D R070357 - RRUFF Database: Raman, X-ray, Infrared, and Chemistry

Agardite-(Y) R070357

Name: Agardite-(Y)
RRUFF ID: R070357
Ideal Chemistry: YCu²⁺₆(AsO₄)₃(OH)₆·3H₂O
Locality: Hayashi, Setoda, Ikuchi Island, Hiroshima Prefecture, Chugoku Region, Honshu Island, Japan
Source: Michael Scott S103028 [view label]
Owner: Michael Scott
Description: Green acicular to fibrous in spherical aggregates
Status: The identification of this mineral is confirmed by single-crystal X-ray diffraction and chemical analysis.

Mineral Group: [ Mixite (10) ]

Quick search: [ All Agardite-(Y) samples (4) ]

CHEMISTRY

RRUFF ID:	R070357.2
Sample Description:	Microprobe Fragment
Measured Chemistry:	(Cu_5.59Ca_0.28Zn_0.03Fe_0.01)_Σ=5.91(Y_0.35La_0.08Nd_0.06Gd_0.03Ce_0.02Sm_0.01Pr_0.01Al_0.50)_Σ=1.05[(AsO₄)_0.80(SiO₄)_0.14(PO₄)_0.02]₃(OH)₆·3.51H₂O
Microprobe Data File:	[ Download Excel File ]

RAMAN SPECTRUM

RRUFF ID:

Sample Description:

Unoriented sample

DOWNLOADS:

To download sample data,
please select a specific
orientation angle.

BROAD SCAN WITH SPECTRAL ARTIFACTS

RRUFF ID:

R070357

Wavelength:

Sample Description:

Unoriented sample

Instrument settings:

Thermo Almega XR 532nm @ 40% of 150mW

DOWNLOADS:

	Raman Data (RAW)
	RRUFF File

POWDER DIFFRACTION

RRUFF ID:

R070357.9

Sample Description:

Powder, using Mo radiation

Cell Refinement Output:

a: 13.571(2)Å b: 13.571(2)Å c: 5.904(2)Å
alpha: 90° beta: 90° gamma: 120° Volume: 941.8(3)Å³ Crystal System: hexagonal

File Type Information

Calculated diffraction file.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

DOWNLOADS:

	Cell Refinement Data
	Cell Refinement Output Data
	DIF File
	X-ray Data (XY - Processed)
	RRUFF File
	X-ray Data (XY - RAW)
	RRUFF File

REFERENCES for Agardite-(Y)
American Mineralogist Crystal Structure Database Record: [view record]
Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]
Dietrich J E, Orliac M, Permingeat F (1969) L’agardite, une nouvelle espèce minérale, et le problème du chlorotile, Bulletin de la Société Française de Minéralogie et de Cristallographie, 92, 420-434 [view file]
Fleischer M (1970) New mineral names, American Mineralogist, 55, 1444-1449 [view file]
Hey M H (1970) Twenty-sixth list of new mineral names, Mineralogical Magazine, 37, 954-967 [view file]
Aruga A, Nakai I (1985) Structure of Ca-rich agardite, (Ca_0.40Y_0.31Fe_0.09Ce_0.06La_0.04Nd_0.01)Cu_6.19[(AsO₄)_2.42(HAsO₄)_0.49](OH)_6.38·3H₂O, Acta Crystallographica, C41, 161-163 [link]
Nickel E H, Mandarino J A (1987) Procedures involving the IMA Commission on New Minerals and Mineral Names and guidelines on mineral nomenclature, American Mineralogist, 72, 1031-1042 [view file]
Olmi F, Sabelli C, Brizzi G (1988) Agardite-(Y), Gysinite-(Nd) and other rare minerals from Sardinia, The Mineralogical Record, 19, 305-310
Brizzi G, Cocco E, Olmi F, Sabelli C (1989) Nuovi ritrovamenti di minerali nella Sardegna sud-occidentale 2°-Sa Duchessa (Domusnovas), Rivista Mineralogica Italiana, 3, 121-134
Olmi F, Sabelli C, Ferroni R T (1991) A contribution to the crystal chemistry of mixite group minerals from Sardinia (Italy), Neues Jahrbuch für Mineralogie, 1991, 487-499
Kunov A Y, Nakov R A, Stanchev C D (2002) First agardite-(Y), -(Nd), -(La) find in Bulgaria, Neues Jahrbuch für Mineralogie, Monatshefte, 2002, 107-116
Walenta K (2003) Mineralien der Mixitgruppe aus dem Schwarzwald, Der Erzgräber, 17, 46-51
Frost R L, Erickson K L, Weier M L, McKinnon A R, Williams P A, Leverett P (2004) Effect of the lanthanide ionic radius on the Raman spectroscopy of lanthanide agardite minerals, Journal of Raman Spectroscopy, 35, 961-966 [link]
Frost R L, Erickson K L, Weier M L, McKinnon A R, Williams P A, Leverett P (2005) Thermal decomposition of agardites (REE) - relationship between dehydroxylation temperature and electronegativity, Thermochimica Acta, 427, 167-170
Frost R L, McKinnon A R, Williams P A, Erickson K L, Weier M L, Leverett P (2005) Studies of natural and synthetic agardites, Neues Jahrbuch für Mineralogie, Abhandlungen, 181, 11-19
Frost R L, Weier M, Martens W (2006) Using Raman spectroscopy to identify mixite minerals, Spectrochimica Acta Part A, 63, 60-65 [link]
Plášil J, Sejkora J, Čejka J, Škoda R, Goliáš V (2009) Supergene mineralization of the Medvedín uranium deposit, Krkonoše Mountains, Czech Republic, Journal of Geosciences, 54, 15-56
Göb S, Wenzel T, Bau M, Jacob D E, Loges A, Markl G (2011) The redistribution of rare-earth elements in secondary minerals of hydrothermal veins, Schwarzwald, southwestern Germany, The Canadian Mineralogist, 49, 1305-1333 [view file]
Morrison S M, Domanik K J, Origlieri M J, Downs R T (2013) Agardite-(Y), Cu²⁺₆Y(AsO₄)₃(OH)₆·3H₂O, Acta Crystallographica, E69, i61-i62 [view file]

