Tetrahedrite-(Zn) R070423

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Name: Tetrahedrite-(Zn)
RRUFF ID: R070423
Ideal Chemistry: Cu6(Cu4Zn2)Sb4S13
Locality: Tunnel Extension mine, Marysvale District (Marysvale Uranium area), Piute County, Utah, USA
Source: Michael Scott S104523 [view label]
Owner: RRUFF
Description: Lead-gray massive in a polished slab, associated with pyrite and quartz
Status: The identification of this mineral is confirmed by single-crystal X-ray diffraction and chemical analysis.
Mineral Group: [ Tetrahedrite (11) ]
Quick search: [ All Tetrahedrite-(Zn) samples (4) ]
CHEMISTRY 
RRUFF ID: R070423.2
Sample Description: Microprobe Fragment
Measured Chemistry: gray: (Cu10.26Zn1.66Fe0.08)Σ=12(Sb2.63Te0.27As0.10)Σ=4(S12.84As1.16)Σ=13; lighter: (Cu10.05Zn1.90Fe0.05)Σ=12(Sb3.72As0.24Te0.04)Σ=4(S12.90As0.10)Σ=13
Microprobe Data File: [ Download Excel File ]
RAMAN SPECTRUM 
RRUFF ID:
Sample Description: Unoriented sample
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BROAD SCAN WITH SPECTRAL ARTIFACTS
RRUFF ID: R070423
Wavelength:
Sample Description: Unoriented sample
Instrument settings: Thermo Almega XR 532nm @ 100% of 150mW
POWDER DIFFRACTION 
RRUFF ID: R070423.9
Sample Description: Single crystal, powder profile is calculated
Cell Refinement Output: a: 10.334(1)Å    b: 10.334(1)Å    c: 10.334(1)Å
alpha: 90°    beta: 90°    gamma: 90°   Volume: 1103.6(1)Å3    Crystal System: cubic
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Calculated diffraction file.

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Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

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REFERENCES for Tetrahedrite-(Zn)

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

Haidinger W (1845) Zweite Klasse: Geogenide. XIV. Ordnung. Glanze. I. Dystomglanz. Tetraedrit., in Handbuch der Bestimmenden Mineralogie Bei Braumüller and Seidel Wien 563-570   [view file]

Genth F A (1868) Contributions to mineralogy - No. VII, American Journal of Science and Arts, 95, 305-321   [view file]

International Mineralogical Association (1962) International Mineralogical Association: Commission on new minerals and mineral names, Mineralogical Magazine, 33, 260-263   [view file]

Wuensch B J (1964) The crystal structure of tetrahedrite, Cu12Sb4S13, Zeitschrift für Kristallographie, 119, 437-453   [view file]

Lévy C (1967) Contribution a la minéralogie des sulfures de cuivre du type Cu3XS4, Mémoires du Bureau de Recherches Géologiques et Minières, 54, 1-178   [view file]

Avilov A S, Imamov R M, Muradyan L A (1971) An electron diffraction study of some phases in the Cu-Sb-S system, Soviet Physics - Crystallography, 15, 616-619   [view file]

Tatsuka K, Morimoto N (1977) Tetrahedrite stability relations in the Cu-Fe-Sb-S system, American Mineralogist, 62, 1101-1109   [view file]

Makovicky E, Skinner B J (1978) Studies of the sulfosalts of copper. VI. Low-temperature exsolution in synthetic tetrahedrite solid solution, Cu12+xSb4+yS13, The Canadian Mineralogist, 16, 611-623   [view file]

Makovicky E, Skinner B J (1979) Studies of the sulfosalts of copper VII. Crystal structures of the exsolution products Cu12.3Sb4S13 and Cu13.8Sb4S13 of unsubstituted synthetic tetrahedrite, The Canadian Mineralogist, 17, 619-634   [view file]

International Mineralogical Association (1980) International Mineralogical Association: Commission on new minerals and mineral names, Mineralogical Magazine, 43, 1053-1055   [view file]

