R050208 - RRUFF Database: Raman, X-ray, Infrared, and Chemistry

Chalcopyrite R050208

Name: Chalcopyrite
RRUFF ID: R050208
Ideal Chemistry: CuFeS₂
Locality: Kidd Creek mine, Timmins, Ontario, Canada
Source: Lloyd Twaites
Owner: RRUFF
Description: Brass yellow metallic fine-grained massive
Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis

Mineral Group: [ Chalcopyrite (6) ]

Quick search: [ All Chalcopyrite samples (4) ]

CHEMISTRY

RRUFF ID:	R050208.2
Sample Description:	Microprobe Fragment
Measured Chemistry:	Cu_1.00Fe_1.00S_2.00
Reference File:	[ View PDF ]

RAMAN SPECTRUM

RRUFF ID:

Sample Description:

Unoriented sample

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To download sample data,
please select a specific
orientation angle.

BROAD SCAN WITH SPECTRAL ARTIFACTS

RRUFF ID:

R050208

Wavelength:

Sample Description:

Unoriented sample

Instrument settings:

Thermo Almega XR 532nm @ 100% of 150mW

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	Raman Data (Processed)
	RRUFF File
	Raman Data (RAW)
	RRUFF File

INFRARED SPECTRUM (Attenuated Total Reflectance)

RRUFF ID:

R050208.1

Sample Description:

Powder

Instrument settings:

SensIR Durascope on a Nicolet Magna 860 FTIR

Resolution:

DOWNLOADS:

	Infrared Data (Processed)
	RRUFF File

RRUFF ID:

R050208.1

Sample Description:

Powder

Instrument settings:

PIKE GladiATR - Far-IR on a Nicolet Magna 860 FTIR

Resolution:

DOWNLOADS:

	Infrared Data (Processed)
	RRUFF File

POWDER DIFFRACTION

RRUFF ID:

R050208.1

Sample Description:

Powder

Cell Refinement Output:

a: 5.2892(2)Å b: 5.2892(2)Å c: 10.4202(6)Å
alpha: 90.° beta: 90.° gamma: 90.° Volume: 291.51(2)Å³ Crystal System: tetragonal

File Type Information

Calculated diffraction file.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

DOWNLOADS:

	Cell Refinement Data
	Cell Refinement Output Data
	DIF File
	X-ray Data (XY - Processed)
	RRUFF File
	X-ray Data (XY - RAW)
	RRUFF File

