Diopside R050666

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Record 28 of 81  

Name: Diopside
RRUFF ID: R050666
Ideal Chemistry: CaMgSi2O6
Locality: Franklin, Sussex County, New Jersey, USA
Source: University of Arizona Mineral Museum [view label]
Owner: RRUFF
Description: Brown cleavage fragment with white hardystonite
Status: The identification of this mineral has been confirmed by X-ray diffraction and chemical analysis
Mineral Group: [ pyroxene (81) ]
Quick search: [ All Diopside samples (19) ]
RRUFF ID: R050666.2
Sample Description: Microprobe Fragment
Measured Chemistry: Ca(Mg0.66Mn0.33Fe0.01)Si2O6
Reference File: [ View PDF ]
Sample Description: Sample is oriented and mounted on a pin
Pin ID: L00536
Orientation: Laser parallel to  c*  (0 0 1).     Fiducial mark perpendicular to laser is parallel to  -a   [-1 0 0].

  To download sample data,
  please select a specific
  orientation angle.

Raman Mode Analysis
Direction of polarization of laser relative to fiducial mark:
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RRUFF ID: R050666
Sample Description: Unoriented sample
Instrument settings: Thermo Almega XR 532nm @ 100% of 150mW
INFRARED SPECTRUM (Attenuated Total Reflectance) 
RRUFF ID: R050666.1
Sample Description: Powder
Instrument settings: SensIR Durascope on a Nicolet Magna 860 FTIR
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RRUFF ID: R050666.1
Sample Description: Powder
Cell Refinement Output: a: 9.8104(6)Å    b: 8.9909(4)Å    c: 5.2641(3)Å
alpha: 90.°    beta: 105.618(6)°    gamma: 90.°   Volume: 447.17(3)Å3    Crystal System: monoclinic
  File Type Information Close
Calculated diffraction file.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

  File Type Information Close
Output file from the Bruker D8 Advance instrument. Includes device headers and XY data.

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REFERENCES for Diopside

American Mineralogist Crystal Structure Database Record: [view record]

Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America. [view file]

d’Andrada J B (1800) Der Eigenschaften und Kennzeichen einiger neuen Fossilien aus Schweden und Norwegen nebst einigen chemischen Bemerkungen über dieselben, Allgemeines Journal der Chemie, 4, 28-39   [view file]

d’Andrada J B (1801) Description of some new fossils (Old English translation), A Journal of Natural Philosophy, Chemistry, and the Arts, 5, 193-196; 211-213   [view file]

Dana E S (1904) Monoclinic Section. Pyroxene, in The System of Mineralogy of James Dwight Data 1837-1868, Sixth Edition John Wiley & Sons New York 352-371   [view file]

Washington H S, Merwin H E (1927) The acmitic pyroxenes, American Mineralogist, 12, 233-252   [view file]

Bannister F A (1932) Proceedings of societies: Mineralogical Society of Great Britian and Ireland, American Mineralogist, 17, 455-455   [view file]

Aleksandrov K S, Ryzhova T V, Belikov B P (1964) The elastic properties of pyroxenes, Soviet Physics - Crystallography, 8, 589-591   [view file]

Grubb P L C (1965) An unusual occurrence of diopside and uvarovite near Thetford, Quebec, The Canadian Mineralogist, 8, 241-248   [view file]

Clark J R, Appleman D E, Papike J J (1969) Crystal-chemical characterization of clinopyroxenes based on eight new structure refinements, Mineralogical Society of America Special Paper, 2, 31-50   [view file]

Nolan J (1969) Physical properties of synthetic and natural pyroxenes in the system diopside-hedenbergite-acmite, Mineralogical Magazine, 37, 216-229   [view file]

Rutstein M S, Yund R A (1969) Unit-cell parameters of synthetic diopside-hedenbergite solid solutions, American Mineralogist, 54, 238-245   [view file]

Sood M K, Platt R G, Edgar A D (1970) Phase relations in portions of the system diopside-nepheline-kalsilite-silica and their importance in the genesis of alkaline rocks, The Canadian Mineralogist, 10, 380-394   [view file]

Cameron M, Sueno S, Prewitt C T, Papike J J (1973) High-temperature crystal chemistry of acmite, diopside, hedenbergite, jadeite, spodumene, and ureyite, American Mineralogist, 58, 594-618   [view file]

