W(OH, F, Cl)-dominant amphibole R040039 - RRUFF Database: Raman, X-ray, Infrared, and Chemistry

Fluorophlogopite R040039

Name: Fluorophlogopite
RRUFF ID: R040039
Ideal Chemistry: KMg₃(Si₃Al)O₁₀F₂
Locality: Franklin, Sussex County, New Jersey, USA
Source: University of Arizona Mineral Museum 4635 [view label]
Owner: RRUFF
Description: Brown hexagonal sheets
Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis

Mineral Group: [ mica (50) ]

Quick search: [ All Fluorophlogopite samples (3) ]

CHEMISTRY

RRUFF ID:	R040039.2
Sample Description:	Microprobe Fragment
Measured Chemistry:	(K_0.92Na_0.06◻_0.02)_Σ=1(Mg_2.94Fe_0.04Ti_0.02)_Σ=3(Si_2.98Al_1.02)O₁₀(F_1.24(OH)_0.76)_Σ=2; OH estimated by charge balance
Microprobe Data File:	[ Download Excel File ]

RAMAN SPECTRUM

RRUFF ID:

Sample Description:

Sample is oriented, mounted onto a pin and polished

Pin ID:

L00415

Orientation:

Laser parallel to [-1 0 -1]. Fiducial mark perpendicular to laser is parallel to b* (0 1 0).

DOWNLOADS:

To download sample data,
please select a specific
orientation angle.

BROAD SCAN WITH SPECTRAL ARTIFACTS

RRUFF ID:

R040039

Wavelength:

Sample Description:

Unoriented sample

Instrument settings:

Thermo Almega XR 532nm @ 100% of 150mW

DOWNLOADS:

	Raman Data (RAW)
	RRUFF File

INFRARED SPECTRUM (Attenuated Total Reflectance)

RRUFF ID:

R040039.1

Instrument settings:

SensIR Durascope on a Nicolet Magna 860 FTIR

Resolution:

DOWNLOADS:

	Infrared Data (Processed)
	RRUFF File

POWDER DIFFRACTION

RRUFF ID:

R040039.1

Sample Description:

Powder

Cell Refinement Output:

a: 5.314(1)Å b: 9.1865(9)Å c: 10.153(1)Å
alpha: 90° beta: 100.09(2)° gamma: 90° Volume: 488.0(0)Å³ Crystal System: monoclinic

File Type Information

Calculated diffraction file.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

DOWNLOADS:

	Cell Refinement Data
	Cell Refinement Output Data
	DIF File
	X-ray Data (XY - Processed)
	RRUFF File
	X-ray Data (XY - RAW)
	RRUFF File

REFERENCES for Fluorophlogopite
American Mineralogist Crystal Structure Database Record: [view record]
Yoder H S, Eugster H P (1954) Phlogopite synthesis and stability range, Geochimica et Cosmochimica Acta, 6, 157-185
Kohn J A, Hatch R A (1955) Synthetic mica investigations, VI: X-ray and optical data on synthetic fluor-phlogopite, American Mineralogist, 40, 10-21
Hazen R M, Burnham C W (1973) The crystal structures of one-layer phlogopite and annite, American Mineralogist, 58, 889-900 [view file]
Valley J W, Petersen E U, Essene E J, Bowman J R (1982) Fluorphlogopite and fluortremolite in Adirondack marbles and calculated C–O–H–F fluid compositions, American Mineralogist, 67, 545-557 [view file]
Gianfagna A, Scordari F, Mazziotti-Tagliani S, Ventruti G, Ottolini L (2007) Fluorophlogopite from Biancavilla (Mt. Etna, Sicily, Italy): Crystal structure and crystal chemistry of a new F-dominant analog of phlogopite, American Mineralogist, 92, 1601-1609 [view file]
Scordari F, Schingaro E, Ventruti G, Nicotra E, Viccaro M, Tagliani S M (2013) Fluorophlogopite from Piano delle Concazze (Mt. Etna, Italy): Crystal chemistry and implications for the crystallization conditions, American Mineralogist, 98, 1017-1025 [view file]
Lacalamita M, Blassone G, Schingaro E, Mesto E, Mormone A, Piochi M, Venturi G, Joachimski M (2017) Fluorophlogopite-bearing and carbonate metamorphosed xenoliths from the Campanian Ignimbrite (Fiano, southern Italy): crystal chemical, geochemical and volcanological insights, Mineralogical Magazine, 81, 1165-1189
Lacalamita M, Schingaro E, Mesto E, Zaccarini F, Biagioni C (2020) Crystal‐chemistry of micas belonging to the yangzhumingite‐fluorophlogopite and phlogopite‐fluorophlogopite series from the Apuan Alps (northern Tuscany, Italy), Physics and Chemistry of Minerals, 47, 54 [view file]

REFERENCES for Fluorophlogopite

American Mineralogist Crystal Structure Database Record: [view record]

Yoder H S, Eugster H P (1954) Phlogopite synthesis and stability range, Geochimica et Cosmochimica Acta, 6, 157-185

Kohn J A, Hatch R A (1955) Synthetic mica investigations, VI: X-ray and optical data on synthetic fluor-phlogopite, American Mineralogist, 40, 10-21

Hazen R M, Burnham C W (1973) The crystal structures of one-layer phlogopite and annite, American Mineralogist, 58, 889-900 [view file]

Valley J W, Petersen E U, Essene E J, Bowman J R (1982) Fluorphlogopite and fluortremolite in Adirondack marbles and calculated C–O–H–F fluid compositions, American Mineralogist, 67, 545-557 [view file]

Gianfagna A, Scordari F, Mazziotti-Tagliani S, Ventruti G, Ottolini L (2007) Fluorophlogopite from Biancavilla (Mt. Etna, Sicily, Italy): Crystal structure and crystal chemistry of a new F-dominant analog of phlogopite, American Mineralogist, 92, 1601-1609 [view file]

Scordari F, Schingaro E, Ventruti G, Nicotra E, Viccaro M, Tagliani S M (2013) Fluorophlogopite from Piano delle Concazze (Mt. Etna, Italy): Crystal chemistry and implications for the crystallization conditions, American Mineralogist, 98, 1017-1025 [view file]

Lacalamita M, Blassone G, Schingaro E, Mesto E, Mormone A, Piochi M, Venturi G, Joachimski M (2017) Fluorophlogopite-bearing and carbonate metamorphosed xenoliths from the Campanian Ignimbrite (Fiano, southern Italy): crystal chemical, geochemical and volcanological insights, Mineralogical Magazine, 81, 1165-1189

Lacalamita M, Schingaro E, Mesto E, Zaccarini F, Biagioni C (2020) Crystal‐chemistry of micas belonging to the yangzhumingite‐fluorophlogopite and phlogopite‐fluorophlogopite series from the Apuan Alps (northern Tuscany, Italy), Physics and Chemistry of Minerals, 47, 54 [view file]