REFERENCES for Chalcopyrite
American Mineralogist Crystal Structure Database Record: [view record]
Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]
Henckel J F (1725) Chalcopyrites, in Pyritologia, oder Kieβ Historie Verlegts Johann Christian Martini Leipzig 114-115 [view file]
Henckel J F (1757) Chalco-pyrites, in Pyritologia: or, a history of the pyrites, the principal body in the mineral kingdom [English translation] Millar and Linde London 16-16 [view file]
Henckel J F (1775) Bom Kupfer im Kieß, in Pyritologia, oder Kieβ Historie Verlegts Johann Christian Martini Leipzig 423-455 [view file]
Hutton C O (1950) Studies of heavy detrital minerals, Bulletin of the Geological Society of America, 61, 635-710 [view file]
Mariano A N (1967) Abstract of paper presented at the twelfth annual meeting: Crystallographic polarity in chalcopyrite, The Canadian Mineralogist, 9, 297-298 [view file]
Hall S R, Stweart J M (1973) The crystal structure refinement of chalcopyrite, CuFeS₂, Acta Crystallographica, B29, 579-585
Hall S R (1975) Crystal structures of the chalcopyrite series, The Canadian Mineralogist, 13, 168-172 [view file]
Dutrizac J E (1976) Reactions in cubanite and chalcopyrite, The Canadian Mineralogist, 14, 172-181 [view file]
Oen I S, Kieft C (1976) Silver - bearing wittichenite - chalcopyrite - bornite intergrowth and associated minerals in the Mangualde pegmatite, Portugal, The Canadian Mineralogist, 14, 185-193 [view file]
Tatsuka K, Morimoto N (1977) Tetrahedrite stability relations in the Cu-Fe-Sb-S system, American Mineralogist, 62, 1101-1109 [view file]
Chen T T, Dutrizac J E, Owens D R, Laflamme J H G (1980) Accelerated tarnishing of some chalcopyrite and tennantite specimens, The Canadian Mineralogist, 18, 173-180 [view file]
Harris D C, Cabri L J, Nobiling R (1984) Silver-bearing chalcopyrite, a principal source of silver in the Izok Lake massive-sulfide deposit: confimation by electron- and proton-microprobe analyses, The Canadian Mineralogist, 22, 493-498 [view file]
Kase K (1987) Tin-bearing chalcopyrite from the Izumo vein, Toyoha mine, Hokkaido, Japan, The Canadian Mineralogist, 25, 9-13 [view file]
Jeppsson M (1988) Photochemically accellerated surface-diffusion of silver on chalcopyrite, isocubanite and pyrrhotite, The Canadian Mineralogist, 26, 973-978 [view file]
Kratz T, Fuess H (1989) Simultane strukturbestimmung von kupferkies und bornit an einem kristall, Zeitschrift für Kristallographie, 186, 167-169 [view file]
Chai G, Naldrett A J, Rucklidge J C, Kilius L R (1993) In situ quantitative analyses for PGE and Au in sulfide minerals of the Jinchuan Ni-Cu deposit by accelerator mass spectrometry, The Canadian Mineralogist, 31, 19-30 [view file]
Larocque A C L, Hodgson C J, Cabri L J, Jackman J A (1995) Ion-microprobe analysis of pyrite, chalcopyrite and pyrrhotite from the Mobrun VMS deposit in northwestern Quebec: evidence for metamorphic remobilization of gold, The Canadian Mineralogist, 33, 373-388 [view file]
Larocque A C L, Jackman J A, Cabri L J, Hodgson C J (1995) Calibration of the ion microprobe for the determination of silver in pyrite and chalcopyrite from the Mobrun VMS deposit, Rouyn-Noranda, Quebec, The Canadian Mineralogist, 33, 361-372 [view file]
Ondruš P, Veselovský F, Gabašová A, Hloušek J, Šrein V, Vavrín I, Skála R, Sejkora J, Drábek M (2003) Primary minerals of the Jáchymov ore district, Journal of the Czech Geological Society, 48, 19-147 [view file]
Gupta H C, Singh M K, Tiwari L M (2004) Zone center wavenumbers of tetragonal AGa₂X₄(A = Cd, Zn; X = S, Se), Journal of Raman Spectroscopy, 35, 78-81
Zhang W, Sang S, Xue C, Papadimitriou D (2005) Raman tensor and selection rules for a chemical vapor transport-grown chalcopyrite single crystal, Journal of Raman Spectroscopy, 36, 777-784
Goh S W, Buckley A N, Lamb R N, Rosenberg R A, Moran D (2006) The oxidation states of copper and iron in mineral sulfides, and the oxides formed on initial exposure of chalcopyrite and bornite to air, Geochimica et Cosmochimica Acta, 70, 2210-2228
Pearce C I, Pattrick R A D, Vaughan D J, Henderson C M B, van der Laan G (2006) Copper oxidation state in chalcopyrite: Mixed Cu d⁹ and d¹⁰ characteristics, Geochimica et Cosmochimica Acta, 70, 4635-4624
Gibbs G V, Cox D F, Rosso K M, Ross N L, Downs R T, Spackman M A (2007) Theoretical electron density distribution for Fe- and Cu-sulfide Earth materials: A connection between bond length, bond critical point properties, local energy densities, and bonded interactions, Journal of Physical Chemistry B, 111, 1923-1931 [view file]
Knight K S, Marshall W G, Zochowski S W (2011) The low temperature and high-pressure thermoelastic and structural properties of chalcopyrite, CuFeS₂, The Canadian Mineralogist, 49, 1015-1034 [view file]
Cai L, Chen X, Ding J, Zhou D (2012) Leaching mechanism for chalcopyrite in hydrochloric acid, Hydrometallurgy, 113-114, 109-118
Gill S B, Piercey S J, Layton-Matthews D (2016) Mineralogy and metal zoning of the Cambrian Zn-Pb-Cu-Ag-Au Lemarchant volcanogenic massive sulfide (VMS) deposit, Newfoundland, The Canadian Mineralogist, 54, 1307-1344
Giebel R J, Gauert C D K, Marks M A W, Costin G, Markl G (2017) Multi-stage formation of REE minerals in the Palabora Carbonatite Complex, South Africa, American Mineralogist, 102, 1218-1233
George L L, Cook N J, Crowe B B P, Ciobanu C L (2018) Trace elements in hydrothermal chalcopyrite, Mineralogical Magazine, 82, 59-88
Plotinskaya O Y, Abramova V D, Groznova E O, Tessalina S G, Seltmann R, Spratt J (2018) Trace-element geochemistry of molybdenite from porphyry Cu deposits of the Birgilda-Tomino ore cluster (South Urals, Russia), Mineralogical Magazine, 82, S281-S306
Markl G, Keim M F, Bayerl R (2019) Unusual mineral diversity in hydrothermal vein-type deposit: The Clara mine, SW Germany, as a type example, The Canadian Mineralogist, 57, 427-456

