R060113 - RRUFF Database: Raman, X-ray, Infrared, and Chemistry

Jarosite R060113

Name: Jarosite
RRUFF ID: R060113
Ideal Chemistry: KFe³⁺₃(SO₄)₂(OH)₆
Locality: Iron Blossom mine, East Tintic District, Eureka, Utah, USA
Source: University of Arizona Mineral Museum 9868 [view label]
Owner: RRUFF
Description: Amber-yellow to dark brown rhombohedral crystals
Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis

Mineral Groups: [ alunite (46) ] [ Alunite (20) ]

Quick search: [ All Jarosite samples (5) ]

CHEMISTRY

RRUFF ID:	R060113.2
Sample Description:	Microprobe Fragment
Measured Chemistry:	(K_0.88Sr_0.12)(Fe³⁺_0.96Al_0.04)₃((S_0.94P_0.06)O₄)₂(OH)₆

RAMAN SPECTRUM

RRUFF ID:

Sample Description:

Unoriented sample

DOWNLOADS:

To download sample data,
please select a specific
orientation angle.

BROAD SCAN WITH SPECTRAL ARTIFACTS

RRUFF ID:

R060113

Wavelength:

Sample Description:

Unoriented sample

Instrument settings:

Thermo Almega XR 532nm @ 100% of 150mW

DOWNLOADS:

	Raman Data (Processed)
	RRUFF File
	Raman Data (RAW)
	RRUFF File

POWDER DIFFRACTION

RRUFF ID:

R060113.1

Sample Description:

Powder

Cell Refinement Output:

a: 7.3013(5)Å b: 7.3013(5)Å c: 17.211(1)Å
alpha: 90° beta: 90° gamma: 120° Volume: 794.6(1)Å³ Crystal System: hexagonal

File Type Information

Calculated diffraction file.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

DOWNLOADS:

	Cell Refinement Data
	Cell Refinement Output Data
	DIF File
	X-ray Data (XY - Processed)
	RRUFF File
	X-ray Data (XY - RAW)
	RRUFF File

