" R040113 - RRUFF Database: Raman, X-ray, Infrared, and Chemistry

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Marialite R040113

Name: Marialite
RRUFF ID: R040113
Ideal Chemistry: Na₄Al₃Si₉O₂₄Cl
Locality: Gouverneur, New York, USA
Source: University of Arizona Mineral Museum 4398 [view label]
Owner: RRUFF
Description: Green prismatic crystal
Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis

Mineral Group: [ Scapolite (11) ]

Quick search: [ All Marialite samples (10) ]

CHEMISTRY

RRUFF ID:	R040113.2
Sample Description:	Microprobe fragment
Measured Chemistry:	(Na_0.50Ca_0.43K_0.07)₄(Si_0.64Al_0.36)₁₂O₂₄(Cl_0.60(CO₃)_0.40)

RAMAN SPECTRUM

RRUFF ID:

Sample Description:

Sample is oriented, mounted on a pin, and polished.

Pin ID:

L01738

Orientation:

Laser parallel to -a* (-1 0 0). Fiducial mark perpendicular to laser is parallel to c [0 0 1].

DOWNLOADS:

To download sample data,
please select a specific
orientation angle.

Raman Mode Analysis

BROAD SCAN WITH SPECTRAL ARTIFACTS

RRUFF ID:

R040113

Wavelength:

Sample Description:

Unoriented sample

Instrument settings:

Thermo Almega XR 532nm @ 100% of 150mW

DOWNLOADS:

	Raman Data (RAW)
	RRUFF File

INFRARED SPECTRUM (Attenuated Total Reflectance)

RRUFF ID:

R040113.1

Sample Description:

Powder

Instrument settings:

SensIR Durascope on a Nicolet Magna 860 FTIR

Resolution:

DOWNLOADS:

	Infrared Data (Processed)
	RRUFF File

POWDER DIFFRACTION

RRUFF ID:

R040113.1

Sample Description:

Powder

Cell Refinement Output:

a: 12.1082(4)Å b: 12.1082(4)Å c: 7.5787(2)Å
alpha: 90.° beta: 90.° gamma: 90.° Volume: 1111.12(6)Å³ Crystal System: tetragonal

File Type Information

Calculated diffraction file.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

DOWNLOADS:

	Cell Refinement Data
	Cell Refinement Output Data
	DIF File
	X-ray Data (XY - Processed)
	RRUFF File
	X-ray Data (XY - RAW)
	RRUFF File

REFERENCES for Marialite
American Mineralogist Crystal Structure Database Record: [view record]
Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]
d’Andrada J B (1800) Der Eigenschaften und Kennzeichen einiger neuen Fossilien aus Schweden und Norwegen nebst einigen chemischen Bemerkungen über dieselben, Allgemeines Journal der Chemie, 4, 28-39 [view file]
d’Andrada J B (1801) Description of some new fossils (Old English translation), A Journal of Natural Philosophy, Chemistry, and the Arts, 5, 193-196; 211-213 [view file]
Haüy R J (1801) Wernerite, Traité de Minéralogie, 3, 119-125 [view file]
vom Rath G (1866) Mineralogisch-geognostische Fragmente aus Italien, Zeitschrift der Deutschen Geologischen Gesellschaft, 18, 487-642 [view file]
Pauling L (1930) The structure of some sodium and calcium aluminosilicates, Proceedings of the National Academy of Sciences, 16, 453-459 [view file]
Papike J J, Zoltai T (1965) The crystal structure of a marialite scapolite, American Mineralogist, 50, 641-655 [view file]
Lin S B, Burley B J (1973) Crystal structure of a sodium and chlorine-rich scapolite, Acta Crystallographica, B29, 1272-1278
Ulbrich H H (1973) Crystallographic data and refractive indices of scapolites, American Mineralogist, 58, 81-92 [view file]
Lin S B, Burley B J (1974) The crystal structure of an intermediate scapolite - wernerite, Tschermaks Mineralogische und Petrographische Mitteilungen, 21, 196-215
Llambías E J, Gordillo C E, Bedlivy D (1977) Scapolite veins in a quartz monzodiorite stock from Los Molles, Mendoza, Argentina, American Mineralogist, 62, 132-135 [view file]
Bayliss P (1987) Mineral nomenclature: scapolite, Mineralogical Magazine, 51, 176-176 [view file]
Zolotarev A A (1993) Gem scapolite from the Eastern Pamirs and some general consitutional features of scapolites, Zapiski Vserossijskogo Mineralogicheskogo Obshchestva, 122, 90-102 [view file]
Sokolova E V, Kabalov Y K, Sherriff B L, Teertstra D K, Jenkins D M, Kunath-Fandrei G, Goetz S, Jäger C (1996) Marialite: Rietveld structure-refinement and ²⁹Si MAS and ²⁷Al satellite transition NMR spectroscopy, The Canadian Mineralogist, 34, 1039-1050 [view file]
Teertstra D K, Sherriff B L (1996) Scapolite cell-parameter trends along the solid-solution series, American Mineralogist, 81, 169-180 [view file]
Zolotarev A A (1996) Once more about schemes and rows of isomorphism within the scapolite group, Zapiski Vserossijskogo Mineralogicheskogo Obshchestva, 125, issue 1 69-73 [view file]
Antao S M, Hassan I (2008) Increase in Al-Si and Na-Ca disorder with temperature in scapolite Me_32.9, The Canadian Mineralogist, 46, 1577-1591 [view file]
Sokolova E, Hawthorne F C (2008) The crystal chemistry of the scapolite-group minerals. I. crystal structure and long-range order, The Canadian Mineralogist, 46, 1527-1554 [view file]
Antao S M, Hassan I (2011) Complete Al-Si order in scapolite Me_37.5, ideally Ca₃Na₅[Al₈Si₁₆O₄₈]Cl(CO₃), and implications for antiphase domain boundaries (APBs), The Canadian Mineralogist, 49, 581-586 [view file]
Antao S M, Hassan I (2011) The structure of marialite (Me₆) and meionite (Me₉₃) in space groups P4₂/n and I4/m, and the absence of phase transitions in the scapolite series, International Centre for Diffraction Data, 26, 78-91 [view file]
Almeida K M F, Jenkins D M (2017) Stability field of the Cl-rich scapolite marialite, American Mineralogist, 102, 2484-2493