REFERENCES for Agardite-(Y)

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Dietrich J E, Orliac M, Permingeat F (1969) L’agardite, une nouvelle espèce minérale, et le problème du chlorotile, Bulletin de la Société Française de Minéralogie et de Cristallographie, 92, 420-434 [view file]

Fleischer M (1970) New mineral names, American Mineralogist, 55, 1444-1449 [view file]

Hey M H (1970) Twenty-sixth list of new mineral names, Mineralogical Magazine, 37, 954-967 [view file]

Aruga A, Nakai I (1985) Structure of Ca-rich agardite, (Ca_0.40Y_0.31Fe_0.09Ce_0.06La_0.04Nd_0.01)Cu_6.19[(AsO₄)_2.42(HAsO₄)_0.49](OH)_6.38·3H₂O, Acta Crystallographica, C41, 161-163 [link]

Nickel E H, Mandarino J A (1987) Procedures involving the IMA Commission on New Minerals and Mineral Names and guidelines on mineral nomenclature, American Mineralogist, 72, 1031-1042 [view file]

Olmi F, Sabelli C, Brizzi G (1988) Agardite-(Y), Gysinite-(Nd) and other rare minerals from Sardinia, The Mineralogical Record, 19, 305-310

Brizzi G, Cocco E, Olmi F, Sabelli C (1989) Nuovi ritrovamenti di minerali nella Sardegna sud-occidentale 2°-Sa Duchessa (Domusnovas), Rivista Mineralogica Italiana, 3, 121-134

Olmi F, Sabelli C, Ferroni R T (1991) A contribution to the crystal chemistry of mixite group minerals from Sardinia (Italy), Neues Jahrbuch für Mineralogie, 1991, 487-499

Kunov A Y, Nakov R A, Stanchev C D (2002) First agardite-(Y), -(Nd), -(La) find in Bulgaria, Neues Jahrbuch für Mineralogie, Monatshefte, 2002, 107-116

Walenta K (2003) Mineralien der Mixitgruppe aus dem Schwarzwald, Der Erzgräber, 17, 46-51

Frost R L, Erickson K L, Weier M L, McKinnon A R, Williams P A, Leverett P (2004) Effect of the lanthanide ionic radius on the Raman spectroscopy of lanthanide agardite minerals, Journal of Raman Spectroscopy, 35, 961-966 [link]

Frost R L, Erickson K L, Weier M L, McKinnon A R, Williams P A, Leverett P (2005) Thermal decomposition of agardites (REE) - relationship between dehydroxylation temperature and electronegativity, Thermochimica Acta, 427, 167-170

Frost R L, McKinnon A R, Williams P A, Erickson K L, Weier M L, Leverett P (2005) Studies of natural and synthetic agardites, Neues Jahrbuch für Mineralogie, Abhandlungen, 181, 11-19

Frost R L, Weier M, Martens W (2006) Using Raman spectroscopy to identify mixite minerals, Spectrochimica Acta Part A, 63, 60-65 [link]

Plášil J, Sejkora J, Čejka J, Škoda R, Goliáš V (2009) Supergene mineralization of the Medvedín uranium deposit, Krkonoše Mountains, Czech Republic, Journal of Geosciences, 54, 15-56

Göb S, Wenzel T, Bau M, Jacob D E, Loges A, Markl G (2011) The redistribution of rare-earth elements in secondary minerals of hydrothermal veins, Schwarzwald, southwestern Germany, The Canadian Mineralogist, 49, 1305-1333 [view file]

Morrison S M, Domanik K J, Origlieri M J, Downs R T (2013) Agardite-(Y), Cu²⁺₆Y(AsO₄)₃(OH)₆·3H₂O, Acta Crystallographica, E69, i61-i62 [view file]