REFERENCES for Jarosite
American Mineralogist Crystal Structure Database Record: [view record]
Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]
Breithaupt J F A (1852) Jarosit, Jarosites kalicus, in Berg- und Huttenmannische Zeitung 11th Edition J. G. Engelhardt Freiberg 68-69 [view file]
Hillebrand W F, Penfield S L (1902) Some additions to the alunite-jarosite group of minerals, American Journal of Science, 164, 211-220 [view file]
Larsen E S (1921) The microscopic determination of the nonopaque minerals, U.S. Geological Survey Bulletin, 671, 5-294 [view file]
Marble J P, Fleischer M (1941) New mineral names, American Mineralogist, 26, 135-136 [view file]
Fleischer M (1957) New mineral names, American Mineralogist, 42, 580-586 [view file]
Brophy G P, Sheridan M F (1965) Sulfate studies IV: the jarosite—natrojarosite—hydronium jarosite solid solution series, American Mineralogist, 50, 1595-1607 [view file]
White J S, Henderson E P, Mason B (1967) Secondary minerals produced by weathering of the Wolf Creek meteorite, American Mineralogist, 52, 1190-1197 [view file]
Brown J B (1970) A chemical study of some synthetic potassium-hydronium jarosites, The Canadian Mineralogist, 10, 696-703 [view file]
Dutrizac J E, Kaiman S (1976) Synthesis and properties of jarosite-type compounds, The Canadian Mineralogist, 14, 151-158 [view file]
Menchetti S, Sabelli C (1976) Crystal chemistry of the alunite series: crystal structure refinement of alunite and synthetic jarosite, Neues Jahrbuch für Mineralogie, Monatshefte, 1976, 406-417
Rossman G R (1976) Spectroscopic and magnetic studies of ferric iron hydroxy sulfates: the series Fe(OH)SO₄·nH₂O and jarosites, American Mineralogist, 61, 398-404 [view file]
Kato T, Miura Y (1977) The crystal structure of jarosite and svanbergite, Mineralogical Journal, 8, 419-430 [view file]
Dutrizac J E, Chen T T (1981) The synthesis of mercury jarosite and the mercury concentration in jarosite-family minerals, The Canadian Mineralogist, 19, 559-569 [view file]
Ivarson K C, Ross G J, Miles N M (1981) Formation of rubidium jarosite during the microbiological oxidation of ferrous iron at room temperature, The Canadian Mineralogist, 19, 429-434 [view file]
Ripmeester J A, Ratcliffe C I, Dutrizac J E, Jambor J L (1986) Hydronium ion in the alunite - jarosite group, The Canadian Mineralogist, 24, 435-447 [view file]
Michel F A, Van Everdingen R O (1987) Formation of a jarosite deposit on Cretaceous shales in the Fort Norman area, Northwest Territories, The Canadian Mineralogist, 25, 221-226 [view file]
Nickel E H, Mandarino J A (1987) Procedures involving the IMA Commission on New Minerals and Mineral Names and guidelines on mineral nomenclature, American Mineralogist, 72, 1031-1042 [view file]
Scott K M (1987) Solid solution in, and classification of, gossan-derived members of the alunite-jarosite family, northwest Queensland, Australia, American Mineralogist, 72, 178-187 [view file]
Tazaki K, Mori T, Nonaka T (1992) Microbial jarosite and gypsum from corrosion of Portland cement concrete, The Canadian Mineralogist, 30, 431-444 [view file]
Sasaki K, Tanaike O, Konno H (1998) Distinction of jarosite-group compounds by Raman spectroscopy, The Canadian Mineralogist, 36, 1225-1235 [view file]
Jambor J L (1999) Nomenclature of the alunite supergroup, The Canadian Mineralogist, 37, 1323-1341 [view file]
Frankel R B, Bazylinski D A (2003) Biologically induced mineralization by bacteria, Reviews in Mineralogy and Geochemistry, 54, 95-114
Grohol D, Huang Q, Toby B H, Lyn J W, Lee Y S, Nocera D G (2003) Powder neuron diffraction analysis and magnetic structure of kagomé-type vanadium jarosite NaV₃(OD)₆(SO4)₂, Physical Review B - Condensed Matter, 68, 094404-7
Paktunc D, Dutrizac J E (2003) Characterization of arsenate-for sulfate substitution in synthetic jarosite using X-ray diffraction and X-ray absorption spectroscopy, The Canadian Mineralogist, 41, 905-919 [view file]
Bishop J L, Murad E (2005) The visible and infrared spectral properties of jarosite and alunite, American Mineralogist, 90, 1100-1107 [view file]
Frost R L, Wills R, Weier M L, Martens W (2005) Comparison of the Raman spectra of natural and synthetic K- and Na-jarosites at 298 and 77 K, Journal of Raman Spectroscopy, 36, 435-444
Frost R L, Wills R A, Weier M L, Martens W, Mills S (2006) A Raman spectroscopic study of selected natural jarosites, Spectrochimica Acta, A63, 1-8
Papike J J, Karner J M, Spilde M N, Shearer C K (2006) Terrestrial analogs of martian sulfates: Major and minor element systematics of alunite-jarosite from Goldfield, Nevada, American Mineralogist, 91, 1197-1200 [view file]
Basciano L C, Peterson R C (2007) Jarosite—hydronium jarosite solid-solution series with full iron site occupancy: Mineralogy and crystal chemistry, American Mineralogist, 92, 1464-1473 [view file]