REFERENCES for Marialite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

d’Andrada J B (1800) Der Eigenschaften und Kennzeichen einiger neuen Fossilien aus Schweden und Norwegen nebst einigen chemischen Bemerkungen über dieselben, Allgemeines Journal der Chemie, 4, 28-39 [view file]

d’Andrada J B (1801) Description of some new fossils (Old English translation), A Journal of Natural Philosophy, Chemistry, and the Arts, 5, 193-196; 211-213 [view file]

Haüy R J (1801) Wernerite, Traité de Minéralogie, 3, 119-125 [view file]

vom Rath G (1866) Mineralogisch-geognostische Fragmente aus Italien, Zeitschrift der Deutschen Geologischen Gesellschaft, 18, 487-642 [view file]

Pauling L (1930) The structure of some sodium and calcium aluminosilicates, Proceedings of the National Academy of Sciences, 16, 453-459 [view file]

Papike J J, Zoltai T (1965) The crystal structure of a marialite scapolite, American Mineralogist, 50, 641-655 [view file]

Lin S B, Burley B J (1973) Crystal structure of a sodium and chlorine-rich scapolite, Acta Crystallographica, B29, 1272-1278

Ulbrich H H (1973) Crystallographic data and refractive indices of scapolites, American Mineralogist, 58, 81-92 [view file]

Lin S B, Burley B J (1974) The crystal structure of an intermediate scapolite - wernerite, Tschermaks Mineralogische und Petrographische Mitteilungen, 21, 196-215

Llambías E J, Gordillo C E, Bedlivy D (1977) Scapolite veins in a quartz monzodiorite stock from Los Molles, Mendoza, Argentina, American Mineralogist, 62, 132-135 [view file]

Bayliss P (1987) Mineral nomenclature: scapolite, Mineralogical Magazine, 51, 176-176 [view file]

Zolotarev A A (1993) Gem scapolite from the Eastern Pamirs and some general consitutional features of scapolites, Zapiski Vserossijskogo Mineralogicheskogo Obshchestva, 122, 90-102 [view file]

Sokolova E V, Kabalov Y K, Sherriff B L, Teertstra D K, Jenkins D M, Kunath-Fandrei G, Goetz S, Jäger C (1996) Marialite: Rietveld structure-refinement and ²⁹Si MAS and ²⁷Al satellite transition NMR spectroscopy, The Canadian Mineralogist, 34, 1039-1050 [view file]

Teertstra D K, Sherriff B L (1996) Scapolite cell-parameter trends along the solid-solution series, American Mineralogist, 81, 169-180 [view file]

Zolotarev A A (1996) Once more about schemes and rows of isomorphism within the scapolite group, Zapiski Vserossijskogo Mineralogicheskogo Obshchestva, 125, issue 1 69-73 [view file]

Antao S M, Hassan I (2008) Increase in Al-Si and Na-Ca disorder with temperature in scapolite Me_32.9, The Canadian Mineralogist, 46, 1577-1591 [view file]

Sokolova E, Hawthorne F C (2008) The crystal chemistry of the scapolite-group minerals. I. crystal structure and long-range order, The Canadian Mineralogist, 46, 1527-1554 [view file]

Antao S M, Hassan I (2011) Complete Al-Si order in scapolite Me_37.5, ideally Ca₃Na₅[Al₈Si₁₆O₄₈]Cl(CO₃), and implications for antiphase domain boundaries (APBs), The Canadian Mineralogist, 49, 581-586 [view file]

Antao S M, Hassan I (2011) The structure of marialite (Me₆) and meionite (Me₉₃) in space groups P4₂/n and I4/m, and the absence of phase transitions in the scapolite series, International Centre for Diffraction Data, 26, 78-91 [view file]

Almeida K M F, Jenkins D M (2017) Stability field of the Cl-rich scapolite marialite, American Mineralogist, 102, 2484-2493