Siderite R050262

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Record 5 of 6  

Name: Siderite
RRUFF ID: R050262
Ideal Chemistry: Fe(CO3)
Locality: Panasqueira mine, Barroca Grande, Beira Baixa, Portugal
Source: Marcus Origlieri
Owner: RRUFF
Description: Group of yellowish brown flattened twinned crystals
Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis
Mineral Group: [ Calcite (36) ]
Quick search: [ All Siderite samples (6) ]
CHEMISTRY 
RRUFF ID: R050262.2
Sample Description: Microprobe Fragment
Measured Chemistry: (Fe0.71Mg0.24Mn0.05)Σ=1CO3 ; light : (Fe0.60Mg0.36Mn0.04)Σ=1CO3 ; intermediate : (Fe0.54Mg0.42Mn0.04)Σ=1CO3 ; darker : (Mg0.54Fe0.42Mn0.04)Σ=1CO3 darkest = magnesite
Microprobe Data File: [ Download Excel File ]
RAMAN SPECTRUM 
RRUFF ID:
Sample Description: Unoriented sample
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BROAD SCAN WITH SPECTRAL ARTIFACTS
RRUFF ID: R050262
Wavelength:
Sample Description: Unoriented sample
Instrument settings: Thermo Almega XR 532nm @ 100% of 150mW
INFRARED SPECTRUM (Attenuated Total Reflectance) 
RRUFF ID: R050262.1
Instrument settings: SensIR Durascope on a Nicolet Magna 860 FTIR
Resolution:
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POWDER DIFFRACTION 
RRUFF ID: R050262.1
Sample Description: Powder
Cell Refinement Output: a: 4.6774(9)Å    b: 4.6774(9)Å    c: 15.30(2)Å
alpha: 90°    beta: 90°    gamma: 120°   Volume: 289.9(0)Å3    Crystal System: hexagonal
  File Type Information Close
Calculated diffraction file.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

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REFERENCES for Siderite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Haidinger W (1845) Zweite Klasse: Geogenide. II. Ordnung. Baryte I. Parachrosbaryt. Siderit., in Handbuch der Bestimmenden Mineralogie Bei Braumüller and Seidel Wien 499-506   [view file]

International Mineralogical Association (1962) International Mineralogical Association: Commission on new minerals and mineral names, Mineralogical Magazine, 33, 260-263   [view file]

Rutt H N, Nicola J H (1974) Raman spectra of carbonates of calcite structure, Journal of Physics C: Solid State Physics, 7, 4522-4528

International Mineralogical Association (1980) International Mineralogical Association: Commission on new minerals and mineral names, Mineralogical Magazine, 43, 1053-1055   [view file]

Effenberger H, Mereiter K, Zemann J (1981) Crystal structure refinements of magnesite, calcite, rhodochrosite, siderite, smithonite, and dolomite, with discussion of some aspects of the stereochemistry of calcite type carbonates, Zeitschrift für Kristallographie, 156, 233-243   [view file]

Heiss G (1988) Crystal structure refinement of a synthetic Fe-Mg-Ca carbonate phase, Zeitschrift für Kristallographie, 185, 604-604   [view file]

Mozley P S, Hoernle K (1990) Geochemistry of carbonate cements in the Sag River and Shublik Formation (Triassic/Jurassic), North Slope, Alaska: implications for the geochemical evolution of formation waters, Sedimentology, 37, 817-836

Sawicki J A, Brown D A, Beveridge T J (1995) Microbial precipitation of siderite and protoferrihydrite in a biofilm, The Canadian Mineralogist, 33, 1-6   [view file]

Frankel R B, Bazylinski D A (2003) Biologically induced mineralization by bacteria, Reviews in Mineralogy and Geochemistry, 54, 95-114

Ondruš P, Veselovský F, Gabašová A, Hloušek J, Šrein V, Vavrín I, Skála R, Sejkora J, Drábek M (2003) Primary minerals of the Jáchymov ore district, Journal of the Czech Geological Society, 48, 19-147   [view file]

Buzgar N, Apopei A I (2009) The Raman study of certain carbonates, Analele Stiintifice Ale Universitatii, Al. I. Cuza Iasi Geologie, 55, 97-112   [view file]

Lavina B, Dera P, Downs R T, Yang W, Sinogeikin S, Meng Y, Shen G, Schiferl D (2010) Structure of siderite FeCO3 to 56 GPa and hysteresis of its spin-pairing transition, Physical Review B, 82, 064110-7

Rividi N, van Zuilen M, Philippot P, Ménez B, Godard G, Poidatz E (2010) Calibration of carbonate composition using micro-Raman analysis: Application to planetary surface exploration, Astrobiology, 10, 293-309

Boulard E, Guyot F, Fiquet G (2012) The influence on Fe content on Raman spectra and unit cell parameters of magnesite-siderite solid solutions, Physics and Chemistry of Minerals, 39, 239-246

Farfan G, Wang S, Ma H, Caracas R, Mao W L (2012) Bonding and structural changes in siderite at high pressure, American Mineralogist, 97, 1421-1426   [view file]

Lin J-F, Liu J, Jacobs C, Prakapenka V B (2012) Vibrational and elastic properties of ferromagnesite across the electronic spin-pairing transition of iron, American Mineralogist, 97, 583-591   [view file]

Tao R, Fei Y, Zhang L (2013) Experimental determination of siderite stability at high pressure, American Mineralogist, 98, 1565-1572

Cerantola V, McCammon C, Kupenko I, Kantor I, Marini C, Wilke M, Ismailova L, Solopova N, Chumakov A, Pascarelli S, Dubrovinsky L (2015) High-pressure spectroscopic study of siderite (FeCO3) with a focus on spin crossover, American Mineralogist, 100, 2670-2681

Müller J, Speziale S, Efthimiopoulos I, Jahn S, Koch-Müller M (2016) Raman spectroscopy of siderite at high pressure: Evidence for a sharp spin transition, American Mineralogist, 101, 2638-2644

Müller J, Efthimiopoulos I, Jahn S, Koch-Müller M (2017) Effect of temperature on the pressure-induced spin transition in siderite and iron-bearing magnesite: a Raman spectroscopy study, European Journal of Mineralogy, 29, 785-793

Farsang S, Facq S, Redfern S A T (2018) Raman modes of carbonate minerals as pressure and temperature gauges up to 6 GPa and 500 °C, American Mineralogist, 103, 1988-1998

Cerantola V, Wilke M, Kantor I, Ismailova L, Kupenko I, McCammon C, Pascarelli S, Dubrovinsky L S (2019) Experimental investigation of FeCO3 (siderite) stability in Earth's lower mantle using XANES spectroscopy, American Mineralogist, 104, 1083-1091

Markl G, Keim M F, Bayerl R (2019) Unusual mineral diversity in hydrothermal vein-type deposit: The Clara mine, SW Germany, as a type example, The Canadian Mineralogist, 57, 427-456