Lane M D (2007) Mid-infrared emission spectroscopy of sulfate and sulfate-bearing minerals, American Mineralogist, 92, 1-18 [view file]
Basciano L C, Peterson R C (2008) Crystal chemistry of the natrojarosite-jarosite and natrojarosite-hydronium jarosite solid-solution: A synthetic study with full Fe site occupancy, American Mineralogist, 93, 853-862 [view file]
Hudson-Edwards K A, Smith A M L, Dubbin W E, Bennett A J, Murphy P J, Wright K (2008) Comprison of the structures of natural and synthetic Pb-Cu-jarosite-type compounds, European Journal of Mineralogy, 2004, 241-252
Murphy P J, Smith A M L, Hudson-Edwards K A, Dubbin W E, Wright K (2009) Raman and IR spectroscopic studies of alunite-supergroup compounds containing Al, Cr³⁺, Fe³⁺ and V³⁺ at the B site, The Canadian Mineralogist, 47, 663-681 [view file]
Sato E, Nakai I, Miyawaki R, Matsubara S (2009) Crystal structures of alunite family minerals: beaverite, corkite, alunite, natroalunite, jarosite, svanbergite, and woodhouseite, Neues Jahrbuch für Mineralogie, Abhandlungen, 185, 313-322
Basciano L C, Peterson R C (2010) A crystallographic study of the incomplete solid-solution between plumbojarosite and jarosite, The Canadian Mineralogist, 48, 651-659 [view file]
Bayliss P, Kolitsch U, Nickel E H, Pring A (2010) Alunite supergroup: recommended nomenclature, Mineralogical Magazine, 74, 919-927 [view file]
Scarlett N V Y, Grey I E, Brand H E A (2010) Ordering of iron vacancies in monoclinic jarosites, American Mineralogist, 95, 1590-1593 [view file]
Mills S J, Nestola F, Kahlenberg V, Christy A G, Hejny C, Redhammer G J (2013) Looking for jarosite on Mars: The low-temperature crystal structure of jarosite, American Mineralogist, 98, 1966-1971
Spratt H J, Rintoul L, Avdeev M, Martens W N (2013) The crystal structure and vibrational spectroscopy of jarosite and alunite minerals, American Mineralogist, 98, 1633-1643
Pitman K M, Noe Dobrea E Z, Jamieson C S, Dalton J B, Abbey W J, Joseph E C S (2014) Reflectance spectroscopy and optical functions for hydrated Fe-sulfates, American Mineralogist, 99, 1593-1603
Sobron P, Bishop J L, Blake D F, Chen B, Rull F (2014) Natural Fe-bearing oxides and sulfates from the Rio Tinto Mars analog site: Critical assessment of VNIR reflectance spectroscopy, laser Raman spectroscopy, and XRD as mineral identification tools, American Mineralogist, 99, 1199-1205
Sklute E C, Glotch T D, Piatek J L, Woerner W R, Martone A A, Kraner M L (2015) Optical constants of synthetic potassium, sodium, and hydronium jarosite, American Mineralogist, 100, 1110-1122
Morrison S M, Downs R T, Blake D F, Prabhu A, Eleish A, Vaniman D T, Ming D W, Rampe E B, Hazen R M, Achilles C N, Treiman A H, Yen A S, Morris R V, Bristow T F, Chipera S J, Sarrazin P C, Fendrich K V, Morookian J M, Farmer J D, Des Marais D J, Craig P I (2018) Relationships between unit-cell parameters and composition for rock-forming minerals on Earth, Mars, and other extraterrestrial bodies, American Mineralogist, 103, 848-856 [view file]
Morrison S M, Downs R T, Blake D F, Vaniman D T, Ming D W, Hazen R M, Treiman A H, Achilles C N, Yen A S, Morris R V, Rampe E B, Bristow T F, Chipera S J, Sarrazin P C, Gellert R, Fendrich K V, Morookian J M, Farmer J D, Des Marais D J, Craig P I (2018) Crystal chemistry of martian minerals from Bradbury Landing through Naukluft Plateau, Gale crater, Mars, American Mineralogist, 103, 857-871 [view file]
Ondrejka M, Bačík P, Sobocký T, Uher P, Škoda R, Mikuš T, Luptáková J, Konečiný P (2018) Minerals of the rhabdophane group and the alunite supergroup in microgranite: products of low-temperature alteration in a highly acidic environment from the Velence Hills, Hungary, Mineralogical Magazine, 82, 1277-1300
Hudson-Edwards K A (2019) Uptake and release of arsenic and antimony in alunite-jarosite and beudantite group minerals, American Mineralogist, 104, 633-640
Markl G, Keim M F, Bayerl R (2019) Unusual mineral diversity in hydrothermal vein-type deposit: The Clara mine, SW Germany, as a type example, The Canadian Mineralogist, 57, 427-456
Biagioni C, Mauro D, Pasero M (2020) Sulfates from the pyrite ore deposits of the Apuan Alps (Tuscany, Italy): A review, Minerals, 10, 1092 [view file]
Hinman N W, Bishop J L, Gulick V C, Kotler Dettmann J M, Morkner P, Berlanga G, Henneberger R M, Bergquist P, Richardson C D, Walter M R, MacKenzie L A, Anitori R P, Scott J R (2021) Targeting mixtures of jarosite and clay minerals for Mars exploration, American Mineralogist, 106, 1237-1254
Cruells M, Roca A (2022) Jarosites: Formation, structure, reactivity and environmental, Metals, 12, 802 [view file]
Whitworth A J, Brand H E A, Wilson S, Grey I E, Stephen N R, Gozukara Y, Frierdich A J (2023) The occurrence of monoclinic jarosite in natural environments, American Mineralogist, 108, 584-594