Turnock A C, Lindsley D H, Grover J E (1973) Synthesis and unit cell parameters of Ca-Mg-Fe pyroxenes, American Mineralogist, 58, 50-59   [view file]

Veblen D R, Buseck P R, Burnham C W (1977) Asbestiform chain silicates: New minerals and structural groups, Science, 198, 359-365   [view file]

Cameron M, Papike J J (1981) Structural and chemical variations in pyroxenes, American Mineralogist, 66, 1-50   [view file]

LeAnderson P J (1981) Calculation of temperature and X(CO2) values for tremolite—K–feldspar—diopside—epidote assemblages, The Canadian Mineralogist, 19, 619-630   [view file]

Levien L, Prewitt C T (1981) High-pressure structural study of diopside, American Mineralogist, 66, 315-323   [view file]

Morimoto N (1988) Nomenclature of pyroxenes, Mineralogical Magazine, 52, 535-550   [view file]

Wang X, Greenwood H J (1988) An experimental study of the equilibrium: grossular + clinochlore = 3 diopside + 2 spinel + 4 H2O, The Canadian Mineralogist, 26, 269-281   [view file]

Cheng W, Greenwood H J (1989) The stability of the assemblage zoisite + diopside, The Canadian Mineralogist, 27, 657-662   [view file]

Dickinson J E, Scarfe C M (1990) Raman spectroscopic study of glasses on the join diopside-albite, Geochimica et Cosmochimica Acta, 54, 1037-1043   [link]

Raudsepp M, Hawthorne F C, Turnock A C, (1990) Crystal chemistry of synthetic pyroxenes on the join CaNiSi2O6-CaMgSi2O6 (diopside): A Rietveld structure refinement study, American Mineralogist, 75, 1274-1281   [view file]

Raudsepp M, Hawthorne F C, Turnock A C (1990) Evaluation of the Rietveld method for the characterization of fine-grained products of mineral synthesis: the diopside-hedenbergite join, The Canadian Mineralogist, 28, 93-109   [view file]

Lüttge A, Metz P (1991) Mechanism and kinetics of the reaction 1 dolomite + 2 quartz = 1 diopside + 2 CO2 investigated by powder experiments, The Canadian Mineralogist, 29, 803-821   [view file]

Swamy V, Dubrovinsky L, Matsui M (1997) High-temperature Raman spectroscopy and quasi-harmonic lattice dynamic simulation of diopside, Physics and Chemistry of Minerals, 24, 440-446   [link]

Richet P, Mysen B, Ingrin J (1998) High-temperature X-ray diffraction and Raman spectroscopy of diopside and pseudowollastonite, Physics and Chemistry of Minerals, 25, 401-414   [link]

Herd C D K, Peterson R C, Rossman G R (2000) Violet-colored diopside from southern Baffin Island, Nunavut, Canada, The Canadian Mineralogist, 38, 1193-1199   [view file]

Huang E, Chen C H, Huang T, Lin E H, Xu J (2000) Raman spectroscopic characteristics of Mg-Fe-Ca pyroxenes, American Mineralogist, 85, 473-479   [view file]

Prencipe M, Tribaudino M, Pavese A, Hoser A, Reehuis M (2000) A single-crystal neutron-diffraction investigation of diopside at 10 K, The Canadian Mineralogist, 38, 183-189   [view file]

Wang A, Jolliff B L, Haskin L A, Kuebler K E, Viskupic K M (2001) Characterization and comparison of structural and compositional features of planetary quadrilateral pyroxenes by Raman spectroscopy, American Mineralogist, 86, 790-806   [view file]

Weng Y H, Presnall D C (2001) The system diopside - forsterite - enstatite at 5.1 GPa: a ternary model for melting of the mantle, The Canadian Mineralogist, 39, 299-308   [view file]

Chopelas A, Serghiou G (2002) Spectroscopic evidence for pressure-induced phase transitions in diopside, Physics and Chemistry of Minerals, 29, 403-408   [link]

Nimis P (2002) The pressures and temperatures of formation of diamond based on thermobarometry of chromian diopside inclusions, The Canadian Mineralogist, 40, 871-884   [view file]

Shannon R D, Shannon R C, Medenbach O, Fischer R X (2002) Refractive index and dispersion of fluorides and oxides, Journal of Physical and Chemical Reference Data, 31, 931-970   [view file]

