Scapolite R100112 - RRUFF Database: Raman, X-ray, Infrared, and Chemistry

Marialite R100112

Name: Marialite
RRUFF ID: R100112
Ideal Chemistry: Na₄Al₃Si₉O₂₄Cl
Locality: Sar-e-Sang District, Koksha Valley, Badakhshan Province, Afghanistan
Source: Robert Woodside [view label]
Owner: RRUFF
Description: Colorless crystal fragment
Status: The identification of this mineral has been confirmed only by single crystal X-ray diffraction.

Mineral Group: [ Scapolite (11) ]

Quick search: [ All Marialite samples (10) ]

RAMAN SPECTRUM

RRUFF ID:

Sample Description:

Unoriented Raman on the primary sample

DOWNLOADS:

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orientation angle.

Raman Mode Analysis

BROAD SCAN WITH SPECTRAL ARTIFACTS

RRUFF ID:

R100112

Wavelength:

Sample Description:

Unoriented Raman on the primary sample

Instrument settings:

Thermo Almega XR 532nm @ 100% of 150mW

DOWNLOADS:

	Raman Data (Processed)
	RRUFF File
	Raman Data (RAW)
	RRUFF File

POWDER DIFFRACTION

RRUFF ID:

R100112.9

Sample Description:

Single crystal, powder profile is calculated

Cell Refinement Output:

a: 12.057(1)Å b: 12.057(1)Å c: 7.581(1)Å
alpha: 90° beta: 90° gamma: 90° Volume: 1102.0(2)Å³ Crystal System: tetragonal

File Type Information

Calculated diffraction file.

File Type Information

Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

DOWNLOADS:

	DIF File
	X-ray Data (XY - RAW)
	RRUFF File

REFERENCES for Marialite
American Mineralogist Crystal Structure Database Record: [view record]
Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]
d’Andrada J B (1800) Der Eigenschaften und Kennzeichen einiger neuen Fossilien aus Schweden und Norwegen nebst einigen chemischen Bemerkungen über dieselben, Allgemeines Journal der Chemie, 4, 28-39 [view file]
d’Andrada J B (1801) Description of some new fossils (Old English translation), A Journal of Natural Philosophy, Chemistry, and the Arts, 5, 193-196; 211-213 [view file]
Haüy R J (1801) Wernerite, Traité de Minéralogie, 3, 119-125 [view file]
vom Rath G (1866) Mineralogisch-geognostische Fragmente aus Italien, Zeitschrift der Deutschen Geologischen Gesellschaft, 18, 487-642 [view file]
Pauling L (1930) The structure of some sodium and calcium aluminosilicates, Proceedings of the National Academy of Sciences, 16, 453-459 [view file]
Papike J J, Zoltai T (1965) The crystal structure of a marialite scapolite, American Mineralogist, 50, 641-655 [view file]
Lin S B, Burley B J (1973) Crystal structure of a sodium and chlorine-rich scapolite, Acta Crystallographica, B29, 1272-1278
Ulbrich H H (1973) Crystallographic data and refractive indices of scapolites, American Mineralogist, 58, 81-92 [view file]
Lin S B, Burley B J (1974) The crystal structure of an intermediate scapolite - wernerite, Tschermaks Mineralogische und Petrographische Mitteilungen, 21, 196-215
Llambías E J, Gordillo C E, Bedlivy D (1977) Scapolite veins in a quartz monzodiorite stock from Los Molles, Mendoza, Argentina, American Mineralogist, 62, 132-135 [view file]
Bayliss P (1987) Mineral nomenclature: scapolite, Mineralogical Magazine, 51, 176-176 [view file]
Zolotarev A A (1993) Gem scapolite from the Eastern Pamirs and some general consitutional features of scapolites, Zapiski Vserossijskogo Mineralogicheskogo Obshchestva, 122, 90-102 [view file]
Sokolova E V, Kabalov Y K, Sherriff B L, Teertstra D K, Jenkins D M, Kunath-Fandrei G, Goetz S, Jäger C (1996) Marialite: Rietveld structure-refinement and ²⁹Si MAS and ²⁷Al satellite transition NMR spectroscopy, The Canadian Mineralogist, 34, 1039-1050 [view file]
Teertstra D K, Sherriff B L (1996) Scapolite cell-parameter trends along the solid-solution series, American Mineralogist, 81, 169-180 [view file]
Zolotarev A A (1996) Once more about schemes and rows of isomorphism within the scapolite group, Zapiski Vserossijskogo Mineralogicheskogo Obshchestva, 125, issue 1 69-73 [view file]
Antao S M, Hassan I (2008) Increase in Al-Si and Na-Ca disorder with temperature in scapolite Me_32.9, The Canadian Mineralogist, 46, 1577-1591 [view file]
Sokolova E, Hawthorne F C (2008) The crystal chemistry of the scapolite-group minerals. I. crystal structure and long-range order, The Canadian Mineralogist, 46, 1527-1554 [view file]
Antao S M, Hassan I (2011) Complete Al-Si order in scapolite Me_37.5, ideally Ca₃Na₅[Al₈Si₁₆O₄₈]Cl(CO₃), and implications for antiphase domain boundaries (APBs), The Canadian Mineralogist, 49, 581-586 [view file]
Antao S M, Hassan I (2011) The structure of marialite (Me₆) and meionite (Me₉₃) in space groups P4₂/n and I4/m, and the absence of phase transitions in the scapolite series, International Centre for Diffraction Data, 26, 78-91 [view file]
Almeida K M F, Jenkins D M (2017) Stability field of the Cl-rich scapolite marialite, American Mineralogist, 102, 2484-2493

