Spinel R060799



Name: Spinel
RRUFF ID: R060799
Ideal Chemistry: MgAl2O4
Locality: Aliabad, Hunza Valley, Pakistan
Source: Marcus Origlieri [view label]
Owner: RRUFF
Description: A group of blue distorted octahedra
Status: The identification of this mineral is confirmed by single-crystal X-ray diffraction and chemical analysis.
Mineral Group: [ Spinel (56) ]
Quick search: [ All Spinel samples (12) ]
CHEMISTRY 
RRUFF ID: R060799.2
Sample Description: Microprobe Fragment
Measured Chemistry: (Mg0.97Fe2+0.03)1.00Al2.00O4
Microprobe Data File: [ Download Excel File ]
RAMAN SPECTRUM 
RRUFF ID:
Sample Description: Sample is oriented and mounted on a pin.
Pin ID: L01579
Orientation: Laser parallel to  a*  (1 0 0).     Fiducial mark perpendicular to laser is parallel to  c   [0 0 1].
DOWNLOADS:

  To download sample data,
  please select a specific
  orientation angle.

Raman Mode Analysis
Direction of polarization of laser relative to fiducial mark:
X Min:    X Max:    X Sort:
BROAD SCAN WITH SPECTRAL ARTIFACTS
RRUFF ID: R060799
Wavelength:
Sample Description: Unoriented sample
Instrument settings: Thermo Almega XR 532nm @ 50% of 150mW
POWDER DIFFRACTION 
RRUFF ID: R060799.9
Sample Description: Single crystal, powder profile is calculated
Cell Refinement Output: a: 8.069(5)Å    b: 8.069(5)Å    c: 8.069(5)Å
alpha: 90°    beta: 90°    gamma: 90°   Volume: 525.3(1)Å3    Crystal System: cubic
  File Type Information Close
Calculated diffraction file.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

X Min:    X Max:    X Sort:
REFERENCES for Spinel

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

de Boodt A B, Tollius A, de Laet I, Theophrasti (1647) De rubino spinello, in Gemmarum et Lapidum Historia Lugduni Batavorum, Ex Officina Ioannis Maire 151-151   [view file]

Rome de l´Isle J B L (1783) Genre VII. Cristaux-Gemmes. Espèce III. Rubis spinelle octaèdre, in Cristallographie, Volume 2, 2nd Edition De LĀ“Imprimerie de Monsieur Paris 224-230   [view file]

Klaproth M H (1797) Chemische Untersuchung des Spinells, Beiträge zur Chemischen Kenntniss der Mineralkörper, 2, 1-12   [view file]

Schairer J F, Foshag W F (1927) New mineral names, American Mineralogist, 12, 232-232   [view file]

Zorina N G, Kvitka S S (1968) Refinement of the structure of the spinel Al2MgO4, Soviet Physics - Crystallography, 13, 599-600   [view file]

Dickson B L, Smith G (1976) Low-temperature optical absorption and Mössbauer spectra of staurolite and spinel, The Canadian Mineralogist, 14, 206-215   [view file]

Jansen J B H, Feenstra A, Schuiling R D (1978) A spinel-forming reaction in aluminous dolomitic marbles of Naxos, Greece, Neues Jahrbuch für Mineralogie, Monatshefte, 1978, 145-158

Essene E J, Peacor D R (1983) Crystal chemistry and petrology of coexisting galaxite and jacobsite and other spinel solutions and solvi, American Mineralogist, 68, 449-455   [view file]

Takéuchi Y, Yamanaka T, Haga N, Hirano M (1984) High-temperature crystallography of olivines and spinels, in Materials Science of the Earth's Interior Terra Scientific Pub. Co. Tokyo 191-231

Arean C O, Vinuela J S D (1985) Structural study of copper–nickel aluminate (CuxNi1-xAl2O4) spinels, Journal of Solid State Chemistry, 60, 1-5

Spry P G, Scott S D (1986) Zincian spinel and staurolite as guides to ore in the Appalachians and Scandinavian Caledonides, The Canadian Mineralogist, 24, 147-163   [view file]

Spry P G (1987) Compositional zoning in zincian spinel, The Canadian Mineralogist, 25, 97-104   [view file]

Wang X, Greenwood H J (1988) An experimental study of the equilibrium: grossular + clinochlore = 3 diopside + 2 spinel + 4 H2O, The Canadian Mineralogist, 26, 269-281   [view file]

Cynn H, Sharma S K, Cooney T F, Nicol M (1992) High-temperature Raman investigation of order-disorder behavior in the MgAl2O4 spinel, Physical Review B, 45, 500-502