Tribaudino M, Nestola F (2002) Average and local structure in P21/c clinopyroxenes along the join diopside-enstatite (CaMgSi2O6-Mg2Si2O6), European Journal of Mineralogy, 14, 549-555

Akaogi M, Yano M, Tejima Y, Iijima M, Kojitani H (2004) High-pressure transition of diopside and wollastonite: phase equilibria and thermochemistry of CaMgSi2O6, CaSiO3 and CaSi2O5--CaTiSiO5 system, Physics of The Earth and Planetary Interiors, 143, 145-156

Hamilton V E, McSween H Y, Hapke B (2005) Mineralogy of Martian atmospheric dust inferred from thermal infrared spectra of aerosols, Journal of Geophysical Research, 110, E12006   [link]

Thompson R M, Downs R T (2008) The crystal structure of diopside at pressure to 10 GPa, American Mineralogist, 93, 177-186   [view file]

Boffa Ballaran T, Nestola F, Tribaudino M, Ohashi H (2009) Bulk modulus variations along the diopside-kosmochlor solid solution, European Journal of Mineralogy, 21, 591-597

Buzatu A, Buzgar N (2010) The Raman study of single-chain silicates, Analele Stiintifice Ale Universitatii, Al. I. Cuza Iasi Geologie, 56, 107-125   [view file]

Plonka A M, Dera P, Irmen P, Rivers M L, Ehm L, Parise J B (2012) β-diopside, a new ultrahigh-pressure polymorph of CaMgSi2O6 with six-coordinated silicon, Geophysical Research Letters, 39, L24307, 1-4

Tribaudino M, Mantovani L, Bersani D, Lottici P P (2012) Raman spectroscopy of (Ca,Mg)MgSi2O6 clinopyroxenes, American Mineralogist, 97, 1339-1347   [view file]

Mantovani L, Tribaudino M, Mezzadri F, Calestani G, Bromiley G (2013) The structure of (Ca,Co)CoSi2O6 pyroxenes and the Ca-M2+ substitution in (Ca,M2+)M2+Si2O6 pyroxenes (M2+ = Co, Fe, Mg), American Mineralogist, 98, 1241-1252

Mantovani L, Tribaudino M, Bertoni G, Salvianti G, Bromiley G (2014) Solid solutions and phase transitions in (Ca,M2+)M2+Si2O6 pyroxenes (M2+ = Co, Fe, Mg), American Mineralogist, 99, 704-711

Yang Y, Xia Q, Zhang P (2015) Evolution of OH groups in diopside and feldspars with temperature, European Journal of Mineralogy, 27, 185-192

Nespolo M, Aroyo M I (2016) The modular structure of pyroxenes, European Journal of Mineralogy, 28, 189-203

Thompson R M, Yang H, Downs R T (2016) Ideal wollastonite and the structural relationship between the pyroxenoids and pyroxenes, American Mineralogist, 101, 2544-2553

Akasaka M, Takasu Y, Handa M, Nagashima M, Hamada M, Ejima T (2019) Distribution of Cr3+ between octahedral and tetrahedral sites in synthetic blue and green (CaMgSi2O6)95(CaCrAlSiO6)5 diopsides, Mineralogical Magazine, 83, 497-505

Gao W, Ciobanu C L, Cook N J, Slattery A, Huang F, Wang D (2019) Nanoscale study of lamellar exsolutions in clinopyroxene from olivine gabbro: Recording crystallization sequences in iron-rich layered intrusions, American Mineralogist, 104, 244-261

Hao M, Pierotti C E, Tkachev S, Prakapenka V, Zhang J S (2019) The single-crystal elastic properties of the jadeite-diopside solid solution and their implications for the composition-dependent seismic properties of eclogite, American Mineralogist, 104, 1016-1021

Balan E, Paulatto L, Liu J, Ingrin J (2020) Low-temperature infrared spectrum and atomic-scale structure of hydrous defects in diopside, European Journal of Mineralogy, 32, 505-520   [view file]

Fan D, Fu S, Lu C, Xu J, Zhang Y, Tkachev S N, Prakapenka V B, Lin J F (2020) Elasticity of single-crystal Fe-enriched diopside at high-pressure conditions: Implications for the origin of upper mantle low-velocity zones, American Mineralogist, 105, 363-374