REFERENCES for Chalcopyrite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Henckel J F (1725) Chalcopyrites, in Pyritologia, oder Kieβ Historie Verlegts Johann Christian Martini Leipzig 114-115 [view file]

Henckel J F (1757) Chalco-pyrites, in Pyritologia: or, a history of the pyrites, the principal body in the mineral kingdom [English translation] Millar and Linde London 16-16 [view file]

Henckel J F (1775) Bom Kupfer im Kieß, in Pyritologia, oder Kieβ Historie Verlegts Johann Christian Martini Leipzig 423-455 [view file]

Hutton C O (1950) Studies of heavy detrital minerals, Bulletin of the Geological Society of America, 61, 635-710 [view file]

Mariano A N (1967) Abstract of paper presented at the twelfth annual meeting: Crystallographic polarity in chalcopyrite, The Canadian Mineralogist, 9, 297-298 [view file]

Hall S R, Stweart J M (1973) The crystal structure refinement of chalcopyrite, CuFeS₂, Acta Crystallographica, B29, 579-585

Hall S R (1975) Crystal structures of the chalcopyrite series, The Canadian Mineralogist, 13, 168-172 [view file]

Dutrizac J E (1976) Reactions in cubanite and chalcopyrite, The Canadian Mineralogist, 14, 172-181 [view file]

Oen I S, Kieft C (1976) Silver - bearing wittichenite - chalcopyrite - bornite intergrowth and associated minerals in the Mangualde pegmatite, Portugal, The Canadian Mineralogist, 14, 185-193 [view file]

Tatsuka K, Morimoto N (1977) Tetrahedrite stability relations in the Cu-Fe-Sb-S system, American Mineralogist, 62, 1101-1109 [view file]

Chen T T, Dutrizac J E, Owens D R, Laflamme J H G (1980) Accelerated tarnishing of some chalcopyrite and tennantite specimens, The Canadian Mineralogist, 18, 173-180 [view file]

Harris D C, Cabri L J, Nobiling R (1984) Silver-bearing chalcopyrite, a principal source of silver in the Izok Lake massive-sulfide deposit: confimation by electron- and proton-microprobe analyses, The Canadian Mineralogist, 22, 493-498 [view file]

Kase K (1987) Tin-bearing chalcopyrite from the Izumo vein, Toyoha mine, Hokkaido, Japan, The Canadian Mineralogist, 25, 9-13 [view file]

Jeppsson M (1988) Photochemically accellerated surface-diffusion of silver on chalcopyrite, isocubanite and pyrrhotite, The Canadian Mineralogist, 26, 973-978 [view file]

Kratz T, Fuess H (1989) Simultane strukturbestimmung von kupferkies und bornit an einem kristall, Zeitschrift für Kristallographie, 186, 167-169 [view file]

