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Tennantite-(Zn) R050438

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Name: Tennantite-(Zn)
RRUFF ID: R050438
Ideal Chemistry: Cu6(Cu4Zn2)As4S13
Locality: Conception del Oro, Zecatecas, Mexico
Source: University of Arizona Mineral Museum 14712 [view label]
Owner: RRUFF
Description: Grey-black crystals associated with white quartz. The crystals appear to vary in chemistry between tennantite and tetrahedrite.
Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis
Mineral Group: [ Tetrahedrite (11) ]
Quick search: [ All Tennantite-(Zn) samples (3) ]
CHEMISTRY 
RRUFF ID: R050438.2
Sample Description: Microprobe Fragment
Measured Chemistry: (Cu9.94Zn1.51Fe0.55)(As3.58Sb0.42)S13.00; = dark phase. (Cu10.03Zn1.70Fe0.27)Σ=12(As2.01Sb1.99)Σ=4S13.00; light phase: (Cu10.03Zn1.84Fe0.13)Σ=12(Sb3.18As0.82)Σ=4S13.00 ; = gray phase
RAMAN SPECTRUM 
RRUFF ID:
Sample Description: Unoriented sample, will burn if too much intensity from the laser
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BROAD SCAN WITH SPECTRAL ARTIFACTS
RRUFF ID: R050438
Wavelength:
Sample Description: Unoriented sample, will burn if too much intensity from the laser
Instrument settings: Thermo Almega XR 532nm @ 1% of 150mW
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Raman Data (RAW) View Graph
RRUFF File
INFRARED SPECTRUM (Attenuated Total Reflectance) 
RRUFF ID: R050438.1
Instrument settings: SensIR Durascope on a Nicolet Magna 860 FTIR
Resolution:
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Infrared Data (Processed)
RRUFF File
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POWDER DIFFRACTION 
RRUFF ID: R050438.1
Sample Description: Powder
Cell Refinement Output: a: 10.2232(2)Å    b: 10.2232(2)Å    c: 10.2232(2)Å
alpha: 90.°    beta: 90.°    gamma: 90.°   Volume: 1068.47(7)Å3    Crystal System: cubic
  File Type Information Close
Calculated diffraction file.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

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Cell Refinement Data
Cell Refinement Output Data
DIF File
X-ray Data (XY - Processed)
RRUFF File
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RRUFF File
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REFERENCES for Tennantite-(Zn)

Descloizeaux P M (1855) Sur les formes cristallines de la dufrénoysite, Annales des Mines, 5, 389-398   [view file]

Wuensch, B.J., Takéuchi, Y., and Nowacki, W (1966) Refinement of the crystal structure of binnite, Cu12As4S13, Zeitschrift für Kristallographie, 123, 1-20   [view file]

Wuensch B J, Takeuchi Y, Nowaki W (1966) Refinement of the crystal structure of binnite, Cu12As4S13, Zeitschrift für Kristallographie, 123, 1-20   [view file]

Biagioni C, George L L, Cook N J, Makovicky E, Moëlo Y, Pasero M, Sejkora J, Stanley C J, Welch M D, Bosi F (2020) The tetrahedrite group: Nomenclature and classification, American Mineralogist, 105, 109-122   [view file]