Raabe K C, Sack R O (1984) Growth zoning in tetrahedrite-tennantite from the Hock Hocking mine, Alma, Colorado, The Canadian Mineralogist, 22, 577-582   [view file]

Johnson M L, Burnham C W (1985) Crystal structure refinement of an arsenic-bearing argentian tetrahedrite, American Mineralogist, 70, 165-170   [view file]

Johnson N E, Craig J R, Rimstidt J D (1986) Compositional trends in tetrahedrite, The Canadian Mineralogist, 24, 385-397   [view file]

Peterson R C, Miller I (1986) Crystal structure and cation distribution in freibergite and tetrahedrite, Mineralogical Magazine, 50, 717-721

Johnson N E, Craig J R, Rimstidt J D (1987) Effect of substitutions on the cell dimension of tetrahedrite, The Canadian Mineralogist, 25, 237-244   [view file]

Lynch J V G (1989) Large–scale hydrothermal zoning reflected in the tetrahedrite—freibergite solid solution, Keno Hill Ag—Pb—Zn district, Yukon, The Canadian Mineralogist, 27, 383-400   [view file]

Seal R R, Essene E J, Kelly W C (1990) Tetrahedrite and tennantite: evaluation of thermodynamic data and phase equilibria, The Canadian Mineralogist, 28, 725-738   [view file]

Rozhdestvenskaya I V, Zayakina N V, Samusikov V P (1993) Crystal structure features of minerals from a series of tetrahedrite-freibergite, Mineralogiceskij Zhurnal, 15, 9-17   [view file]

Arlt T, Diamond L W (1998) Composition of tetrahedrite-tennantite and 'schwazite' in the Schwaz silver mines, North Tyrol, Austria, Mineralogical Magazine, 62, 801-820   [view file]

King R J (2001) Minerals explained 32: The tetrahedrite group, Geology Today, 17, 77-80

Sack R O (2002) Note in "large-scale hydrothermal zoning reflected in tetrahedrite-freibergite solid solution, Keno Hill Ag—Pb—Zn district, Yukon" by J.V. Gregory Lynch, The Canadian Mineralogist, 40, 1717-1719   [view file]

Ondruš P, Veselovský F, Gabašová A, Hloušek J, Šrein V, Vavrín I, Skála R, Sejkora J, Drábek M (2003) Primary minerals of the Jáchymov ore district, Journal of the Czech Geological Society, 48, 19-147   [view file]

Kharbish S, Libowitzky E, Beran A (2007) The effect of As-Sb substitution in the Raman spectra of tetrahedrite-tennantite and pyrargyrite-proustite solid solutions, European Journal of Mineralogy, 19, 567-574

Ramasamy K, Sims H, Butler W H, Gupta A (2014) Selective nanocrystal synthesis and calculated electronic structure of all four phases of copper–antimony–sulfide, Chemistry of Materials, 26, 2891-2899

Gill S B, Piercey S J, Layton-Matthews D (2016) Mineralogy and metal zoning of the Cambrian Zn-Pb-Cu-Ag-Au Lemarchant volcanogenic massive sulfide (VMS) deposit, Newfoundland, The Canadian Mineralogist, 54, 1307-1344

Apopei A I, Damian G, Buzgar N, Buzatu A, Andráš P, Milovska S (2017) The determination of the Sb/As content in natural tetrahedrite-tennantite and bournonite-seligmannite solid solution series by Raman spectroscopy, Mineralogical Magazine, 81, 1439-1456

Makovicky E, Karup-Møller S (2017) Exploratory studies of substitutions in the tetrahedrite/tennantite-goldfieldite solid solution, The Canadian Mineralogist, 55, 233-244

Biagioni C, George L L, Cook N J, Makovicky E, Moëlo Y, Pasero M, Sejkora J, Stanley C J, Welch M D, Bosi F (2020) The tetrahedrite group: Nomenclature and classification, American Mineralogist, 105, 109-122   [view file]