-1312