,32.2531,-110.948 R060416 - RRUFF Database: Raman, X-ray, Infrared, and Chemistry

Sodalite R060416

Name: Sodalite
RRUFF ID: R060416
Ideal Chemistry: Na₄(Si₃Al₃)O₁₂Cl
Locality: Koksha Valley, Badakshan Province, Afghanistan
Source: Herb Obodda 109 [view label]
Owner: RRUFF
Description: Colorless fragment
Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis

Mineral Groups: [ cancrinite-sodalite (37) ] [ sodalite (24) ]

Quick search: [ All Sodalite samples (8) ]

CHEMISTRY

RRUFF ID:	R060416.2
Sample Description:	Microprobe fragment
Measured Chemistry:	Na_8.00Al_6.00Si_6.00O₂₄Cl_2.00

RAMAN SPECTRUM

RRUFF ID:

Sample Description:

Sample is oriented, mounted on a pin, and polished.

Pin ID:

L01209

Orientation:

Laser parallel to -a* (-1 0 0). Fiducial mark perpendicular to laser is parallel to b [0 1 0].

DOWNLOADS:

To download sample data,
please select a specific
orientation angle.

Raman Mode Analysis

BROAD SCAN WITH SPECTRAL ARTIFACTS

RRUFF ID:

R060416

Wavelength:

Sample Description:

Unoriented Raman on the primary sample

Instrument settings:

Thermo Almega XR 532nm @ 100% of 150mW

DOWNLOADS:

	Raman Data (RAW)
	RRUFF File

POWDER DIFFRACTION

RRUFF ID:

R060416.1

Sample Description:

Powder

Cell Refinement Output:

a: 8.88077(4)Å b: 8.88077(4)Å c: 8.88077(4)Å
alpha: 90.° beta: 90.° gamma: 90.° Volume: 700.410(9)Å³ Crystal System: cubic

File Type Information

Calculated diffraction file.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

DOWNLOADS:

	Cell Refinement Data
	Cell Refinement Output Data
	DIF File
	X-ray Data (XY - Processed)
	RRUFF File
	X-ray Data (XY - RAW)
	RRUFF File

