Hydrotalcite R060527 - RRUFF Database: Raman, X-ray, Infrared, and Chemistry

Hydrotalcite R060527

Name: Hydrotalcite
RRUFF ID: R060527
Ideal Chemistry: Mg₆Al₂CO₃(OH)₁₆(H₂O)₄
Locality: Jacupiranga Pegmatite, Sao Paulo State, Brazil
Source: Michael Scott S100217 [view label]
Owner: RRUFF
Description: Orange hexagonal prisms topped with steep pyramids. 2H polytype
Status: The identification of this mineral has been confirmed only by single crystal X-ray diffraction.

Mineral Group: [ Hydrotalcite (22) ]

Quick search: [ All Hydrotalcite samples (2) ]

CHEMISTRY

RRUFF ID:	R060527.2
Sample Description:	Microprobe Fragment

RAMAN SPECTRUM

RRUFF ID:

Sample Description:

Unoriented sample

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orientation angle.

BROAD SCAN WITH SPECTRAL ARTIFACTS

RRUFF ID:

R060527

Wavelength:

Sample Description:

Unoriented sample

Instrument settings:

Thermo Almega XR 532nm @ 100% of 150mW

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	Raman Data (Processed)
	RRUFF File

POWDER DIFFRACTION

RRUFF ID:

R060527.9

Sample Description:

Single crystal, powder profile is calculated

Cell Refinement Output:

a: 3.037(3)Å b: 3.037(3)Å c: 15.08(2)Å
alpha: 90° beta: 90° gamma: 120° Volume: 120.51(4)Å³ Crystal System: hexagonal

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REFERENCES for Hydrotalcite
American Mineralogist Crystal Structure Database Record: [view record]
Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]
Hochstetter C (1842) Untersuchung über die Zusammensetzung einiger Mineralien, Journal für Praktische Chemie, 27, 375-378 [view file]
Frondel C (1941) Constitution and polymorphism of the pyroaurite and sjögrenite groups, American Mineralogist, 26, 295-315 [view file]
Caillère S (1945) Sur l'hydrotalcite de snarum (Norvège), Bulletin de la Société Française de Minéralogie et de Cristallographie, 67, 411-419 [view file]
Ross G J, Kodama H (1967) Properties of a synthetic magnesium-aluminum carbonate hydroxide and its realtionship to magnesium-aluminum double hydroxide, manasseite and hydrotalcite, American Mineralogist, 52, 1036-1047 [view file]
Allmann R, Jespen H P (1969) Die struktur des hydrotalkits, Neues Jahrbuch für Mineralogie, Monatshefte, 1969, 544-551
Taylor H F W (1973) Crystal structures of some double hydroxide minerals, Mineralogical Magazine, 39, 377-389 [view file]
Bailey S W (1977) Report of the I.M.A-I.U.Cr. Joint Committee on Nomenclature, American Mineralogist, 62, 411-415 [view file]
Bookin A S, Cherkashin V I, Drits V A (1993) Polytype diversity of the hydrotalcite-like minerals II. determination of the polytypes of experimentally studied varieties, Clays and Clay Minerals, 41, 558-564 [view file]
Bookin A S, Drits V A (1993) Polytype Diversity of the Hydrotalcite-like minerals I. Possible polytypes and their diffraction features, Clays and Clay Minerals, 41, 551-557 [view file]
Bellotto M, Rebours B, Clause O, Lynch J, Bazin D, Elkaïm E (1996) A reexamination of hydrotalcite crystal chemistry, Journal of Physical Chemistry, 100, 8527-8534
Rousselot I, Taviot-Gueho C, Leroux F, Leone P, Palvadeau P, Besse J (2002) Insights on the structural chemistry of hydrocalumite and hydrotalcite-like materials: investigation of the series Ca₂M³⁺(OH)₆Cl·2H₂O (M³⁺: Al³⁺, Ga³⁺, Fe³⁺, and Sc³⁺) by x-ray powder diffraction, Journal of Solid State Chemistry, 167, 137-144
Frost R L, Weier M L, Kloprogge J T (2003) Raman spectroscopy of some natural hydrotalcites with sulphate and carbonate in the interlayer, Journal of Raman Spectroscopy, 34, 760-768
Lozano R P, Rossi C, La Iglesia A, Matesanz E (2012) Zaccagnaite-3R, a new Zn-Al hydrotalcite polytype from El Soplao cave (Cantabria, Spain), American Mineralogist, 97, 513-523 [view file]
Mills S J, Christy A G, Génin J -M R, Kameda T, Colombo F (2012) Nomenclature of the hydrotalcite supergroup: natural layered double hydroxides, Mineralogical Magazine, 76, 1289-1336 [view file]
Mills S J, Christy A G, Kampf A R, Housley R M, Favreau G, Boulliard J -C, Bourgoin V (2012) Zincalstibite-9R: the first nine-layer polytype with the layered double hydroxide structure-type, Mineralogical Magazine, 76, 1337-1345 [view file]
Theiss F L, Ayoko G A, Frost R L (2013) Stichtite a review, Clay Minerals, 48, 143-148 [view file]
Mills S J, Christy A G, Schmitt R (2016) The creation of neotypes for hydrotalcite, Mineralogical Magazine, 80, 1023-1029 [view file]
Zhitova E S, Krivovichev S V, Pekov I, Greenwell H C (2019) Crystal chemistry of natural layered double hydroxides. 5. Single-crystal structure refinement of hydrotalcite, [Mg₆Al₂(OH)₁₆](CO₃)(H₂O)₄, Mineralogical Magazine, 83, 269-280 [view file]