REFERENCES for Jarosite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Breithaupt J F A (1852) Jarosit, Jarosites kalicus, in Berg- und Huttenmannische Zeitung 11th Edition J. G. Engelhardt Freiberg 68-69 [view file]

Hillebrand W F, Penfield S L (1902) Some additions to the alunite-jarosite group of minerals, American Journal of Science, 164, 211-220 [view file]

Larsen E S (1921) The microscopic determination of the nonopaque minerals, U.S. Geological Survey Bulletin, 671, 5-294 [view file]

Marble J P, Fleischer M (1941) New mineral names, American Mineralogist, 26, 135-136 [view file]

Fleischer M (1957) New mineral names, American Mineralogist, 42, 580-586 [view file]

Brophy G P, Sheridan M F (1965) Sulfate studies IV: the jarosite—natrojarosite—hydronium jarosite solid solution series, American Mineralogist, 50, 1595-1607 [view file]

White J S, Henderson E P, Mason B (1967) Secondary minerals produced by weathering of the Wolf Creek meteorite, American Mineralogist, 52, 1190-1197 [view file]

Brown J B (1970) A chemical study of some synthetic potassium-hydronium jarosites, The Canadian Mineralogist, 10, 696-703 [view file]

Dutrizac J E, Kaiman S (1976) Synthesis and properties of jarosite-type compounds, The Canadian Mineralogist, 14, 151-158 [view file]

Menchetti S, Sabelli C (1976) Crystal chemistry of the alunite series: crystal structure refinement of alunite and synthetic jarosite, Neues Jahrbuch für Mineralogie, Monatshefte, 1976, 406-417

Rossman G R (1976) Spectroscopic and magnetic studies of ferric iron hydroxy sulfates: the series Fe(OH)SO₄·nH₂O and jarosites, American Mineralogist, 61, 398-404 [view file]

Kato T, Miura Y (1977) The crystal structure of jarosite and svanbergite, Mineralogical Journal, 8, 419-430 [view file]

Dutrizac J E, Chen T T (1981) The synthesis of mercury jarosite and the mercury concentration in jarosite-family minerals, The Canadian Mineralogist, 19, 559-569 [view file]

Ivarson K C, Ross G J, Miles N M (1981) Formation of rubidium jarosite during the microbiological oxidation of ferrous iron at room temperature, The Canadian Mineralogist, 19, 429-434 [view file]

Ripmeester J A, Ratcliffe C I, Dutrizac J E, Jambor J L (1986) Hydronium ion in the alunite - jarosite group, The Canadian Mineralogist, 24, 435-447 [view file]

Michel F A, Van Everdingen R O (1987) Formation of a jarosite deposit on Cretaceous shales in the Fort Norman area, Northwest Territories, The Canadian Mineralogist, 25, 221-226 [view file]

Nickel E H, Mandarino J A (1987) Procedures involving the IMA Commission on New Minerals and Mineral Names and guidelines on mineral nomenclature, American Mineralogist, 72, 1031-1042 [view file]

