Vivianite R050076



Name: Vivianite
RRUFF ID: R050076
Ideal Chemistry: Fe2+3(PO4)2·8H2O
Locality: near Canutillos mine, Potosi, Saavedra, Bolivia
Source: Rock Currier
Owner: RRUFF
Description: Green prismatic and elongated single crystal
Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis
Mineral Group: [ Vivianite (16) ]
Quick search: [ All Vivianite samples (6) ]
CHEMISTRY 
RRUFF ID: R050076.2
Sample Description: Microprobe Fragment
Measured Chemistry: (Fe2+0.99Mn0.01)3(P1.00O4)2ยท8H2O
RAMAN SPECTRUM 
RRUFF ID:
Sample Description: Unoriented sample
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BROAD SCAN WITH SPECTRAL ARTIFACTS
RRUFF ID: R050076
Wavelength:
Sample Description: Unoriented sample
Instrument settings: Thermo Almega XR 532nm @ 100% of 150mW
INFRARED SPECTRUM (Attenuated Total Reflectance) 
RRUFF ID: R050076.1
Instrument settings: SensIR Durascope on a Nicolet Magna 860 FTIR
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POWDER DIFFRACTION 
RRUFF ID: R050076.1
Sample Description: Powder
Cell Refinement Output: a: 10.129(2)Å    b: 13.416(4)Å    c: 4.681(3)Å
alpha: 90.°    beta: 104.76(3)°    gamma: 90.°   Volume: 615.2(3)Å3    Crystal System: monoclinic
  File Type Information Close
Calculated diffraction file.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

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REFERENCES for Vivianite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Werner A G (1817) Vivianit, in Letztes Mineral-System bey Craz und Gerlach, und bey Carl Gerold Freiberg und Wien 41-42   [view file]

Mori H, Ito T (1950) The structure of vivianite and symplesite, Acta Crystallographica, 3, 1-6

Faye G H (1968) The optical absorption spectra of iron in six-coordinate sites in chlorite, biotite, phlogopite and vivianite. Some aspects of pleochroism in the sheet silicates, The Canadian Mineralogist, 9, 403-425   [view file]

Mattievich E and Danon J (1977) Hydrothermal synthesis and Mössbauer studies of ferrous phosphates of the homologous series Fe32+(PO4)2(H2O)n, Journal of Inorganic and Nuclear Chemistry, 39, 569-580

Fejdi P, Poullen J F, Gaspérin M (1980) Affinement de la structure de la vivianite Fe3(PO4)2·8H2O, Bulletin de Minéralogie, 103, 135-138

Dormann J L, Gaspérin M, Poullen J F (1982) Étude structurale de la séquence d‘oxydationde la vivianite Fe3(PO4)2·8H2O, Bulletin de Minéralogie, 105, 147-160

Piriou B, Poullen J F (1984) Raman-study of vivianite, Journal of Raman Spectroscopy, 15, 343-346

Sameshima T, Henderson G S, Black P M, Rodgers K A (1985) X-ray diffraction studies of vivianite, metavivianite, and barićite, Mineralogical Magazine, 49, 81-85   [view file]

Rodgers K A (1986) Metavivianite and kerchenite: a review, Mineralogical Magazine, 50, 687-691   [view file]

Bartl H (1989) Water of crystallization and its hydrogen-bonded crosslinking in vivianite Fe3(PO4)2·8H2O; a neutron diffraction investigation, Fresenius' Zeitschrift für Analytische Chemie, 333, 401-403

Manning P G, Murphy T P, Prepas E E (1991) Intensive formation of vivianite in the bottom sediments of mesotrophic Narrow Lake, Alberta, The Canadian Mineralogist, 29, 77-85   [view file]

Rodgers K A, Kobe H W, Childs C W (1993) Characterization of vivianite from Catavi, Llallagua Bolivia, Mineralogy and Petrology, 47, 193-208   [view file]

Martincea S, Constantinescu E, Ladriere J (1997) Relatively unoxidized vivianite in limnic coal from Capeni, Baraolt Basin, Romania, The Canadian Mineralogist, 35, 713-722   [view file]

Frost R L, Martens W, Williams P A, Kloprogge J T (2002) Raman and infrared spectroscopic study of the vivianite-group phosphates vivianite, baricite, and bobierrite, Mineralogical Magazine, 66, 1063-1073   [link]   [view file]

Frankel R B, Bazylinski D A (2003) Biologically induced mineralization by bacteria, Reviews in Mineralogy and Geochemistry, 54, 95-114

Frost R L, Kloprogge T, Weier M L, Martens W N, Ding Z, Edwards H G H (2003) Raman spectroscopy of selected arsenates - implications for soil remediation, Spectrochimica Acta Part A-Molecular and Biomolecular Spectroscopy, 59, 2241-2246   [link]

Frost R L, Weier M, Lyon W G (2004) Metavivianite an intermediate mineral phase between vivianite, and ferro/ferristrunzite - a Raman spectroscopic study, Neues Jahrbuch für Mineralogie, Monatshefte, 2004, 228-240   [link]

Frost R L, Weier M (2004) Raman spectroscopic study of vivianites of different origins, Neues Jahrbuch für Mineralogie, Monatshefte, 2004, 445-463   [link]

Capitelli F, Chita G, Ghiara M R, Rossi M (2012) Crystal-chemical investigation of Fe3(PO4)2 ·8H2O vivianite minerals, Zeitschrift für Kristallographie, 227, 92-101

Dyar M D, Jawin E R, Breves E, Marchand G, Nelms M, Lane M D, Mertzman S A, Bish D L and Bishop J L (2014) Mössbauer parameters of iron in phosphate minerals: Implications for interpretation of martian data, American Mineralogist, 99, 914-942   [view file]