Chai G, Naldrett A J, Rucklidge J C, Kilius L R (1993) In situ quantitative analyses for PGE and Au in sulfide minerals of the Jinchuan Ni-Cu deposit by accelerator mass spectrometry, The Canadian Mineralogist, 31, 19-30 [view file]

Larocque A C L, Hodgson C J, Cabri L J, Jackman J A (1995) Ion-microprobe analysis of pyrite, chalcopyrite and pyrrhotite from the Mobrun VMS deposit in northwestern Quebec: evidence for metamorphic remobilization of gold, The Canadian Mineralogist, 33, 373-388 [view file]

Larocque A C L, Jackman J A, Cabri L J, Hodgson C J (1995) Calibration of the ion microprobe for the determination of silver in pyrite and chalcopyrite from the Mobrun VMS deposit, Rouyn-Noranda, Quebec, The Canadian Mineralogist, 33, 361-372 [view file]

Ondruš P, Veselovský F, Gabašová A, Hloušek J, Šrein V, Vavrín I, Skála R, Sejkora J, Drábek M (2003) Primary minerals of the Jáchymov ore district, Journal of the Czech Geological Society, 48, 19-147 [view file]

Gupta H C, Singh M K, Tiwari L M (2004) Zone center wavenumbers of tetragonal AGa₂X₄(A = Cd, Zn; X = S, Se), Journal of Raman Spectroscopy, 35, 78-81

Zhang W, Sang S, Xue C, Papadimitriou D (2005) Raman tensor and selection rules for a chemical vapor transport-grown chalcopyrite single crystal, Journal of Raman Spectroscopy, 36, 777-784

Goh S W, Buckley A N, Lamb R N, Rosenberg R A, Moran D (2006) The oxidation states of copper and iron in mineral sulfides, and the oxides formed on initial exposure of chalcopyrite and bornite to air, Geochimica et Cosmochimica Acta, 70, 2210-2228

Pearce C I, Pattrick R A D, Vaughan D J, Henderson C M B, van der Laan G (2006) Copper oxidation state in chalcopyrite: Mixed Cu d⁹ and d¹⁰ characteristics, Geochimica et Cosmochimica Acta, 70, 4635-4624

Gibbs G V, Cox D F, Rosso K M, Ross N L, Downs R T, Spackman M A (2007) Theoretical electron density distribution for Fe- and Cu-sulfide Earth materials: A connection between bond length, bond critical point properties, local energy densities, and bonded interactions, Journal of Physical Chemistry B, 111, 1923-1931 [view file]

Knight K S, Marshall W G, Zochowski S W (2011) The low temperature and high-pressure thermoelastic and structural properties of chalcopyrite, CuFeS₂, The Canadian Mineralogist, 49, 1015-1034 [view file]

Cai L, Chen X, Ding J, Zhou D (2012) Leaching mechanism for chalcopyrite in hydrochloric acid, Hydrometallurgy, 113-114, 109-118

Gill S B, Piercey S J, Layton-Matthews D (2016) Mineralogy and metal zoning of the Cambrian Zn-Pb-Cu-Ag-Au Lemarchant volcanogenic massive sulfide (VMS) deposit, Newfoundland, The Canadian Mineralogist, 54, 1307-1344

Giebel R J, Gauert C D K, Marks M A W, Costin G, Markl G (2017) Multi-stage formation of REE minerals in the Palabora Carbonatite Complex, South Africa, American Mineralogist, 102, 1218-1233

George L L, Cook N J, Crowe B B P, Ciobanu C L (2018) Trace elements in hydrothermal chalcopyrite, Mineralogical Magazine, 82, 59-88

Plotinskaya O Y, Abramova V D, Groznova E O, Tessalina S G, Seltmann R, Spratt J (2018) Trace-element geochemistry of molybdenite from porphyry Cu deposits of the Birgilda-Tomino ore cluster (South Urals, Russia), Mineralogical Magazine, 82, S281-S306

Markl G, Keim M F, Bayerl R (2019) Unusual mineral diversity in hydrothermal vein-type deposit: The Clara mine, SW Germany, as a type example, The Canadian Mineralogist, 57, 427-456