Annabergite R050462

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Name: Annabergite
RRUFF ID: R050462
Ideal Chemistry: Ni3(AsO4)2·8H2O
Locality: Plaka mine, Laurium, Attica, Greece
Source: University of Arizona Mineral Museum 2447 [view label]
Owner: RRUFF
Description: Green bladed crystals
Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis
Mineral Group: [ Vivianite (17) ]
Quick search: [ All Annabergite samples (2) ]
CHEMISTRY 
RRUFF ID: R050462.2
Sample Description: Microprobe fragment
Measured Chemistry: (Ni2.97Zn0.03)Σ=3(As1.00O4)2·8H2O; lighter vein: (Ni2.95Zn0.05)Σ=3(As1.00O4)2·8H2O
Microprobe Data File: [ Download Excel File ]
RAMAN SPECTRUM 
RRUFF ID:
Sample Description: Unoriented sample
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BROAD SCAN WITH SPECTRAL ARTIFACTS
RRUFF ID: R050462
Wavelength:
Sample Description: Unoriented sample
Instrument settings: Thermo Almega XR 532nm @ 100% of 150mW
INFRARED SPECTRUM (Attenuated Total Reflectance) 
RRUFF ID: R050462.1
Sample Description: Powder
Instrument settings: SensIR Durascope on a Nicolet Magna 860 FTIR
Resolution:
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POWDER DIFFRACTION 
RRUFF ID: R050462.1
Sample Description: Powder
Cell Refinement Output: a: 10.192(1)Å    b: 13.3384(8)Å    c: 4.730(1)Å
alpha: 90.°    beta: 104.98(1)°    gamma: 90.°   Volume: 621.2(1)Å3    Crystal System: monoclinic
  File Type Information Close
Calculated diffraction file.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

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REFERENCES for Annabergite

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Phillips W, Brooke H J, Miller W H (1852) Annabergite, in An Elementary Introduction to Mineralogy Longman, Brown, Green, and Longmans London 503-504   [view file]

Mrose M E, Larson R R, Estep P A (1976) Forbesite — a mixture of cobaltoan annabergite and arsenolite, The Canadian Mineralogist, 14, 414-421   [view file]

Jambor J L, Dutrizac J E (1995) Solid solutions in the annabergite - erythrite - hörnesite synthetic system, The Canadian Mineralogist, 33, 1063-1071   [view file]

Wildner M, Giester G, Lengauer C L, McCammon C A (1996) Structure and crystal chemistry of vivianite-type compounds: Crystal structures of erythrite and annabergite with a Mössbauer study of erythrite, European Journal of Mineralogy, 8, 187-192

Frost R L, Kloprogge T, Weier M L, Martens W N, Ding Z, Edwards H G H (2003) Raman spectroscopy of selected arsenates - implications for soil remediation, Spectrochimica Acta Part A-Molecular and Biomolecular Spectroscopy, 59, 2241-2246   [link]

Frost R L, Martens W, Williams P A, Kloprogge J T (2003) Raman spectroscopic study of the vivianite arsenate minerals, Journal of Raman Spectroscopy, 34, 751-759   [link]