R080042 - RRUFF Database: Raman, X-ray, Infrared, and Chemistry

Stishovite R080042

Name: Stishovite
RRUFF ID: R080042
Ideal Chemistry: SiO₂
Locality: Synthetic at 15 GPa/1500ºC
Source: Jürgen Konzett
Owner: RRUFF
Description: Transparent single crystal
Status: The identification of this mineral is confirmed by single-crystal X-ray diffraction and chemical analysis.

Mineral Group: [ Rutile (23) ]

Quick search: [ All Stishovite samples (2) ]

CHEMISTRY

RRUFF ID:	R080042.2
Sample Description:	Microprobe Fragment
Measured Chemistry:	Si_1.00O₂; trace amounts of Fe and Al
Microprobe Data File:	[ Download Excel File ]

RAMAN SPECTRUM

RRUFF ID:

Sample Description:

Unoriented sample

DOWNLOADS:

To download sample data,
please select a specific
orientation angle.

BROAD SCAN WITH SPECTRAL ARTIFACTS

RRUFF ID:

R080042

Wavelength:

Sample Description:

Unoriented sample

Instrument settings:

Thermo Almega XR 532nm @ 100% of 150mW

DOWNLOADS:

	Raman Data (RAW)
	RRUFF File

POWDER DIFFRACTION

RRUFF ID:

R080042.9

Sample Description:

Single crystal, powder profile is calculated

Cell Refinement Output:

a: 4.178(1)Å b: 4.178(1)Å c: 2.666(1)Å
alpha: 90° beta: 90° gamma: 90° Volume: 46.55(2)Å³ Crystal System: tetragonal

File Type Information

Calculated diffraction file.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

DOWNLOADS:

	DIF File
	X-ray Data (XY - RAW)
	RRUFF File

REFERENCES for Stishovite
American Mineralogist Crystal Structure Database Record: [view record]
Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]
Chao E C T, Fahey J J, Littler J, Milton D J (1962) Stishovite, SiO₂, a very high pressure new mineral from Meteor Crater, Arizona, Journal of Geophysical Research, 67, 419-421
Fleischer M (1962) New mineral names, American Mineralogist, 47, 805-812 [view file]
Fleischer M (1963) New mineral names, American Mineralogist, 48, 433-437 [view file]
International Mineralogical Association (1967) Commission on new minerals and mineral names, Mineralogical Magazine, 36, 131-136 [view file]
Sinclair W, Ringwood A E (1978) Single crystal analysis of the structure of stishovite, Nature, 272, 714-715
Hill R J, Newton M D, Gibbs G V (1983) A crystal chemical study of stishovite, Journal of Solid State Chemistry, 47, 185-200
Endo S, Akai T, Akahama Y, Wakatsuki M, Nakamura T, Tomii Y, Koto K, Ito Y, Tokonami M (1986) High temperature X-ray study of single crystal stishovite synthesized with Li₂WO₄ as flux, Physics and Chemistry of Minerals, 13, 146-151
Hemley R J, Mao H K, Chao E C T (1986) Raman spectrum of natural and synthetic stishovite, Physics and Chemistry of Minerals, 13, 285-290
Spackman M A, Hill R J, Gibbs G V (1987) Exploration of structure and bonding in stishovite with Fourier and pseudoatom refinement methods using single crystal and powder X-ray diffraction data, Physics and Chemistry of Minerals, 14, 139-150
von Czarnowski A, Hübner K (1987) Raman and Infrared investigations of stishovite and their interpretation, Physica Status Solidi, 142, K91-K96
Ross N L, Shu J F, Hazen R M, Gasparik T (1990) High-pressure crystal chemistry of stishovite, American Mineralogist, 75, 739-747 [view file]
Swamy V, Saxena S K, Sundman B, Zhang J (1994) A thermodynamic assessment of silica phase diagram, Journal of Geophysical Research, 99, 11787-11794
Yamanaka T, Fukuda T, Tsuchiya J (2002) Bonding character of SiO₂ stishovite under high pressures up to 30 GPa, Physics and Chemistry of Minerals, 29, 633-641
Ohtani E, Ozawa S, Miyahara M, Ito Y, Mikouchi T, Kimura M, Arai T, Sato K, Hiraga K (2011) Coesite and stishovite in a shocked lunar meteorite, Asuka-881757, and impact events in lunar surface, Proceedings of the National Academy of Sciences, 108, 463-466
Mashino I, Ohtani E, Hirao N, Mitsui T, Masuda R, Seto M, Sakai T, Takahashi S, Nakano S (2014) The spin state of iron in Fe³⁺-bearing Mg-perovskite and its crystal chemistry at high pressure, American Mineralogist, 99, 1555-1561
Kaneko S, Miyahara M, Ohtani E, Arai T, Hirao N, Sato K (2015) Discovery of stishovite in Apollo 15299 sample, American Mineralogist, 100, 1308–1311
Klier K, Spirko J A, Landskron K M (2015) Optical absorption anisotropy of high-density, wide-gap, high-hardness SiO₂ polymorphs seifertite, stishovite, and coesite, American Mineralogist, 100, 120-129
Nisr C, Shim S H, Leinenweber K, Chizmeshya A (2017) Raman spectroscopy of water-rich stishovite and dense high-pressure silica up to 55 GPa, American Mineralogist, 102, 2180-2189
Fischer R A, Campbell A J, Chidester B A, Reaman D M, Thompson E C, Pigott J S, Prakapenka V B, Smith J S (2018) Equations of state and phase boundary for stishovite and CaCl₂-type SiO₂, American Mineralogist, 103, 792-802
Tschauner O (2019) High-pressure minerals, American Mineralogist, 104, 1701-1731
Chen H, Leinenweber K, Kunz M, Bechtel H A, Liu Z, Shim S (2020) Phase transformation of hydrous ringwoodite to the lower-mantle phases and the formation of dense hydrous silica, American Mineralogist, 105, 1342-1348
Das P K, Mohn C E, Brodholt J P, Trønnes R G (2020) High-pressure silica phase transitions: Implications for deep mantle dynamics and silica crystallization in the protocol, American Mineralogist, 105, 1014-1020