REFERENCES for Sodalite
American Mineralogist Crystal Structure Database Record: [view record]
Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]
Thomson T (1811) A chemical analysis of sodalite, a new mineral from Greenland, A Journal of Natural Philosophy, Chemistry, and the Arts, 29, 285-292 [view file]
Thomson T (1812) A chemical analysis of sodalite, a new mineral from Greenland, Transactions of the Royal Society of Edinburgh, 6, 387-395 [view file]
Rose G (1839) Ueber den Sodalith und Cancrinit, Journal für Praktische Chemie, 17, 348-351 [view file]
Lorenzen J (1882) On some minerals from the sodalite-syenite in the Juliane-haab district, south Greenland, Mineralogical Magazine, 5, 49-70 [view file]
Barrer R M, White E A D (1952) The hydrothermal chemitry of silicates Part II.* Synthetic crystalline sodium aluminosilicates, Journal of the Chemical Society, 1952, 1561-1571 [view file]
Van Peteghem J K, Burley B J (1963) Studies on solid solution between sodalite, nosean and hauyne, The Canadian Mineralogist, 7, 808-813 [view file]
Subbarao K V (1969) An intergrowth between albite and sodalite, The Canadian Mineralogist, 9, 721-723 [view file]
Sturt B A, Ramsay D M (1971) Observation on "An intergrowth between albite and sodalite", The Canadian Mineralogist, 10, 904-904 [view file]
Annersten H, Hassib A (1979) Blue sodalite, The Canadian Mineralogist, 17, 39-46 [view file]
Leoni L, Mellini M, Merlino S, Orlandi P (1979) Cancrinite-like minerals: new data and crystal chemical considerations, Rendiconti della Società Italiana di Mineralogia e Petrologia, 35, 713-719 [view file]
Peterson R C (1983) The structure of hackmanite, a variety of sodalite, from Mont St-Hilaire, Quebec, The Canadian Mineralogist, 21, 549-552 [view file]
Hassan I, Grundy H D (1984) The crystal structures of sodalite-group minerals, Acta Crystallographica, B40, 6-13
Papike J J (1988) Chemistry of the rock-forming silicates: Multiple-chain, sheet, and framework structures, Reviews of Geophysics, 26, 407-444 [view file]
Pinckston R D, Smith D G W (1994) Mineralogy of the Lake zone, Thor Lake rare-metals deposit, N.W.T., Canada, Canadian Journal of Earth Sciences, 32, 516-532
Behrens P, Kempa P B, Assmann S, Wiebcke M, Felsche J (1995) The structures of anhydrous silver sodalite Ag₃[Al₃Si₃O₁₂] at 298, 623, and 723 K from Rietveld refinements of X-ray powder diffraction data: mechanism of thermal expansion and of the phase transition at 678 K, Journal of Solid State Chemistry, 115, 55-65
Ballirano P, Maras A, Buseck P R (1996) Crystal chemistry and IR spectroscopy of Cl- and SO₄-bearing cancrinite-like minerals, American Mineralogist, 81, 1003-1012 [view file]
Thompson J G, Dougherty J, Melnitchenko A, Lobo C, Withers R L (1996) Sodalite-type Na₈Mg₃Si₉O₂₄(OH)₂ and Na₈Mg₃Si₉O₂₄(OH,Cl)₂: novel framework magnesiosilicates, Journal of Materials Chemistry, 6, 1933-1937
Smaalen S, Dinnebier R, Katzke H, Depmeier W (1997) Structural characterization of the high-temperature phase transitions in Ca₈[Al₁₂O₂₄](MoO₄)₂ aluminate sodalite using x-ray powder diffraction, Journal of Solid State Chemistry, 129, 130-143
Antao S M, Hassan I (2002) Thermal analyses of sodalite, tugtupite, danalite and helvite, The Canadian Mineralogist, 40, 163-172 [view file]
Shannon R D, Shannon R C, Medenbach O, Fischer R X (2002) Refractive index and dispersion of fluorides and oxides, Journal of Physical and Chemical Reference Data, 31, 931-970 [view file]
Pan Y, Dong P (2003) Bromine in scapolite-group minerals and sodalite: XRF microprobe analysis, exchange experiments, and application to skarn deposits, The Canadian Mineralogist, 41, 529-540 [view file]
Hassan I, Antao S M, Parise J B (2004) Sodalite: high-temperature structures obtained from synchrotron radiation and rietveld refinements, American Mineralogist, 89, 359-364 [view file]
Ballirano P, Maras A (2005) Crystal chemical and structural characterization of an unusual CO₃-bearing sodalite-group mineral, European Journal of Mineralogy, 17, 805-812
Antao S M, Hassan I, Wang J, Lee P L, Toby B H (2008) State-of-the-art high-resolution powder x-ray diffraction (HRPXRD) illustrated with Rietveld structure refinement of quartz, sodalite, tremolite, and meionite, The Canadian Mineralogist, 46, 1501-1509 [view file]
Hettmann K, Wenzel T, Marks M, Markl G (2012) The sulfur speciation in S-bearing minerals: New constraints by a combination of electron microprobe analysis and DFT calculations with special reference to sodalite-group minerals, American Mineralogist, 97, 1653-1661 [view file]
Balassone G, Bellatreccia F, Ottolini L, Mormone A, Petti C, Ghiara M R, Altomare A, Saviano M, Rizi R, D'Orazio L (2016) Sodalite-group minerals, from the Somma-Vesuvius volcano (Naples, Italy): A combined EPMA, SIMS, and FTIR crystal-chemical study, The Canadian Mineralogist, 54, 583-604

REFERENCES for Sodalite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Thomson T (1811) A chemical analysis of sodalite, a new mineral from Greenland, A Journal of Natural Philosophy, Chemistry, and the Arts, 29, 285-292 [view file]

Thomson T (1812) A chemical analysis of sodalite, a new mineral from Greenland, Transactions of the Royal Society of Edinburgh, 6, 387-395 [view file]

Rose G (1839) Ueber den Sodalith und Cancrinit, Journal für Praktische Chemie, 17, 348-351 [view file]

Lorenzen J (1882) On some minerals from the sodalite-syenite in the Juliane-haab district, south Greenland, Mineralogical Magazine, 5, 49-70 [view file]

Barrer R M, White E A D (1952) The hydrothermal chemitry of silicates Part II.* Synthetic crystalline sodium aluminosilicates, Journal of the Chemical Society, 1952, 1561-1571 [view file]

Van Peteghem J K, Burley B J (1963) Studies on solid solution between sodalite, nosean and hauyne, The Canadian Mineralogist, 7, 808-813 [view file]