Scott K M (1987) Solid solution in, and classification of, gossan-derived members of the alunite-jarosite family, northwest Queensland, Australia, American Mineralogist, 72, 178-187 [view file]

Tazaki K, Mori T, Nonaka T (1992) Microbial jarosite and gypsum from corrosion of Portland cement concrete, The Canadian Mineralogist, 30, 431-444 [view file]

Sasaki K, Tanaike O, Konno H (1998) Distinction of jarosite-group compounds by Raman spectroscopy, The Canadian Mineralogist, 36, 1225-1235 [view file]

Jambor J L (1999) Nomenclature of the alunite supergroup, The Canadian Mineralogist, 37, 1323-1341 [view file]

Frankel R B, Bazylinski D A (2003) Biologically induced mineralization by bacteria, Reviews in Mineralogy and Geochemistry, 54, 95-114

Grohol D, Huang Q, Toby B H, Lyn J W, Lee Y S, Nocera D G (2003) Powder neuron diffraction analysis and magnetic structure of kagomé-type vanadium jarosite NaV₃(OD)₆(SO4)₂, Physical Review B - Condensed Matter, 68, 094404-7

Paktunc D, Dutrizac J E (2003) Characterization of arsenate-for sulfate substitution in synthetic jarosite using X-ray diffraction and X-ray absorption spectroscopy, The Canadian Mineralogist, 41, 905-919 [view file]

Bishop J L, Murad E (2005) The visible and infrared spectral properties of jarosite and alunite, American Mineralogist, 90, 1100-1107 [view file]

Frost R L, Wills R, Weier M L, Martens W (2005) Comparison of the Raman spectra of natural and synthetic K- and Na-jarosites at 298 and 77 K, Journal of Raman Spectroscopy, 36, 435-444

Frost R L, Wills R A, Weier M L, Martens W, Mills S (2006) A Raman spectroscopic study of selected natural jarosites, Spectrochimica Acta, A63, 1-8

Papike J J, Karner J M, Spilde M N, Shearer C K (2006) Terrestrial analogs of martian sulfates: Major and minor element systematics of alunite-jarosite from Goldfield, Nevada, American Mineralogist, 91, 1197-1200 [view file]

Basciano L C, Peterson R C (2007) Jarosite—hydronium jarosite solid-solution series with full iron site occupancy: Mineralogy and crystal chemistry, American Mineralogist, 92, 1464-1473 [view file]

Lane M D (2007) Mid-infrared emission spectroscopy of sulfate and sulfate-bearing minerals, American Mineralogist, 92, 1-18 [view file]

Basciano L C, Peterson R C (2008) Crystal chemistry of the natrojarosite-jarosite and natrojarosite-hydronium jarosite solid-solution: A synthetic study with full Fe site occupancy, American Mineralogist, 93, 853-862 [view file]

Hudson-Edwards K A, Smith A M L, Dubbin W E, Bennett A J, Murphy P J, Wright K (2008) Comprison of the structures of natural and synthetic Pb-Cu-jarosite-type compounds, European Journal of Mineralogy, 2004, 241-252

Murphy P J, Smith A M L, Hudson-Edwards K A, Dubbin W E, Wright K (2009) Raman and IR spectroscopic studies of alunite-supergroup compounds containing Al, Cr³⁺, Fe³⁺ and V³⁺ at the B site, The Canadian Mineralogist, 47, 663-681 [view file]

Sato E, Nakai I, Miyawaki R, Matsubara S (2009) Crystal structures of alunite family minerals: beaverite, corkite, alunite, natroalunite, jarosite, svanbergite, and woodhouseite, Neues Jahrbuch für Mineralogie, Abhandlungen, 185, 313-322

Basciano L C, Peterson R C (2010) A crystallographic study of the incomplete solid-solution between plumbojarosite and jarosite, The Canadian Mineralogist, 48, 651-659 [view file]

Bayliss P, Kolitsch U, Nickel E H, Pring A (2010) Alunite supergroup: recommended nomenclature, Mineralogical Magazine, 74, 919-927 [view file]