REFERENCES for Marialite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

d’Andrada J B (1800) Der Eigenschaften und Kennzeichen einiger neuen Fossilien aus Schweden und Norwegen nebst einigen chemischen Bemerkungen über dieselben, Allgemeines Journal der Chemie, 4, 28-39 [view file]

d’Andrada J B (1801) Description of some new fossils (Old English translation), A Journal of Natural Philosophy, Chemistry, and the Arts, 5, 193-196; 211-213 [view file]

Haüy R J (1801) Wernerite, Traité de Minéralogie, 3, 119-125 [view file]

vom Rath G (1866) Mineralogisch-geognostische Fragmente aus Italien, Zeitschrift der Deutschen Geologischen Gesellschaft, 18, 487-642 [view file]

Pauling L (1930) The structure of some sodium and calcium aluminosilicates, Proceedings of the National Academy of Sciences, 16, 453-459 [view file]

Papike J J, Zoltai T (1965) The crystal structure of a marialite scapolite, American Mineralogist, 50, 641-655 [view file]

Lin S B, Burley B J (1973) Crystal structure of a sodium and chlorine-rich scapolite, Acta Crystallographica, B29, 1272-1278

Ulbrich H H (1973) Crystallographic data and refractive indices of scapolites, American Mineralogist, 58, 81-92 [view file]

Lin S B, Burley B J (1974) The crystal structure of an intermediate scapolite - wernerite, Tschermaks Mineralogische und Petrographische Mitteilungen, 21, 196-215

Llambías E J, Gordillo C E, Bedlivy D (1977) Scapolite veins in a quartz monzodiorite stock from Los Molles, Mendoza, Argentina, American Mineralogist, 62, 132-135 [view file]

Bayliss P (1987) Mineral nomenclature: scapolite, Mineralogical Magazine, 51, 176-176 [view file]

Zolotarev A A (1993) Gem scapolite from the Eastern Pamirs and some general consitutional features of scapolites, Zapiski Vserossijskogo Mineralogicheskogo Obshchestva, 122, 90-102 [view file]

Sokolova E V, Kabalov Y K, Sherriff B L, Teertstra D K, Jenkins D M, Kunath-Fandrei G, Goetz S, Jäger C (1996) Marialite: Rietveld structure-refinement and ²⁹Si MAS and ²⁷Al satellite transition NMR spectroscopy, The Canadian Mineralogist, 34, 1039-1050 [view file]

Teertstra D K, Sherriff B L (1996) Scapolite cell-parameter trends along the solid-solution series, American Mineralogist, 81, 169-180 [view file]

Zolotarev A A (1996) Once more about schemes and rows of isomorphism within the scapolite group, Zapiski Vserossijskogo Mineralogicheskogo Obshchestva, 125, issue 1 69-73 [view file]

Antao S M, Hassan I (2008) Increase in Al-Si and Na-Ca disorder with temperature in scapolite Me_32.9, The Canadian Mineralogist, 46, 1577-1591 [view file]

Sokolova E, Hawthorne F C (2008) The crystal chemistry of the scapolite-group minerals. I. crystal structure and long-range order, The Canadian Mineralogist, 46, 1527-1554 [view file]

Antao S M, Hassan I (2011) Complete Al-Si order in scapolite Me_37.5, ideally Ca₃Na₅[Al₈Si₁₆O₄₈]Cl(CO₃), and implications for antiphase domain boundaries (APBs), The Canadian Mineralogist, 49, 581-586 [view file]

Antao S M, Hassan I (2011) The structure of marialite (Me₆) and meionite (Me₉₃) in space groups P4₂/n and I4/m, and the absence of phase transitions in the scapolite series, International Centre for Diffraction Data, 26, 78-91 [view file]

Almeida K M F, Jenkins D M (2017) Stability field of the Cl-rich scapolite marialite, American Mineralogist, 102, 2484-2493