Subbarao K V (1969) An intergrowth between albite and sodalite, The Canadian Mineralogist, 9, 721-723 [view file]

Sturt B A, Ramsay D M (1971) Observation on "An intergrowth between albite and sodalite", The Canadian Mineralogist, 10, 904-904 [view file]

Annersten H, Hassib A (1979) Blue sodalite, The Canadian Mineralogist, 17, 39-46 [view file]

Leoni L, Mellini M, Merlino S, Orlandi P (1979) Cancrinite-like minerals: new data and crystal chemical considerations, Rendiconti della Società Italiana di Mineralogia e Petrologia, 35, 713-719 [view file]

Peterson R C (1983) The structure of hackmanite, a variety of sodalite, from Mont St-Hilaire, Quebec, The Canadian Mineralogist, 21, 549-552 [view file]

Hassan I, Grundy H D (1984) The crystal structures of sodalite-group minerals, Acta Crystallographica, B40, 6-13

Papike J J (1988) Chemistry of the rock-forming silicates: Multiple-chain, sheet, and framework structures, Reviews of Geophysics, 26, 407-444 [view file]

Pinckston R D, Smith D G W (1994) Mineralogy of the Lake zone, Thor Lake rare-metals deposit, N.W.T., Canada, Canadian Journal of Earth Sciences, 32, 516-532

Behrens P, Kempa P B, Assmann S, Wiebcke M, Felsche J (1995) The structures of anhydrous silver sodalite Ag₃[Al₃Si₃O₁₂] at 298, 623, and 723 K from Rietveld refinements of X-ray powder diffraction data: mechanism of thermal expansion and of the phase transition at 678 K, Journal of Solid State Chemistry, 115, 55-65

Ballirano P, Maras A, Buseck P R (1996) Crystal chemistry and IR spectroscopy of Cl- and SO₄-bearing cancrinite-like minerals, American Mineralogist, 81, 1003-1012 [view file]

Thompson J G, Dougherty J, Melnitchenko A, Lobo C, Withers R L (1996) Sodalite-type Na₈Mg₃Si₉O₂₄(OH)₂ and Na₈Mg₃Si₉O₂₄(OH,Cl)₂: novel framework magnesiosilicates, Journal of Materials Chemistry, 6, 1933-1937

Smaalen S, Dinnebier R, Katzke H, Depmeier W (1997) Structural characterization of the high-temperature phase transitions in Ca₈[Al₁₂O₂₄](MoO₄)₂ aluminate sodalite using x-ray powder diffraction, Journal of Solid State Chemistry, 129, 130-143

Antao S M, Hassan I (2002) Thermal analyses of sodalite, tugtupite, danalite and helvite, The Canadian Mineralogist, 40, 163-172 [view file]

Shannon R D, Shannon R C, Medenbach O, Fischer R X (2002) Refractive index and dispersion of fluorides and oxides, Journal of Physical and Chemical Reference Data, 31, 931-970 [view file]

Pan Y, Dong P (2003) Bromine in scapolite-group minerals and sodalite: XRF microprobe analysis, exchange experiments, and application to skarn deposits, The Canadian Mineralogist, 41, 529-540 [view file]

Hassan I, Antao S M, Parise J B (2004) Sodalite: high-temperature structures obtained from synchrotron radiation and rietveld refinements, American Mineralogist, 89, 359-364 [view file]

Ballirano P, Maras A (2005) Crystal chemical and structural characterization of an unusual CO₃-bearing sodalite-group mineral, European Journal of Mineralogy, 17, 805-812

Antao S M, Hassan I, Wang J, Lee P L, Toby B H (2008) State-of-the-art high-resolution powder x-ray diffraction (HRPXRD) illustrated with Rietveld structure refinement of quartz, sodalite, tremolite, and meionite, The Canadian Mineralogist, 46, 1501-1509 [view file]

Hettmann K, Wenzel T, Marks M, Markl G (2012) The sulfur speciation in S-bearing minerals: New constraints by a combination of electron microprobe analysis and DFT calculations with special reference to sodalite-group minerals, American Mineralogist, 97, 1653-1661 [view file]

Balassone G, Bellatreccia F, Ottolini L, Mormone A, Petti C, Ghiara M R, Altomare A, Saviano M, Rizi R, D'Orazio L (2016) Sodalite-group minerals, from the Somma-Vesuvius volcano (Naples, Italy): A combined EPMA, SIMS, and FTIR crystal-chemical study, The Canadian Mineralogist, 54, 583-604