Scarlett N V Y, Grey I E, Brand H E A (2010) Ordering of iron vacancies in monoclinic jarosites, American Mineralogist, 95, 1590-1593 [view file]

Mills S J, Nestola F, Kahlenberg V, Christy A G, Hejny C, Redhammer G J (2013) Looking for jarosite on Mars: The low-temperature crystal structure of jarosite, American Mineralogist, 98, 1966-1971

Spratt H J, Rintoul L, Avdeev M, Martens W N (2013) The crystal structure and vibrational spectroscopy of jarosite and alunite minerals, American Mineralogist, 98, 1633-1643

Pitman K M, Noe Dobrea E Z, Jamieson C S, Dalton J B, Abbey W J, Joseph E C S (2014) Reflectance spectroscopy and optical functions for hydrated Fe-sulfates, American Mineralogist, 99, 1593-1603

Sobron P, Bishop J L, Blake D F, Chen B, Rull F (2014) Natural Fe-bearing oxides and sulfates from the Rio Tinto Mars analog site: Critical assessment of VNIR reflectance spectroscopy, laser Raman spectroscopy, and XRD as mineral identification tools, American Mineralogist, 99, 1199-1205

Sklute E C, Glotch T D, Piatek J L, Woerner W R, Martone A A, Kraner M L (2015) Optical constants of synthetic potassium, sodium, and hydronium jarosite, American Mineralogist, 100, 1110-1122

Morrison S M, Downs R T, Blake D F, Prabhu A, Eleish A, Vaniman D T, Ming D W, Rampe E B, Hazen R M, Achilles C N, Treiman A H, Yen A S, Morris R V, Bristow T F, Chipera S J, Sarrazin P C, Fendrich K V, Morookian J M, Farmer J D, Des Marais D J, Craig P I (2018) Relationships between unit-cell parameters and composition for rock-forming minerals on Earth, Mars, and other extraterrestrial bodies, American Mineralogist, 103, 848-856 [view file]

Morrison S M, Downs R T, Blake D F, Vaniman D T, Ming D W, Hazen R M, Treiman A H, Achilles C N, Yen A S, Morris R V, Rampe E B, Bristow T F, Chipera S J, Sarrazin P C, Gellert R, Fendrich K V, Morookian J M, Farmer J D, Des Marais D J, Craig P I (2018) Crystal chemistry of martian minerals from Bradbury Landing through Naukluft Plateau, Gale crater, Mars, American Mineralogist, 103, 857-871 [view file]

Ondrejka M, Bačík P, Sobocký T, Uher P, Škoda R, Mikuš T, Luptáková J, Konečiný P (2018) Minerals of the rhabdophane group and the alunite supergroup in microgranite: products of low-temperature alteration in a highly acidic environment from the Velence Hills, Hungary, Mineralogical Magazine, 82, 1277-1300

Hudson-Edwards K A (2019) Uptake and release of arsenic and antimony in alunite-jarosite and beudantite group minerals, American Mineralogist, 104, 633-640

Markl G, Keim M F, Bayerl R (2019) Unusual mineral diversity in hydrothermal vein-type deposit: The Clara mine, SW Germany, as a type example, The Canadian Mineralogist, 57, 427-456

Biagioni C, Mauro D, Pasero M (2020) Sulfates from the pyrite ore deposits of the Apuan Alps (Tuscany, Italy): A review, Minerals, 10, 1092 [view file]

Hinman N W, Bishop J L, Gulick V C, Kotler Dettmann J M, Morkner P, Berlanga G, Henneberger R M, Bergquist P, Richardson C D, Walter M R, MacKenzie L A, Anitori R P, Scott J R (2021) Targeting mixtures of jarosite and clay minerals for Mars exploration, American Mineralogist, 106, 1237-1254

Cruells M, Roca A (2022) Jarosites: Formation, structure, reactivity and environmental, Metals, 12, 802 [view file]

Whitworth A J, Brand H E A, Wilson S, Grey I E, Stephen N R, Gozukara Y, Frierdich A J (2023) The occurrence of monoclinic jarosite in natural environments, American Mineralogist, 108, 584-594