Waerenborgh J C, Figueiredo M O, Cabral J M P, Pereira L C J (1994) Temperature and composition dependence of the cation distribution in synthetic ZnFeyAl2-yO4(0 < y < 1) spinels, Journal of Solid State Chemistry, 111, 300-309

Wendschuh-Josties M, O'Neill H St C, Bente K, Brey G (1995) Lattice and oxygen parameters of ZnGa2O4 as a function of equilibration temperature, Neues Jahrbuch für Mineralogie, Monatshefte, 1995, 273-280

Cabella R, Gazzotti M, Lucchetti G (1997) Loveringite and baddeleyite in layers of chromian spinel from the Bracco ophiolitic unit, northern Apennines, Italy, The Canadian Mineralogist, 35, 899-908   [view file]

Clynne M A, Borg L E (1997) Olivine and chromian spinel in primitive calc-alkaline and tholeiitic lavas from the southernmost Cascade Range, California: a reflection of relative fertility of the source, The Canadian Mineralogist, 35, 453-472   [view file]

Lutz H D, Kringe C, Mohn K, Stingl T (1998) Decomposition of spinel-type nickel chromium indium sulfides–x-ray powder structure determination, Journal of Solid State Chemistry, 136, 193-198

Redfern S A T, Harrison R J, O'Neill H St C, Wood D R R (1999) Thermodynamics and kinetics of cation ordering in MgAl2O4 spinel up to 1600 °C from in situ neutron diffraction, American Mineralogist, 84, 299-310   [view file]

Grygar T, Bezdicka P, Vorm P, Jordanova N, Krtil P (2001) Spinel solid solutions in the Li-Fe-Mn-O system, Journal of Solid State Chemistry, 161, 152-160

Palos A I, Anne M, Strobel P (2001) Topotactic reactions, structural studies, and lithium intercalation in cation-deficient spinels with formula close to Li2Mn4O9, Journal of Solid State Chemistry, 160, 108-117

Shannon R D, Shannon R C, Medenbach O, Fischer R X (2002) Refractive index and dispersion of flourides and oxides, Journal of Physical and Chemical Reference Data, 31, 931-970   [view file]

Litvinenko A K (2003) Genetic position of precius spinel in magnesium skarns of the South-West Pamirs, Zapiski Vserossijskogo Mineralogicheskogo Obshchestva, 132, issue 1 76-81   [view file]

Nakatsuka A, Ueno H, Nakayama N, Mizota T, Maekawa H (2004) Single-crystal X-ray diffraction study of cation distribution in MgAl2O4 - MgFe2O4 spinel solid solution, Physics and Chemistry of Minerals, 31, 278-287

Uchida H, Lavina B, Downs R T, Chesley J (2005) Single-crystal X-ray diffraction of spinels from the San Carlos Volcanic Field, Arizona: spinel as a geothermometer, American Mineralogist, 90, 1900-1908   [view file]

Martignago F, Andreozzi G B, Dal Negro A (2006) Thermodynamics and kinetics of cation ordering in natural and synthetic Mg(Al,Fe3+)2O4 spinels from in situ high-temperature X-ray diffraction, American Mineralogist, 91, 306-312   [view file]

Princivalle F, Martignago F, Dal Negro A (2006) Kinetics of cation ordering in natural Mg(Al,Cr3+)2O4 spinels, American Mineralogist, 91, 313-318   [view file]

Bosi F, Hålenius U, Andreozzi G B, Skogby H, Lucchesi S (2007) Structural refinement and crystal chemistry of Mn-doped spinel: a case for tetrahedrally coordinated Mn3+ in an oxygen-based structure, American Mineralogist, 92, 27-33   [view file]

Kojitani H, Hisatomi R, Akaogi M (2007) High-pressure relations and crystal chemistry of calcium ferrite-type solid solutions in the system MgAl2O4-Mg2SiO4, American Mineralogist, 92, 1112-1118   [view file]

Liu X, O’Neill H St. C (2007) Effects of P2O5 and TiO2 on the partial melting of spinel lherzolite in the system CaO—MgO—Al2O3—SiO2 at 1.1 GPa, The Canadian Mineralogist, 45, 649-655   [view file]

Nestola F, Boffa Ballaran T, Balic-Zunic T, Princivalle F, Secco L, Dal Negro A (2007) Comparative compressibility and structural behavior of spinel MgAl2O4 at high pressures: the independency on the degree of cation order, American Mineralogist, 92, 1838-1843   [view file]

Palin E J, Harrison R J (2007) A Monte Carlo investigation of the thermodynamics of cation ordering in 2-3 spinels, American Mineralogist, 92, 1334-1345   [view file]