REFERENCES for Hydrotalcite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Hochstetter C (1842) Untersuchung über die Zusammensetzung einiger Mineralien, Journal für Praktische Chemie, 27, 375-378 [view file]

Frondel C (1941) Constitution and polymorphism of the pyroaurite and sjögrenite groups, American Mineralogist, 26, 295-315 [view file]

Caillère S (1945) Sur l'hydrotalcite de snarum (Norvège), Bulletin de la Société Française de Minéralogie et de Cristallographie, 67, 411-419 [view file]

Ross G J, Kodama H (1967) Properties of a synthetic magnesium-aluminum carbonate hydroxide and its realtionship to magnesium-aluminum double hydroxide, manasseite and hydrotalcite, American Mineralogist, 52, 1036-1047 [view file]

Allmann R, Jespen H P (1969) Die struktur des hydrotalkits, Neues Jahrbuch für Mineralogie, Monatshefte, 1969, 544-551

Taylor H F W (1973) Crystal structures of some double hydroxide minerals, Mineralogical Magazine, 39, 377-389 [view file]

Bailey S W (1977) Report of the I.M.A-I.U.Cr. Joint Committee on Nomenclature, American Mineralogist, 62, 411-415 [view file]

Bookin A S, Cherkashin V I, Drits V A (1993) Polytype diversity of the hydrotalcite-like minerals II. determination of the polytypes of experimentally studied varieties, Clays and Clay Minerals, 41, 558-564 [view file]

Bookin A S, Drits V A (1993) Polytype Diversity of the Hydrotalcite-like minerals I. Possible polytypes and their diffraction features, Clays and Clay Minerals, 41, 551-557 [view file]

Bellotto M, Rebours B, Clause O, Lynch J, Bazin D, Elkaïm E (1996) A reexamination of hydrotalcite crystal chemistry, Journal of Physical Chemistry, 100, 8527-8534

Rousselot I, Taviot-Gueho C, Leroux F, Leone P, Palvadeau P, Besse J (2002) Insights on the structural chemistry of hydrocalumite and hydrotalcite-like materials: investigation of the series Ca₂M³⁺(OH)₆Cl·2H₂O (M³⁺: Al³⁺, Ga³⁺, Fe³⁺, and Sc³⁺) by x-ray powder diffraction, Journal of Solid State Chemistry, 167, 137-144

Frost R L, Weier M L, Kloprogge J T (2003) Raman spectroscopy of some natural hydrotalcites with sulphate and carbonate in the interlayer, Journal of Raman Spectroscopy, 34, 760-768

Lozano R P, Rossi C, La Iglesia A, Matesanz E (2012) Zaccagnaite-3R, a new Zn-Al hydrotalcite polytype from El Soplao cave (Cantabria, Spain), American Mineralogist, 97, 513-523 [view file]

Mills S J, Christy A G, Génin J -M R, Kameda T, Colombo F (2012) Nomenclature of the hydrotalcite supergroup: natural layered double hydroxides, Mineralogical Magazine, 76, 1289-1336 [view file]

Mills S J, Christy A G, Kampf A R, Housley R M, Favreau G, Boulliard J -C, Bourgoin V (2012) Zincalstibite-9R: the first nine-layer polytype with the layered double hydroxide structure-type, Mineralogical Magazine, 76, 1337-1345 [view file]

Theiss F L, Ayoko G A, Frost R L (2013) Stichtite a review, Clay Minerals, 48, 143-148 [view file]

Mills S J, Christy A G, Schmitt R (2016) The creation of neotypes for hydrotalcite, Mineralogical Magazine, 80, 1023-1029 [view file]

Zhitova E S, Krivovichev S V, Pekov I, Greenwell H C (2019) Crystal chemistry of natural layered double hydroxides. 5. Single-crystal structure refinement of hydrotalcite, [Mg₆Al₂(OH)₁₆](CO₃)(H₂O)₄, Mineralogical Magazine, 83, 269-280 [view file]