REFERENCES for Stishovite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Chao E C T, Fahey J J, Littler J, Milton D J (1962) Stishovite, SiO₂, a very high pressure new mineral from Meteor Crater, Arizona, Journal of Geophysical Research, 67, 419-421

Fleischer M (1962) New mineral names, American Mineralogist, 47, 805-812 [view file]

Fleischer M (1963) New mineral names, American Mineralogist, 48, 433-437 [view file]

International Mineralogical Association (1967) Commission on new minerals and mineral names, Mineralogical Magazine, 36, 131-136 [view file]

Sinclair W, Ringwood A E (1978) Single crystal analysis of the structure of stishovite, Nature, 272, 714-715

Hill R J, Newton M D, Gibbs G V (1983) A crystal chemical study of stishovite, Journal of Solid State Chemistry, 47, 185-200

Endo S, Akai T, Akahama Y, Wakatsuki M, Nakamura T, Tomii Y, Koto K, Ito Y, Tokonami M (1986) High temperature X-ray study of single crystal stishovite synthesized with Li₂WO₄ as flux, Physics and Chemistry of Minerals, 13, 146-151

Hemley R J, Mao H K, Chao E C T (1986) Raman spectrum of natural and synthetic stishovite, Physics and Chemistry of Minerals, 13, 285-290

Spackman M A, Hill R J, Gibbs G V (1987) Exploration of structure and bonding in stishovite with Fourier and pseudoatom refinement methods using single crystal and powder X-ray diffraction data, Physics and Chemistry of Minerals, 14, 139-150

von Czarnowski A, Hübner K (1987) Raman and Infrared investigations of stishovite and their interpretation, Physica Status Solidi, 142, K91-K96

Ross N L, Shu J F, Hazen R M, Gasparik T (1990) High-pressure crystal chemistry of stishovite, American Mineralogist, 75, 739-747 [view file]

Swamy V, Saxena S K, Sundman B, Zhang J (1994) A thermodynamic assessment of silica phase diagram, Journal of Geophysical Research, 99, 11787-11794

Yamanaka T, Fukuda T, Tsuchiya J (2002) Bonding character of SiO₂ stishovite under high pressures up to 30 GPa, Physics and Chemistry of Minerals, 29, 633-641

Ohtani E, Ozawa S, Miyahara M, Ito Y, Mikouchi T, Kimura M, Arai T, Sato K, Hiraga K (2011) Coesite and stishovite in a shocked lunar meteorite, Asuka-881757, and impact events in lunar surface, Proceedings of the National Academy of Sciences, 108, 463-466

Mashino I, Ohtani E, Hirao N, Mitsui T, Masuda R, Seto M, Sakai T, Takahashi S, Nakano S (2014) The spin state of iron in Fe³⁺-bearing Mg-perovskite and its crystal chemistry at high pressure, American Mineralogist, 99, 1555-1561

Kaneko S, Miyahara M, Ohtani E, Arai T, Hirao N, Sato K (2015) Discovery of stishovite in Apollo 15299 sample, American Mineralogist, 100, 1308–1311

Klier K, Spirko J A, Landskron K M (2015) Optical absorption anisotropy of high-density, wide-gap, high-hardness SiO₂ polymorphs seifertite, stishovite, and coesite, American Mineralogist, 100, 120-129

Nisr C, Shim S H, Leinenweber K, Chizmeshya A (2017) Raman spectroscopy of water-rich stishovite and dense high-pressure silica up to 55 GPa, American Mineralogist, 102, 2180-2189

Fischer R A, Campbell A J, Chidester B A, Reaman D M, Thompson E C, Pigott J S, Prakapenka V B, Smith J S (2018) Equations of state and phase boundary for stishovite and CaCl₂-type SiO₂, American Mineralogist, 103, 792-802

Tschauner O (2019) High-pressure minerals, American Mineralogist, 104, 1701-1731

Chen H, Leinenweber K, Kunz M, Bechtel H A, Liu Z, Shim S (2020) Phase transformation of hydrous ringwoodite to the lower-mantle phases and the formation of dense hydrous silica, American Mineralogist, 105, 1342-1348

Das P K, Mohn C E, Brodholt J P, Trønnes R G (2020) High-pressure silica phase transitions: Implications for deep mantle dynamics and silica crystallization in the protocol, American Mineralogist, 105, 1014-1020