Bosi F, Hålenius U, D'Ippolito V, Andreozzi G B (2012) Blue spinel crystals in the MgAl2O4-CoAl2O4 series: Part II. Cation ordering over short-range and long-range scales, American Mineralogist, 97, 1834-1840   [view file]

D'Ippolito V, Andreozzi G B, Bosi F, Hålenius U (2012) Blue spinel crystals in the MgAl2O4-CoAl2O4 series: Part I. Flux growth and chemical characterization, American Mineralogist, 97, 1828-1833   [view file]

Fregola R A, Bosi F, Skogby H, Hålenius U (2012) Cation ordering over short-range and long-range scales in the MgAl2O4-CuAl2O4 series, American Mineralogist, 97, 1821-1827   [view file]

Princivalle F, Martignago F, Nestola F, Dal Negro A (2012) Kinetics of cation ordering in synthetic Mg(Al,Fe3+)2O4 spinels, European Journal of Mineralogy, 24, 633-643

Woodland A B, Angel R J, Koch M (2012) Structural systematics of spinel and spinelloid phases in the system MFe2O4-M2SiO4 with M = Fe2+ and Mg, European Journal of Mineralogy, 24, 657-668

Bonazzi P, Chelazzi L, Bindi L (2013) Superstructure, crystal chemistry, and cation distribution in filipstadite, a Sb5+-bearing, spinel-related mineral, American Mineralogist, 98, 361-366

Reichmann H J, Jacobsen S D, Ballaran T B (2013) Elasticity of franklinite and trends for transition-metal oxide spinels, American Mineralogist, 98, 601-608

Alvaro M, Nestola F, Ross N, Domeneghetti C, Reznitsky L (2014) High-pressure behavior of thiospinel CuCr2S4, American Mineralogist, 99, 908-913

Biagoni C, Pasero M (2014) The systematics of the spinel-type minerals: An overview, American Mineralogist, 99, 1254-1264

Lenaz D, Youbi N, Min A D, Boumehdi M A, Abbou M B (2014) Low intra-crystalline closure temperatures of Cr-bearing spinels from the mantle xenoliths of the Middle Atlas Neogene-Quaternary Volcanic Field (Morocco): Mineralogical evidence of a cooler mantle beneath the West African Craton, American Mineralogist, 99, 267-275

Robinson P, Langenhorst F, McEnroe S A, Fabian K, Ballaran T B (2014) Ferroan geikielite and coupled spinel-rutile exsolution from titanohematite: interface characterization and magnetic properties, American Mineralogist, 99, 1694-1712

Bruschini E, Speziale S, Andreozzi G B, Bosi F, Hålenius U (2015) The elasticity of MgAl2O4–MnAl2O4 spinels by Brillouin scattering and an empirical approach for bulk modulus prediction, American Mineralogist, 100, 644-651

Erukhimovitch V, Mordekoviz Y, Hayun S (2015) Spectroscopic study of ordering in non-stoichiometric magnesium aluminate spinel, American Mineralogist, 100, 1744-1751

Nestola F, Periotto B, Anzolini C, Andreozzi G B, Woodland A B, Lenaz D, Alvaro M, Princivalle F (2015) Equation of state of hercynite, FeAl2O4, and high-pressure systematics of Mg-Fe-Cr-Al spinels, Mineralogical Magazine, 79, 285-294

Papike J J, Burger P V, Bell A S, Shearer C K, Le L, Jones J (2015) Normal to inverse transition in martian spinel: understanding the interplay between chromium, vanadium, and iron valence state partitioning through a crystal-chemical lens, American Mineralogist, 100, 2018-2025

Lenaz D, Velicogna M, Hålenius U, O'Driscoll B (2016) Structural parameters of Cr-bearing spinels and pleonaste from the Cuillin Igneous Complex (Isle of Skye, Scotland): Implications for metamorphic and cooling history, Mineralogical Magazine, 80, 749-763

Giebel R J, Gauert C D K, Marks M A W, Costin G, Markl G (2017) Multi-stage formation of REE minerals in the Palabora Carbonatite Complex, South Africa, American Mineralogist, 102, 1218-1233

Jastrzębska I, Szczerba J, Błachowski A, Stoch P (2017) Structure and microstructure evolution of hercynite spinel (Fe2+Al2O4) after annealing treatment, European Journal of Mineralogy, 29, 63-72

Lenaz D, Lughi V (2017) Raman spectroscopy and the inversion degree of natural Cr-bearing spinels, American Mineralogist, 102, 327-332